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An Efficient One-Pot Strategies for the Synthesis of [1,3] Oxazine Derivatives

Bapurao B. Shingate|Murlidhar S. Shingare|Suryakant B. Sapkal|Kiran F. Shelke
대한화학회|2010.08|대한화학회지 (Journal of the Korean Chemical Society)|제54권 제4호|pp. 437-442

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참고문헌

키워드

Ionic liquidGrindingCyclocondensation[13] Oxazine derivativesOne-pot strategies3] Oxazine 유도체One-pot 전략
주제분류화학

초록

Sodium hydrogen sulphate (NaHSO4), n-tetra butyl ammonium bromide (TBAB) as a phase transfer catalyst (PTC) in water, and 1-butyl-3-methyl imidazolium hydrogen sulphate [bmim]HSO4 as ionic liquid (IL) has been used as a mild reaction promoter for the cyclocondensation of formalin, β-naphthol and aromatic amines to afford respective 2,3-dihydro-2-phenyl-1H-naphtho-[1,2-e] [1,3] oxazine derivatives. The present protocols are greener, high yielding and involved the nonchromatographic isolation procedure.

Abstract

수용액 속에서 NaHSO4, TBAB (phase transfer catalyst), ionic liquid (IL) (1-butyl-3-methyl imidazolium hydrogen sulphate [bmim]HSO4)를 사용하여, formalin, β-naphthol, aromatic amines을 반응시켜서 대응하는 2,3-dihydro-2-phenyl-1Hnaphtho-[1,2-e] [1,3] oxazine 유도체를 합성할 수 있는 보다 친환경적이고, 수율이 좋고, 크로마토그래피 분리 방법을 사용하지 않는 합성 방법을 개발하였다.

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