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One-pot Synthesis of Dihydropyrimidinones Using Polyoxometalate Tri-supported Transition Metal Complexes

Polyoxometalate Tri-supported Transition Metal Complexes를 이용한 Dihydropyrimidinones의 one-pot 합성

Hamid Aliyan|Razieh Fazaeli|Foroogh Mohammadifar|Amir Abbas Zamani|Mohammad Javad Bagi
대한화학회|2011.08|대한화학회지 (Journal of the Korean Chemical Society)|제55권 제4호|pp. 666-672

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참고문헌

키워드

Polyoxometalates (POMs)Keggin molybdenum-vanadium heteropolyoxoanionsDihydropyrimidinones (DHPMs)inorganic-organic complex유-무기 착물
주제분류화학

초록

The catalytic activity of an inorganic-organic complex with a vanadium-substituted polyoxometalate 1, formulated as [Cu(2,2′-bipy)][Cu(2,2′-bipy)_2]_2[PMo_8V_6O_(42)]·1.5H_2O was studied in the Biginelli reactions. The obtained results showed that, in the one-pot synthesis of dihydropyrimidinones, the turnover frequencies (TOF) for the [Cu(2,2′-bipy)][Cu(2,2′-bipy)_2]_2[PMo_8V_6O_(42)]·1.5H_2O catalyst were higher than the H_3PMo_(12)O_(40) catalyst.

Abstract

The catalytic activity of an inorganic-organic complex with a vanadium-substituted polyoxometalate 1, formulated as [Cu(2,2′-bipy)][Cu(2,2′-bipy)_2]_2[PMo_8V_6O_(42)]·1.5H_2O was studied in the Biginelli reactions. The obtained results showed that, in the one-pot synthesis of dihydropyrimidinones, the turnover frequencies (TOF) for the [Cu(2,2′-bipy)][Cu(2,2′-bipy)_2]_2[PMo_8V_6O_(42)]·1.5H_2O catalyst were higher than the H_3PMo_(12)O_(40) catalyst.

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