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Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction

Mohammad Hakimi
대한화학회|2013.12|대한화학회지 (Journal of the Korean Chemical Society)|제57권 제6호|pp. 721-725|DOI http://dx.doi.org/10.5012/jkcs.2013.57.6.721

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키워드

X-ray crystal structurePicolinateSpectral characterizationChromium(III) complex
주제분류화학

초록

Reaction between 2-pyridinecarboxylic acid (Hpic) and K3[Cr(O2)4] give complex [Cr(pic)3].H2O (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two O-H···O hydrogen bonds.

Abstract

Reaction between 2-pyridinecarboxylic acid (Hpic) and K3[Cr(O2)4] give complex [Cr(pic)3].H2O (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two O-H···O hydrogen bonds.

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