Study of Dynamics of Allyl Chloride-2-Butanone Binary System Using Time Domain Reflectometry
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Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density (ρ) and refractive index (nD) are also measured. These parameters are used to determine excess dielectric constant,excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.
Abstract
Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density (ρ) and refractive index (nD) are also measured. These parameters are used to determine excess dielectric constant,excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.
참고문헌 (32)
- Dharmalingam, K, , Mol. Phys, 18(20), pp.2835~ (2006)
- Sivagurunathan, P, , Physica B, 387, pp.203~ (2007)
- Undre, P, , Pramana J. Phys, 68, pp.851~ (2007)
- Pawar V. P, , J. Mol. Liq, 95, pp.63~ (2002)
- Baraldi, P, , J. Sol. Chem, 31(11), pp.873~ (2002)
- Lomte, S. B, , J. Chem. Eng. Data, 54, pp.127~ (2009)
- Clara, R. A, , J. Chem. Thermodynamics, 40, pp.292~ (2008)
- Ortega, J, , Can. J. Chem, 63, pp.3354~ (1985)
- Maharolkar, A. P, , Int. J. Chem, 2(2), pp.250~ (2010)
- Dharne, G. M, , Int. J. Pharma and Bio Sci, 1(2), pp.1~ (2010)
- Dharne, G. M, , Mat. Sci. Res. India, 5(2), pp.391~ (2008)
- Madhurima, V, , Phys. Chem. Liq, 44(5), pp.563~ (2006)
- Gilani, A. G, , J. Chem. Thermodynamics, 43, pp.569~ (2011)
- Gemert, M. J. C. van, , Adv. Mol. Relaxation Processes, 6, pp.123~ (1974)
- Bertolini, D, , Rev. Sci. Instrum, 61, pp.12~ (1990)
- Berberian, J. G, , J. Non-Cryst. Solids, 305, pp.10~ (2002)
- Shannon, C. E, , Proc. IRE, 37, pp.10~ (1949)
- Samulan, H. A, , Proc. IRE, 39, pp.175~ (1951)
- Cole, R. H, , J. Appl. Phys, 66, pp.793~ (1989)
- Debye, P., "Polar Molecules" (1929), Chemical Catalog
- Mehrotra, S. C, , J. Chem. Phys, 66, pp.5306~ (1977)
- Bruggeman, D. A. G., , Ann. Phys. (Leopz.), 5, pp.636~ (1935)
- Putintsev, N. M, , Russian J. Phys. Chem, 80(12), pp.1949~ (2006)
- Marshall, William L, "Nature Proceedings. hdl: 10101", npre.2474, 2008
- Glasstone, S, "The Theory of Rate Process" (1941), McGraw-Hill
- Hill, N. E, "Dielectric Properties and Molecular Behavior" (1969), Van Nostrand
- Sengwa, R. J, , J. Sol. Chem, 38, pp.763~ (2009)
- Sengwa, R. J, , J. Mol. Liq, 151, pp.17~ (2010)
- Sivagurunathan, P, , Main Group Chem, 4(3), pp.235~ (2005)
- Gupta, M, , Phy. Chem. Liq, 48(4), pp.415~ (2010)
- Redlich, O, , Ind. Eng. Chem, 40, pp.345~ (1948)
- Sengwa, R. J., , J. Mol. Liq, 108(1), pp.47~ (2003)