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DABCO-Catalyzed Green Synthesis of 2-Hydroxy-1,4-diones via Direct Aldol Reaction of Arylglyoxals in Water

Mahnaz Saraei|Bagher Eftekhari-Sis|Sakineh Mozaffarnia
대한화학회|2013.04|대한화학회지 (Journal of the Korean Chemical Society)|제57권 제2호|pp. 252-259

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참고문헌

키워드

1Green chemistry4-DiketonesAldol reactionArylglyoxalsDABCO
주제분류화학

초록

A green and simple method to synthesize of 1,4-diketones via aldol reaction of arylglyoxals and ketones such as 1-(4-methoxyphenyl)-2-propanone, deoxybenzoin and substituted acetophenones in the presence of a catalytic amount of DABCO in water at room temperature has been reported. Corresponding 2-hydroxy-1,4-diones were obtained in moderate to high yields with simple separation of obtained solid from reaction mixture and recrystallization.

Abstract

A green and simple method to synthesize of 1,4-diketones via aldol reaction of arylglyoxals and ketones such as 1-(4-methoxyphenyl)-2-propanone, deoxybenzoin and substituted acetophenones in the presence of a catalytic amount of DABCO in water at room temperature has been reported. Corresponding 2-hydroxy-1,4-diones were obtained in moderate to high yields with simple separation of obtained solid from reaction mixture and recrystallization.

참고문헌 (78)

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