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Rate Enhancement by Micelle Encapsulation for Oxidation of L-Glutamic Acid in Aqueous Media at Room Temperature

Bidyut Saha|Kakali Mukherjee
대한화학회|2013.08|대한화학회지 (Journal of the Korean Chemical Society)|제57권 제4호|pp. 425-431|DOI http://dx.doi.org/10.5012/jkcs.2013.57.4.425

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참고문헌

키워드

CatalystOxidationPromoterMicelle
주제분류화학

초록

Oxidation of glutamic acid is performed in aqueous acid media at 30 oC under the kinetic condition [glutamic acid]T>>[Cr(VI)]T. Effect of combination of micellar catalyst (SDS, TX-100) and promoter (PA, bpy, phen) has been studied. Among the promoters phen accelerates the reaction most in aqueous media. But the rate acceleration is small in the case. Combination of promoter and catalyst produces much better result. Maximum rate enhancement occurs in presence of the combination of bpy and SDS.

Abstract

Oxidation of glutamic acid is performed in aqueous acid media at 30 oC under the kinetic condition [glutamic acid]T>>[Cr(VI)]T. Effect of combination of micellar catalyst (SDS, TX-100) and promoter (PA, bpy, phen) has been studied. Among the promoters phen accelerates the reaction most in aqueous media. But the rate acceleration is small in the case. Combination of promoter and catalyst produces much better result. Maximum rate enhancement occurs in presence of the combination of bpy and SDS.

참고문헌 (33)

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