The Synthesis and Light Absorption Behaviour of Novel Coumarin Chromophores
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The synthetic route to coumarin systems is well established and one approach of particular interest leads to the intermediate 7-diethylamino-3-formylcoumarin. A combination of the N,N-diethylamino-coumarin donor with a wide range of acceptor groups of varying electron withdrawing strength should permit the synthesis of a series of extended coumarin dyes with absorption maxima range from 500 to 600 nm, or even beyond. In this communication, a novel efficient synthesis of indoles, benzothiazole and benzoxazole based on coumarin chromophores were achieved and the coloristic and fluorophoric properties of these chromophores were studied.
Abstract
The synthetic route to coumarin systems is well established and one approach of particular interest leads to the intermediate 7-diethylamino-3-formylcoumarin. A combination of the N,N-diethylamino-coumarin donor with a wide range of acceptor groups of varying electron withdrawing strength should permit the synthesis of a series of extended coumarin dyes with absorption maxima range from 500 to 600 nm, or even beyond. In this communication, a novel efficient synthesis of indoles, benzothiazole and benzoxazole based on coumarin chromophores were achieved and the coloristic and fluorophoric properties of these chromophores were studied.
참고문헌 (25)
- Prasanna de Silva, A, "Signaling Recognition Events with Fluorescent Sensors and Switches", Chem. Rev, 97, pp.1515~1566 (1997)
- Prasanna de Silva, A, "Bright Molecules with Sense, Logic, Numeracy and Utility", Org. Biomol. Chem, 6, pp.2468~2481 (2008)
- Ohkawa, M, "U.S. Patent 3,933,847", ~ (1976)
- Horst, H, "U.S. Patent 3,985,763", ~ (1976)
- Loew, P, "U.S. Patent 4,064,136", ~ (1977)
- Loew, P, "U.S. Patent 4,146,712", ~ (1979)
- Ayyangar, N. R, "Polycyclic Compounds Part VI: Structural Features of C.I. Disperse Yellow 232", Dyes and Pigments, 13(4), pp.301~310 (1990)
- Ayyangar, N. R, "Polycyclic Compounds Part VII: Synthesis, Laser Characteristics and Dyeing Behaviour of 7-Diethylamno-2H-1-benzopyran-2-ones", Dyes and Pigments, 16(3), pp.197~204 (1991)
- Moeckli, P, "Preparation of Some New Red Fluorescent 4-Cyanocoumarin Dyes", Dyes and Pigments, 1(1), pp.3291~15 (1980)
- Mockli, P, "U.S. Patent 4,609,738, 1986; U.S. Patent 5,547,579", ~ (1985)
- Mach, W, "Ger. Offen. 2,253,538", ~ (1972)
- Horng, M. L, "Subpicosecond Measurement of Polar Salvation Dynamics: Coumarin 153 Revisited", J. Phys. Chem, 99, pp.17311~17337 (1995)
- Arbeloa, T. L, "Influence of Fluorinated Group on the Photophysics of 7-Aminocoumarins", J. Luminescence, 68, pp.149~155 (1996)
- Du, D. M, "Micro-environmental Effects on the Photochemical and Photophysical Processes of Long Chain Coumarin Esters", Chem. J. Chin. Univ.-Chin, 19, pp.1611~1613 (1998)
- Raju, B. B, "Photophysical Properties of 7-Diethylaminocoumarin Dyes in Dioxanewater Mixtures: Hydrogen Bonding, Dielectric Enrichment and Polarity Effects", Phys. Chem. Chem. Phys, 1, pp.3539~3547 (1999)
- Ramalingam, A, "Photophysics of TICT States of 7-Diethylamino-4- methyl Coumarin Dye by Energy Transfer Techniques", Spectrochim. Acta, Part A: Molec. Biomolec. Spect, 56, pp.1206~1210 (2000)
- "Res. Chem. Intermed", 2005, 575~583
- Raikar, U. S, "Rotational Diffusion and Solvatochromic Correlation of Coumarin 6 Laser Dye", J. Fluorescence, 16, pp.847~854 (2006)
- Raikar, U. S, "Solvent Effects on the Absorption and Fluorescence Spectra of Coumarins 6 and 7 Molecules: Determination of Ground State and Excited State Dipole Moment", Spectrochim. Acta, 65, pp.673~677 (2006)
- Tablet, C, "Quenching of the Fluorescence of Carboxy-5,6-benzocoumarin by Aromatic Amines", J. Photochem. Photobiol. A Chem, 189, pp.73~79 (2007)
- Wang, T, "The Synthesis of Novel Coumarin Dyes and the Study of Their Photoreaction Properties", Dyes Pigments, 75, pp.104~110 (2007)
- Hantzsch, A, , Ber. Dtsch, Chem. Ges, 55, pp.953~ (1922)
- Pugzlys, A, , M. Int. J. Photoenergy, pp.24~29 (2006)
- Camposeo, A, , Org. Electro, 8, pp.114~119 (2007)
- Ricceri, R, , Langmuir, 13, pp.3434~3441 (1997)
