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Application of Radiotracer Technique in Remediation of Zn(II) from Aqueous Solutions by dry cowdung powder

Sabrina Afzal Shaikh|Hemlata Kapil Bagla
한국원자력학회 (Korean Nuclear Society)|2022.02|Nuclear Engineering and Technology|제54권 제2호|pp. 456-461|DOI https://doi.org/10.1016/j.net.2021.08.013

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키워드

Eco-friendlyZincBiosorptionGreen chemistry
주제분류원자력공학

초록

Heavy metal pollution is caused due to anthropogenic activities and is considered as a serious environmental problem which endangers human health and environment. The present study deals withbiosorption, an eco-friendly technique for the removal of heavy metal Zn(II) from aqueous medium. Various natural materials have been explored for the uptake of metal ions, where most of them arephysically or chemically enhanced. Dry cowdung powder (DCP) has been utilized as a low-cost, environmentally friendly humiresin without any pre-treatment, thus demonstrating the concept of GreenChemistry. Batch biosorption studies using 65Zn(II) tracer were performed and the impact of differentexperimental parameters was studied. Results revealed that at pH 6, 94 ± 2% of Zn(II) was effectivelybiosorbed in 5 min, at 303 K. The process was spontaneous and exothermic, following pseudo-secondorder reaction. The mechanism of heavy metal biosorption employing green adsorbent was thereforeelucidated in order to determine the optimal method for removing Zn(II) ions. DCP has a lot of potentialin the wastewater treatment industry, as seen by its ability to meet 3A's affordability, adaptability, andacceptability criteria. As a result, DCP emerges as one of the most promising challengers for greenchemistry and the zero-waste idea

Abstract

Heavy metal pollution is caused due to anthropogenic activities and is considered as a serious environmental problem which endangers human health and environment. The present study deals withbiosorption, an eco-friendly technique for the removal of heavy metal Zn(II) from aqueous medium. Various natural materials have been explored for the uptake of metal ions, where most of them arephysically or chemically enhanced. Dry cowdung powder (DCP) has been utilized as a low-cost, environmentally friendly humiresin without any pre-treatment, thus demonstrating the concept of GreenChemistry. Batch biosorption studies using 65Zn(II) tracer were performed and the impact of differentexperimental parameters was studied. Results revealed that at pH 6, 94 ± 2% of Zn(II) was effectivelybiosorbed in 5 min, at 303 K. The process was spontaneous and exothermic, following pseudo-secondorder reaction. The mechanism of heavy metal biosorption employing green adsorbent was thereforeelucidated in order to determine the optimal method for removing Zn(II) ions. DCP has a lot of potentialin the wastewater treatment industry, as seen by its ability to meet 3A's affordability, adaptability, andacceptability criteria. As a result, DCP emerges as one of the most promising challengers for greenchemistry and the zero-waste idea

참고문헌 (51)

  1. M. V. Blanco, "Kinetics of bioaccumulation of heavy metals in Odontesthes bonariensis is explained by a single and common mechanism", Ecol. Model, 274, pp.50~56 (2014)
  2. P. Anastas, "Green Chemistry : Theory and Practice" (1998), Oxford University Press
  3. L. Zhu, "5-Arylvinylene-2,2’-bipyridyls: bright “push-pull” dyes as componentes in fluorescente indicators for zinc ions", J. Photochem. Photobiol. Chem, 311, pp.1~15 (2015)
  4. J. Nriagu, , Zinc toxicity in humans : Encycl. Environ. Heal, pp.801~807 (2011)
  5. L. M. Gaetke, "Copper toxicity, oxidative stress, and antioxidant nutrients", Toxicology, 189, pp.147~163 (2003)
  6. A. Prasad, "Zinc deficiency : its characterization and treatment", Met. Ions Biol. Syst, 41, pp.103~137 (2004)
  7. R. C. Sahu, "Adsorption of Zn(II)on activated red mud : neutralized by CO2", Desalination, 266, pp.93~97 (2011)
  8. A. O. Oje, "Environmental pollution levels of lead and zinc in ishiagu and uburu communities of Ebonyi state, Nigeria", Bull. Environ. Contam. Toxicol, 85, pp.313~317 (2010)[DOI]
  9. Affonso Celso Goncalves, "Heavy Metal Contamination in Brazilian Agricultural Soils due to Application of Fertilizers", Environmental Risk Assessment of Soil Contamination (2014), InTech[DOI]
  10. X. Zhang, "Impacts of lead", zinc mining and smelting on the environment and human health in China, 2012, pp.184, 2261~2273
  11. A. I. Zouboulis, "Removal of cadmium from dilute solutions by hydroxylapatite II. Flotation studies", Separ. Sci. Technol, 32, pp.1755~1767 (1997)
  12. L. Charerntanyarak, "Heavy metals removal by chemical coagulation and precipitation", Water Sci. Technol, 39, pp.135~138 (1999)
  13. A. Dabrowski, "Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method", Chemosphere, 56, pp.91~106 (2004)
  14. A. Witek-Krowiak, "Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent", Desalination, 265, pp.126~134 (2011)
  15. R. Gandhimathi, "Biosorption of Cu(II)and Zn(II)ions from aqueous solution by water hyacinth(Eichhornia crassipes)", Int. J. Environ. Waste Manag, 11, pp.365~386 (2013)
  16. A. Buasri, "Equilibrium and kinetic studies of biosorption of Zn(II)ions from wastewater using modified corn cob", APCBEE Procedia, 3, pp.60~64 (2012)
  17. T. Lee, "Waste green sands as reactive media for the removal of zinc from water", Chemosphere, 56, pp.571~581 (2004)
  18. C. Zhou, "Removal of Pb(II)and Zn(II)from aqueous solutions by raw crab shell : a comparative study", Water Environ. Res, 88, pp.374~383 (2016)
  19. M. Gorgievski, "Kinetics, equilibrium and mechanism of Cu2þ, Ni2þ and Zn2þ ions biosorption using wheat straw", Ecol. Eng, 58, pp.113~122
  20. X. Zuo, "Biosorption of copper, zinc and cadmium using sodium hydroxide immersed Cymbopogon schoenanthus L. Spreng (lemon grass)", Ecol. Eng, 49, pp.186~189 (2012)
  21. A. Saeed, "Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent", Separ. Purif. Technol, 45, pp.25~31 (2005)[DOI]
  22. Marina Corral-Bobadilla, "Bioremediation of Waste Water to Remove Heavy Metals Using the Spent Mushroom Substrate of Agaricus bisporus", Water, 11(3), pp.454~ (2019), MDPI AG[DOI]
  23. M. do S. Vale, "Cr and Zn biosorption by Aspergillus Niger", Environ. Times. Earth Sci, 75, pp.462~473 (2016)[DOI]
  24. C. Chen, "Cation (Kþ, Mg2þ, Naþ, Ca2þ) release in Zn (II) biosorption by Saccharomyces cerevisiae", Huanjing Kexue, 27, pp.2261~2267 (2006)
  25. F. Al-Tohami, "Adsorption of Zn(II)ions from aqueous solutions by novel adsorbent : Ngella sativa seeds", APCBEE Procedia, 5, pp.400~404 (2013)
  26. A. Chergui, "Simultaneous biosorption of Cu2þ, Zn2þ and Cr6þ from aqueous solution by Streptomyces rimosus biomass", Desalination, 206, pp.179~184 (2007)
  27. S. Z. Sabae, "D. S, Bioremediation of Znþ2, Cuþ2and Feþ2 using Bacillus subtilis D215 and Pseudomonas putida biovar A D225", Biosci. Res, 3, pp.189~204 (2006)
  28. S. B. Akinde, "Aerobic heterotrophic bacteria and petroleum-utilizing bacteria from cow dung and poultry manure", World J. Microbiol. Biotechnol, 24, pp.1999~2002 (2008)[DOI]
  29. N. S. Barot, "Biosorption of radiotoxic 90Sr by green adsorbent : dry cow dung powder", J. Radioanal. Nucl. Chem, 294, pp.81~86 (2012)[DOI]
  30. S. A. Shaikh, "Comparative study of 110mAg(I)removal from aqueous media by humic substances", J. Radioanal. Nucl. Chem, 322, pp.225~230 (2019)[DOI]
  31. N. S. Barot, "Eco-friendly waste water treatment by cow-dung powder (Adsorption studies of Cr(III), Cr (VI) & Cd(II) using Tracer Technique)", Desalin. Water Treat, 38, pp.104~113 (2012)
  32. N. S. Barot, "Studies on biosorption of Cr(VI)on a green resin : dry cow dung poeder and tracer technique", Radiochim. Acta, 100, pp.833~842 (2012)[DOI]
  33. G. H. Jeffery, "Vogel's Textbook of Quantitative Chemical Analysis" (1989), John Wiley and Sons Inc
  34. G. Balasubramanian, "Element analysis with fundamental parameters using an XRF spectrum analysis MATLAB algorithm", Int. J. Eng. Appl. Sci, 3, pp.2394~3661 (2016)
  35. S. Faust, "Adsorption Processes for Water Treatment" (1986), Elsevier
  36. K. Uthra, "Biosorption of nickel using mixed cultures of Pseudomonas aeruginosa and Bacillus subtilis", Def. Life Sci. J, 2, pp.442~ (2017)[DOI]
  37. W. T. Tan, "Removal of lead, cadmium and zinc by waste tea leaves", Environ. Technol. Lett, 9, pp.1223~1232 (1988)
  38. V. Munagapati, "Biosorption of Cu(II), Cd(II) and Pb(II) by Acacia leucocephala bark powder: kinetics, equilibrium and thermodynamics", Chem. Eng. J, 157, pp.357~365 (2010)[DOI]
  39. Munagapati Venkata Subbaiah, "Biosorption of Nickel(II) from Aqueous Solution by the Fungal Mat of Trametes versicolor (Rainbow) Biomass: Equilibrium, Kinetics, and Thermodynamic Studies", Biotechnology and Bioprocess Engineering, 18(2), pp.280~288 (2013), 한국생물공학회
  40. L. Langmuir, "The constitution and fundamental properties of solids and liquids", J. Am. Chem. Soc, 38, pp.2221~2295 (1916)
  41. H. Freundlich, "Over the adsorption in solution", J. Phys. Chem, 57, pp.385~470 (1906)
  42. O. E. Okeola FO, "Freundlich and Langmuir isotherms parameters for adsorption of methylene blue by activated carbon derived from agrowastes", Adv Nat Appl Sci, 4, pp.281~288 (2010)
  43. Z. Z. Abidin, "Biosorption of Zn(II)from aqueous solution by jatropha curcas press cake", J. Sci. Ind. Res, 73, pp.191~194 (2014)
  44. U. Israel, U.M. Eduok, "Biosorption of zinc from aqueous solution using coconut (Cocos nucifera L) coir dust", Arch. Appl. Sci. Res, 4, pp.809~819 (2012)
  45. E. Valdman, "Continuous biosorption of Cu and Zn by immobilized waste biomass Sargassum sp", Process Biochem, 36, pp.869~873 (2001)[DOI]
  46. M. Horsfall, "Sorption of chromium(VI) from aqueous solution by cassava (Manihot sculenta cranz.), Waste Biomass", Chem. Biodivers, 3, pp.161~174 (2006)[DOI]
  47. E. Bulut, "Adsorption of malachite green ontobentonite : equilibrium and kinetic study and process design", Microporous Mesoporous Mater, 115, pp.234~246 (2008)
  48. H. E. Bakouri, "Adsorptive features of acidtreated olive stones for drin pesticides: equilibrium, kinetic and thermodynamic modeling studies", Bioresour. Technol, 100, pp.4147~4155 (2009)
  49. R. R. Navarro, "Heavy metal precipitation by polycationepolyanion complex of PEI and its phosphonomethylated derivative", J. Hazard Mater, 123, pp.203~209 (2005)
  50. P. King, "Biosorption of zinc onto Syzygium cumini L. : equilibrium and kinetic studies", Chem. Eng. J, 144, pp.181~187 (2008)
  51. T. W. Tee, "Removal of lead, cadmium and zinc by waste tea leaves", Environ. Technol. Lett, 9, pp.1223~1232 (1988)

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