본문 바로가기
KERD
논문KCI 등재

Role of modifiers on the structural, mechanical, optical and radiation protection attributes of Eu3+ incorporated multi constituent glasses

Sayyed M.I.|Poojha M.K. Komal|Marimuthu K.|Teresa P. Evangelin|Almousa Nouf
한국원자력학회 (Korean Nuclear Society)|2022.10|Nuclear Engineering and Technology|제54권 제10호|pp. 3841-3848|DOI 10.1016/j.net.2022.05.006

2

조회

0

다운로드

0

인용

0

참고문헌

키워드

FTIRRadiation shieldingMulti constituent glassesElastic moduliOptical bandgapBonding parameters
주제분류원자력공학

초록

The effect of modifiers on the optical features and radiation defying ability of the Eu3þ ions doped multi constituent glasses was examined. XRD has established the amorphous nature of the specimen. The presence of various functional/fundamental groups in the present glasses was analyzed through FTIR spectra. The physical, structural and elastic traits of the glasses were explored. The variation in the structural compactness of the glass structure according to the incorporated modifier was enlightened to describe their suitability for a better shielding media. For the examined glasses, the metallization criterion value varied in the range 0.613e0.692, indicating the non-metallic character of the glasses with possible nonlinear optical applications. The computed elastic moduli expose the Li-containing glass (BTLi:Eu) to be tightly packed and rigid, which is a requirement for a better shielding channel. Furthermore, the optical bandgap and the Urbach energy values are calculated based on the optical absorption spectra. The evaluated bonding parameters revealed the nature of the fabricated glasses covalent. In addition, we investigated the radiation attenuation attributes of the prepared Eu3þ ions doped multi constituent glasses using Phy-X software. We determined the linear attenuation coefficient (LAC) and reported the influence of the five oxides Li2O3, CaO, BaO, SrO, and ZnO on the LAC values. The LAC varied between 0.433 and 0.549 cm1 at 0.284 MeV. The 39B2O325TeO215Li2O310Na2O10K2O 1Eu2O3 glass has a much smaller LAC than the other glasses.

Abstract

The effect of modifiers on the optical features and radiation defying ability of the Eu3þ ions doped multi constituent glasses was examined. XRD has established the amorphous nature of the specimen. The presence of various functional/fundamental groups in the present glasses was analyzed through FTIR spectra. The physical, structural and elastic traits of the glasses were explored. The variation in the structural compactness of the glass structure according to the incorporated modifier was enlightened to describe their suitability for a better shielding media. For the examined glasses, the metallization criterion value varied in the range 0.613e0.692, indicating the non-metallic character of the glasses with possible nonlinear optical applications. The computed elastic moduli expose the Li-containing glass (BTLi:Eu) to be tightly packed and rigid, which is a requirement for a better shielding channel. Furthermore, the optical bandgap and the Urbach energy values are calculated based on the optical absorption spectra. The evaluated bonding parameters revealed the nature of the fabricated glasses covalent. In addition, we investigated the radiation attenuation attributes of the prepared Eu3þ ions doped multi constituent glasses using Phy-X software. We determined the linear attenuation coefficient (LAC) and reported the influence of the five oxides Li2O3, CaO, BaO, SrO, and ZnO on the LAC values. The LAC varied between 0.433 and 0.549 cm1 at 0.284 MeV. The 39B2O325TeO215Li2O310Na2O10K2O 1Eu2O3 glass has a much smaller LAC than the other glasses.

참고문헌 (58)

  1. Mengge Dong, "Study of comprehensive shielding behaviors of chambersite deposit for neutron and gamma ray", Progress in Nuclear Energy, 146, pp.104155~ (2022), Elsevier BV[DOI]
  2. I. O. Olarinoye, "Effect of Ag2O", V2O5substitution on the radiation shielding ability of tellurite glass system via XCOM approach and FLUKA simulations, 2021, pp.96, 065308~
  3. Y. Al-Hadeethi, "Evaluation of gamma ray shielding characteristics of CaF2–BaO –P2O5 glass system using Phy-X", PSD computer program, 2020, pp.126, 103397~[DOI]
  4. Y. Al-Hadeethi, "BaO–Li2O–B2O3 glass systems: Potential utilization in gamma radiation protection", Progress in Nuclear Energy, 129, pp.103511~ (2020), Elsevier BV[DOI]
  5. M. Kamislioglu, "Research on the effects of bismuth borate glass system on nuclear radiation shielding parameters", Results Phys, 22, pp.103844~ (2021)[DOI]
  6. B. O. Elbashir, "Comparison of Monte Carlo simulation of gamma ray attenuation coefficients of amino acids with XCOM program and experimental data", Results Phys, 9, pp.6~11 (2018)[DOI]
  7. N.K. Libeesh, "Applicability of the multispectral remote sensing on determining the natural rock complexes distribution and their evaluability on the radiation protection applications", Radiation Physics and Chemistry, 193, pp.110004~ (2022), Elsevier BV[DOI]
  8. N.K. Libeesh, "Advanced nuclear radiation shielding studies of some mafic and ultramafic complexes with lithological mapping", Radiation Physics and Chemistry, 189, pp.109777~ (2021), Elsevier BV[DOI]
  9. N.K. Libeesh, "Characterization of Ultramafic–Alkaline–Carbonatite complex for radiation shielding competencies: An experimental and Monte Carlo study with lithological mapping", Ore Geology Reviews, 142, pp.104735~ (2022), Elsevier BV[DOI]
  10. N. K. Libeesh, "Multispectral remote sensing for determination the Ultra-mafic complexes distribution and their applications in reducing the equivalent dose from the radioactive wastes", The European Physical Journal Plus, 137(2) (2022), Springer Science and Business Media LLC[DOI]
  11. S. Arivazhagan, "Gamma-ray protection capacity evaluation and satellite data based mapping for the limestone, charnockite, and gneiss rocks in the Sirugudi taluk of the Dindigul district, India", Radiation Physics and Chemistry, 196, pp.110108~ (2022), Elsevier BV[DOI]
  12. O. Agar, "An investigation on shielding properties of BaO, MoO3 and P2O5 based glasses using MCNPX code", Results in Physics, 12, pp.629~634 (2019), Elsevier BV[DOI]
  13. Abdu Saeed, "Neutron and charged particle attenuation properties of volcanic rocks", Radiation Physics and Chemistry, 184, pp.109454~ (2021), Elsevier BV[DOI]
  14. M. S. Al-Buriahi, "Effects of MgO addition on the radiation attenuation properties of 45S5 bioglass system at the energies of medical interest : an in silico study", J. Australas. Ceram. Soc, 57, pp.1107~1115 (2021)[DOI]
  15. Gokhan Kilic, "Synthesis and structural, optical, physical properties of Gadolinium (III) oxide reinforced TeO2–B2O3–(20-x)Li2O-xGd2O3 glass system", Journal of Alloys and Compounds, 877, pp.160302~ (2021), Elsevier BV[DOI]
  16. Mohammed Sultan Al‐Buriahi, "Radiation attenuation properties of some commercial polymers for advanced shielding applications at low energies", Polymers for Advanced Technologies, 32(6), pp.2386~2396 (2021), Wiley[DOI]
  17. G. Kilic, "Fabrication, structural, optical, physical and radiation shielding characterization of indium (III) oxide reinforced 85TeO2-(15–x)ZnO-xIn2O3 glass system", Ceramics International, 47(19), pp.27305~27315 (2021), Elsevier BV[DOI]
  18. Gokhan Kilic, "Ytterbium (III) oxide reinforced novel TeO2–B2O3–V2O5 glass system: Synthesis and optical, structural, physical and thermal properties", Ceramics International, 47(13), pp.18517~18531 (2021), Elsevier BV[DOI]
  19. G. Kilic, "The role of B2O3 on the structural, thermal, and radiation protection efficacy of vanadium phosphate glasses", Applied Physics A, 127(4) (2021), Springer Science and Business Media LLC[DOI]
  20. K.A. Naseer, "Influence of Bi2O3 concentration on barium-telluro-borate glasses: Physical, structural and radiation-shielding properties", Ceramics International, 47(1), pp.329~340 (2021), Elsevier BV[DOI]
  21. M.S. Al-Buriahi, "Effect of chromium oxide on the physical, optical, and radiation shielding properties of lead sodium borate glasses", Journal of Non-Crystalline Solids, 544, pp.120171~ (2020), Elsevier BV[DOI]
  22. A. S. Abouhaswa, "Influence of ZrO2 on gamma shielding properties of lead borate glasses", Applied Physics A, 126(1) (2020), Springer Science and Business Media LLC[DOI]
  23. Jamila S. Alzahrani, "Simulating the radiation shielding properties of TeO2–Na2O–TiO glass system using PHITS Monte Carlo code", Computational Materials Science, 196, pp.110566~ (2021), Elsevier BV[DOI]
  24. G. Kilic, "structural and nuclear radiation shielding properties of Sm2O3 reinforced borotellurite glasses", Ceram. Int, 47, pp.6154~6168 (2021)[DOI]
  25. Gharam A. Alharshan, "Radiation-transmission and self-absorption factors of P2O5 – SrO – Sb2O3 glass system", Radiation Physics and Chemistry, 193, pp.109938~ (2022), Elsevier BV[DOI]
  26. Gokhan Kilic, "Ta2O5 reinforced Bi2O3–TeO2–ZnO glasses: Fabrication, physical, structural characterization, and radiation shielding efficacy", Optical Materials, 112, pp.110757~ (2021), Elsevier BV[DOI]
  27. M. I. Sayyed, "Effect of TeO2 addition on the gamma radiation shielding competence and mechanical properties of boro-tellurite glass : an experimental approach", J. Mater. Res. Technol, 18, pp.1017~1027 (2022)[DOI]
  28. P. Vani, "Thulium-doped barium tellurite glasses: structural, thermal, linear, and non-linear optical investigations", Journal of Materials Science: Materials in Electronics, 32(18), pp.23030~23046 (2021), Springer Science and Business Media LLC[DOI]
  29. N. Kaur, "Structural characterization of borotellurite and aluminoborotellurite glasses", J. Non-Cryst. Solids, 404, pp.116~123 (2014)[DOI]
  30. Z. A. Said Mahraz, "Concentration dependent luminescence quenching of Er3þ-doped zinc boro-tellurite glass", J. Lumin, 144, pp.139~145 (2013)[DOI]
  31. K. A. Naseer, "Enhanced luminescence properties of Er3þ", Yb3þ doped zinc tellurofluoroborate glasses for 1.5 mm optical amplification, 2020, ~
  32. K. A. Naseer, "The impact of Er", Yb co-doping on the spectroscopic performance of bismuth borophosphate glasses for photonic applications, 2021, pp.183, 109788~
  33. K. Annapoorani, "Spectroscopic properties of Eu3þ ions doped Barium telluroborate glasses for red laser applications", J. Non-Cryst. Solids, 463, pp.148~157 (2017)[DOI]
  34. I. Kebaili, "Gamma-ray shielding parameters of lithium borotellurite glasses using Geant4 code", Appl. Phys. A, 126, pp.536~ (2020)[DOI]
  35. M. I. Sayyed, "Structural, thermal, optical features and shielding parameters investigations of optical glasses for gamma radiation shielding and defense applications", J. Non-Cryst. Solids, 487, pp.53~59 (2018)[DOI]
  36. G. Lakshminarayana, "Structural, thermal, and optical absorption studies of Er3+, Tm3+, and Pr3+-doped borotellurite glasses", Journal of Non-Crystalline Solids, 459, pp.150~159 (2017), Elsevier BV[DOI]
  37. Mridula Dogra, "Investigation of gamma ray shielding, structural and dissolution rate properties of Bi 2 O 3 -BaO-B 2 O 3 -Na 2 O glass system", Radiation Physics and Chemistry, 144, pp.171~179 (2018), Elsevier BV[DOI]
  38. B. T. Tonguc, "Studies on mass attenuation coefficients, effective atomic numbers and electron densities for some biomolecules", Radiat. Phys. Chem, 153, pp.86~91 (2018)[DOI]
  39. M. S. Al-Buriahi, "Mass attenuation coefficients, effective atomic numbers and electron densities of some contrast agents for computed tomography", Radiat. Phys. Chem, 166, pp.108507~ (2020)
  40. M. S. Al-Buriahi, "Micro-hardness and gamma-ray attenuation properties of lead iron phosphate glasses", J. Mater. Sci. Mater. Electron, 32, pp.13906~13916 (2021)[DOI]
  41. P. Evangelin Teresa, "Influence of modifiers on the physical, structural, elastic and radiation shielding competence of Dy3+ ions doped Alkali boro-tellurite glasses", Radiation Physics and Chemistry, 189, pp.109741~ (2021), Elsevier BV[DOI]
  42. P. Evangelin Teresa, "Optical properties and radiation shielding studies of europium doped modifier reliant multi former glasses", Optik, 247, pp.168005~ (2021), Elsevier BV[DOI]
  43. P. Evangelin Teresa, "Study on the luminescence behavior of Dy3+ ions activated, modifier dependent alkali boro-tellurite glasses for white LED application", Optik, 259, pp.169024~ (2022), Elsevier BV[DOI]
  44. P. Karthikeyan, "Luminescence studies on Dy 3+ doped calcium boro-tellurite glasses for White light applications", Physica B: Condensed Matter, 521, pp.347~354 (2017), Elsevier BV[DOI]
  45. M. N. Ami Hazlin, "Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion", Phys. B Condens. Matter, 510, pp.38~42 (2017)[DOI]
  46. S. Rada, "The local structure of europium–lead-borate glass ceramics", Journal of Molecular Structure, 924-926, pp.89~92 (2009), Elsevier BV[DOI]
  47. K. A. Naseer, "Impact of Bi2O3 modifier concentration on barium–zincborate glasses: physical, structural, elastic, and radiation-shielding properties", The European Physical Journal Plus, 136(1) (2021), Springer Science and Business Media LLC[DOI]
  48. P. Suthanthirakumar, "Effect of Pr3þ ions concentration on the spectroscopic properties of Zinc telluro-fluoroborate glasses for laser and optical amplifier applications", J. Lumin, 187, pp.392~402 (2017)[DOI]
  49. G. Sathiyapriya, "Structural, optical and nuclear radiation shielding properties of strontium barium borate glasses doped with dysprosium and niobium", J. Mater. Sci. Mater. Electron, 32, pp.8570~8592 (2021)[DOI]
  50. K.A. Naseer, "The concentration impact of Yb3+ on the bismuth boro-phosphate glasses: Physical, structural, optical, elastic, and radiation-shielding properties", Radiation Physics and Chemistry, 188, pp.109617~ (2021), Elsevier BV[DOI]
  51. V. Dimitrov, "Linear and nonlinear optical properties of simple oxides. II", J. Appl. Phys, 79, pp.1741~1745 (1996)[DOI]
  52. R. Reddy, "Optical electronegativity and refractive index of materials", Opt. Mater, 10, pp.95~100 (1998)[DOI]
  53. M. Kumar, "Synthesis, characterization and studies of radiative properties on Eu3þ-doped ZnAl2O4", J. Lumin, 132, pp.2810~2816 (2012)[DOI]
  54. S. Pravinraj, "Enhanced luminescence behaviour of Eu3þ doped heavy metal oxide telluroborate glasses for Laser and LED applications", Phys. B Condens. Matter, 509, pp.84~93 (2017)[DOI]
  55. K.A. Naseer, "Optical, elastic, and neutron shielding studies of Nb2O5 varied Dy3+ doped barium-borate glasses", Optik, 251, pp.168436~ (2022), Elsevier BV[DOI]
  56. W. T. Carnall, "Electronic energy levels of the trivalent lanthanide aquo ions. II. Gd3þ", J. Chem. Phys, 49, pp.4424~4442 (1968)[DOI]
  57. K.A. Naseer, "The impact of Er3+ ions on the spectroscopic scrutiny of Bismuth bariumtelluroborate glasses for display devices and 1.53 μm amplification", Journal of Non-Crystalline Solids, 520, pp.119463~ (2019), Elsevier BV[DOI]
  58. Erdem Şakar, "Phy-X", PSD: Development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry, 2020, pp.166, 108496~[DOI]

관련 논문AI추천

Role of Nd (III) ions on B2O3–TeO2-GeO2-MgO glass composition for optical and ionizing protection applicationHamad M. Kh, Kadhim Abed Jawad, Kaky Kawa M., Mahdi Rahman I., Mhareb M.H.A., Sayyed M.I.한국원자력학회 · Nuclear Engineering and Technology2025 · 제57권 제1호Influence of transition metals on the radiation shielding capability of Eu3+ ions doped telluro borophosphate glassesBassam S.A., El-Rehim A.F. Abd, Khandaker Mayeen Uddin, Mahmoud K.A., Naseer K.A., Sangeeth C.S. Suchand, Sayyed M.I.한국원자력학회 · Nuclear Engineering and Technology2025 · 제57권 제3호Impact of varying Bi2O3 content on physical, mechanical, structural and gamma ray shielding properties of Bi2O3-B2O3-SiO2-Na2O glass systemAlmuqrin Aljawhara H., Kumar Ashok, Sayyed M.I.한국원자력학회 · Nuclear Engineering and Technology2025 · 제57권 제10호Investigation of optical and radiation shielding properties in bismuth oxide-doped barium borate glassesAbouhaswa A.S., Alhakami Mohammad H., Althubiti Numa A., Taha Taha Abdel Mohaymen한국원자력학회 · Nuclear Engineering and Technology2025 · 제57권 제9호A closer look at the structure and gamma-ray shielding properties of newly designed boro -tellurite glasses reinforced by bismuth (III) oxideAbdullahi I., Hashim S., Ismail Abd Khamim, Mahmoud K.G., Sayyed M.I., Thabit Hammam Abdurabu, Yusof N.N.한국원자력학회 · Nuclear Engineering and Technology2023 · 제55권 제5호Dual-purpose borate based glasses: optical features and Monte Carlo simulations of gamma radiation shieldingBiradar Shrikant, Mahmoud K.A., Najam Laith Ahmed, Rilwan U., Sayyed M.I.한국원자력학회 · Nuclear Engineering and Technology2025 · 제57권 제11호

이 간행물의 다른 논문 (33건)

Development of a distributed high-speed data acquisition and monitoring system based on a special data packet format for HUST RF negative ion sourceZuo Chen, Chen Dezhi, Li Dong, Yin Ling, Wang Saipp. 3587-3594Optimization of preventive maintenance of nuclear safety-class DCS based on reliability modelingXu Biao, Zhang Xu, Peng Hao, Wang Yuanbing, Hu Qingrenpp. 3595-3603The development of EASI-based multi-path analysis code for nuclear security system with variability extensionSetiadipura Topan, Su'ud Zaki, Purqon Acep, Andiwijayakusuma Dinanpp. 3604-3613Measurement of the ICRH antenna phasing using antenna strap probe based diagnostic system in EAST tokamakLiang Q.C., Zhang X.J., Yang H., Yuan S., Mao Y.Z., Zhang W., Zhu G.H., Wang L., Qin C.M., Zhao Y.P., Cheng Y., Zhang K., Liu L.N.pp. 3614-3619Consistency check algorithm for validation and re-diagnosis to improve the accuracy of abnormality diagnosis in nuclear power plants이승준, 김근희, 김재민, 신지현pp. 3620-3630
원문 보기