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Experimental Study on CO2 Diffusivity in Cementitious Materials

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주제분류금속공학

초록

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

Abstract

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

참고문헌 (8)

  1. "Service Life of Structures with Regard to Corrosion of Embedded Steel Performance of Concrete in Marine Environment", pp.223~65 (1980)
  2. "Corrosion of steel in concrete report of the technical committee 60-CSC", pp.22~ (1988)
  3. "A carbonation prediction model for accelerated carbonation of concrete Magazine of Concrete Research", pp.191~ (1994)
  4. "Models for estimation of service life of concrete barriers in low-level radioactive waste disposal U. S. Department of Energy", pp.22~ (1990)
  5. "Physical and chemical characteristics affecting the durability of concrete", pp.186~ (1991)
  6. "The diffusion of carbon dioxide and oxygen in aerated concrete in Int. Coll. on Materials Science and Restoration", pp.629~ (1986)
  7. "Performance creteria for concrete durability", pp.5 22 231~ (1995)
  8. "Standard practice for maintaining constant relative humidity by means of aqueous solution", pp.~85 (1996)

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