Corrosion Protection Properties of Cobalt Salt for Water-Based Epoxy Coatings on 2024-T3 Aluminum Alloy
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In this paper, the efficiency and the inhibition mechanisms of cobalt salts (cobalt nitrate and cobalt-exchangesilica Co/Si) for the corrosion protection of AA2024 were investigated in a neutral aqueous solution byusing the electrochemical impedance spectroscopy (EIS) and polarization curves. The experimental measurementssuggest that cobalt cation plays a role as a cathodic inhibitor. The efficiency of cobalt cation was importantat the concentration range from 0.001 to 0.01 M. The formation of precipitates of oxides/hydroxides ofcobalt on the surface at low inhibitor concentration was confirmed by the Scanning Electron Microscopy/EnergyDispersive X-Ray Spectroscopy (SEM/EDS) analysis. EIS measurements were also conducted for the AA2024surface covered by water-based epoxy coating comprising Co/Si salt. The results obtained from exposurein the electrolyte demonstrated the improvement of the barrier and inhibition properties of the coating exposedin the electrolyte solution for a lengthy time. The SEM/EDS analysis in artificial scribes of the coatingafter salt spray testing revealed the release of cobalt cations in the coating defect to induce the barrierlayer on the exposed AA2024 substrate.
Abstract
In this paper, the efficiency and the inhibition mechanisms of cobalt salts (cobalt nitrate and cobalt-exchangesilica Co/Si) for the corrosion protection of AA2024 were investigated in a neutral aqueous solution byusing the electrochemical impedance spectroscopy (EIS) and polarization curves. The experimental measurementssuggest that cobalt cation plays a role as a cathodic inhibitor. The efficiency of cobalt cation was importantat the concentration range from 0.001 to 0.01 M. The formation of precipitates of oxides/hydroxides ofcobalt on the surface at low inhibitor concentration was confirmed by the Scanning Electron Microscopy/EnergyDispersive X-Ray Spectroscopy (SEM/EDS) analysis. EIS measurements were also conducted for the AA2024surface covered by water-based epoxy coating comprising Co/Si salt. The results obtained from exposurein the electrolyte demonstrated the improvement of the barrier and inhibition properties of the coating exposedin the electrolyte solution for a lengthy time. The SEM/EDS analysis in artificial scribes of the coatingafter salt spray testing revealed the release of cobalt cations in the coating defect to induce the barrierlayer on the exposed AA2024 substrate.
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