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한국연안이매패류에잔류하는PBDEs 및OCs에관한연구

A Study on Polybrominated Diphenyl Ethers and Organochlorine Compounds Residues Persistent in Korean Coastal Bivalves

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초록

Bivalve samples from 30 locations Korean coastal waters were analyzed to characterize the contamination with and distribution of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs). The congeners of PBDE in 30 bivalve samples were analyzed by high resolution gas chromatography with a high resolution mass detector. The levels of PBDEs in bivalve samples ranged from 0.092 to 13.5 ng/g wet weight. These values for PBDEs concentrations in bivalves from Korea were higher than or comparable to available values for bivalves from other countries. In the congener profiles, BDE-47 (mean contribution=42.2%) was predominant, followed by BDE-99 (23.1%), BDE-100 (11.9%) and BDE-154 (3.5%). Among the OCs analyzed, ΣPCBs and ΣDDTs levels were highest, followed by ΣHCHs, ΣCHLs and HCB. The wet weight based ΣPCBs and ΣDDTs ranged from 0.28 ng/g to 19.4 ng/g, and from 0.19 ng/g to 4.86 ng/g, respectively. The ΣPCBs and ΣDDTs levels in bivalves along the entire Korean coast were lower than those of the USA, and below the Food and Drug Administration (USA. FDA) limits for fish and shell fish. However, the human health criteria and wild life criteria of the USA. Environmental Protection Agency (USA. EPA) were exceeded for DDE and ΣHCHs at most of the sampling points.

Abstract

Bivalve samples from 30 locations Korean coastal waters were analyzed to characterize the contamination with and distribution of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs). The congeners of PBDE in 30 bivalve samples were analyzed by high resolution gas chromatography with a high resolution mass detector. The levels of PBDEs in bivalve samples ranged from 0.092 to 13.5 ng/g wet weight. These values for PBDEs concentrations in bivalves from Korea were higher than or comparable to available values for bivalves from other countries. In the congener profiles, BDE-47 (mean contribution=42.2%) was predominant, followed by BDE-99 (23.1%), BDE-100 (11.9%) and BDE-154 (3.5%). Among the OCs analyzed, ΣPCBs and ΣDDTs levels were highest, followed by ΣHCHs, ΣCHLs and HCB. The wet weight based ΣPCBs and ΣDDTs ranged from 0.28 ng/g to 19.4 ng/g, and from 0.19 ng/g to 4.86 ng/g, respectively. The ΣPCBs and ΣDDTs levels in bivalves along the entire Korean coast were lower than those of the USA, and below the Food and Drug Administration (USA. FDA) limits for fish and shell fish. However, the human health criteria and wild life criteria of the USA. Environmental Protection Agency (USA. EPA) were exceeded for DDE and ΣHCHs at most of the sampling points.

참고문헌 (33)

  1. Tanabe, S, "Mussel watch marine pollution monitoringof butyltins and organochlorines in coastal waters of Thailand, Philippines and India", Ocean Coastal Management, 43, pp.819~839 (2000)
  2. de Wit, C. A, "An overview of brominated flame retardants in the environment", Chemosphere, 46, pp.583~624 (2002)
  3. Branchi, I, "Effects of perinatal exposure to a polybrominated diphenyl ether (PBDE 99) on mouse neurobehavioural development", Neurotoxicology, 23, pp.375~384 (2002)
  4. "Bromine Science and Environmental Forum (BSEF) : An introuduction to brominated flame retardants", ~ (2001)
  5. Hong, S. H, "Nationwide monitoring of polychlorinated biphenyls and organochlorine pesticides in sediments from coastal environment of Korea", Chemosphere, 64, pp.1479~1488 (2006)
  6. Burreau, S, "Biomagnification of polychlorinated biphenyls (PCBs) and polychlorinated diphenyl ethers (PBDEs) studied in pike (Esox lucius), perch (Perca fluviatilis) and roach (Rutilus rutilus) from the Baltic Sea", Chemosphere, 55, pp.1043~1052 (2004)
  7. Johnson-Restrepo, B, "Polybrominated diphenyl ethers and polychlorinated biphenyls in a marine food web of coastal Florida", Environmental Science and Technology, 39, pp.8243~8250 (2005)
  8. Monirith, I, "Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries", Marine Pollution Bulletin, 46, pp.281~300 (2003)
  9. HRMS, "Brominted diphenyl ethers in water, soil,sediment, and tissue by HRGC", pp.2003, USEPA
  10. Nakamura, H, "Levels of polychlorinated dibenzo-p-dioxins, dibenzofurans, PCBs, DDTs and HCHs in human adipose tissue and breast milk from the south of Vietnam", Organohalogen Compounds, 21, pp.71~76 (1993)
  11. Bayen, S, "Occurrence of polychlorinated biphenyls and polybrominated diphenyl ether in green mussels (Perna viridis) from Singapore, Southeast Asia", Environmental Technology Chemistry, 22, pp.2432~2437 (2003)
  12. Liu, Y, "Polybrominated diphenyl ethers (PBDEs) in sediments and mussel tissues from Hong Kong marine waters", Marine Pollution Bulletin, 50, pp.1173~1184 (2003)
  13. Mai, B. X, "Distribution of polybrominated diphenyl ethers in sediments of the Pearl River Delta and adjacent South China Sea", Environmental Science andTechnology, 39, pp.3521~3527 (2005)
  14. Ohta, S, "Contamination levels of PBDEs, TBBPA, PCDDs", DFs and PXDDs, Organohalogen compounds, pp.2002, 57[DOI]
  15. Oros, D. R, "Levels and distribution of polybrominated diphenyl ethers in water, surface sediments, and bivalves from the San Francisco estuary", Environmental Science and Technology, 39, pp.33~41 (2005)
  16. Christensen, J. H, "Screening of polybrominated diphenyl ethers in blue mussels, marine and freshwater sediments in Denmark", Journal of Environment Monitoring, 3, pp.543~547 (2001)
  17. Bethune,C, "Current levels of primary polybrominated diphenyl ethers in Norwegian seafood", Organohalogen Compounds, 66, pp.3861~3866 (2004)
  18. "Korea Environment Institute (KEI) : International regulations and counterplans of brominated flame retardants" (2005), Korea Environment Institute
  19. Back, I. C, "Residueand Exposure Assessment of Polybrominated Diphenyl Ethers (PBDEs) in Breast Milk from Two Korea Regions", pp.168~172 (2008), Proceedings of Environmental Health in Asia-Pacific Region
  20. Kim, B. H, "Concentrations of polybrominated diphenyl ethers, polychlorinated dibenzo-pdioxins and dibenzofurans, and polychlorinated biphenyls in human blood samples from Korea", Science of the Total Environment, 336, pp.45~56 (2005)
  21. 여현구, "안성 지역 소나무 잎과 토양 중 PBDEs의 농도 수준 및 특성", 한국환경보건학회지, 32(2), pp.111~117 (2006), 한국환경보건학회
  22. We, S. U, "Polybrominated Diphenyl Ethers Contamination of Korea Food", pp.173~176 (2008), Proceedings of Environmental Health in Asia-Pacific Region
  23. Wang, X. M, "Polybrominated diphenyl ethers in airborne particulates collected during a research expedition from the Bohai Sea to the Arctic", Environmental Science and Technology, 39, pp.7803~7809 (2005)
  24. Hites, R. A, "Polybrominated diphenyl ethers in the environment and in people: A meta-analysis of concentrations", Environmental Science and Technology, 38, pp.945~956 (2004)
  25. Burreau, S, "Dietary uptake in pike (Esox lucius) of some polychlorinated biphenyls, polychlorinated naphthalenes and polybrominated diphenyl ethers administered in natural diet", Environmental Technology Chemistry, 16, pp.2508~2513 (1997)
  26. Qualitystatus report 2000, , OSPAR Commission, 41~63 (2000)
  27. Kannan,K, "Geographical distribution and accumulation and accumulation features of organochlorine residues in fish in trophical Asian and Oceania", Environment Science and Technology, 29, pp.2673~2683 (1995)
  28. Report of Working Group for the International Study of the pollution of the North Sea and its Effects on Living Resources and their Exploitation, "ICES", Cooparative Report Res, 191~, pp.39 (1974)
  29. Long, E. R, "Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments", Environmental Management, 19, pp.81~97 (1995)
  30. Richard, E. J, "DDT metabolism in microbial system", Residu Reviews, 61, pp.1~8 (1976)
  31. Aguilar, A, "Relationship of DDE", PDDT in marine mammals to the chronology of DDT input into the ecosystem, 1982, pp.41, 840~844
  32. Willett, K. L, "Differential toxicity and environmental fates of hexachlorocyclohexane isomers", Environmental Science and Technology, 32, pp.2197~2207 (1998)
  33. Shim, W. J, "Status and Historical Trend in the Accumulation of Toxic Chemicals in Masan-Chinhae Bay, Workshop on Ecosystem Management of interrelated River Basins", Estuaries and Coastal Sea, 26, pp.1~14 (2005)

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