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휴대용 XRF를 이용한 서울시 학교 내 어린이용품 중 일부 유해물질 함량 조사

Measurement of Hazardous Substances in Children’s Goods at Schools in Seoul

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Objectives: Excluding in their homes, children spend most of their time at an elementary school, daycare center, and/or kindergarten. For educational or recreational purposes, they make use of many children’s goods at these places. Some children’s goods contain phthalates and heavy metals with polyvinyl chloride (PVC), so due to their physiological and behavioral characteristics children are exposed to high concentrations of phthalates and heavy metals. This study aims to measure PVC and heavy metals, which are harmful substances in children’s goods which can have an effect on children’s health. Methods: Six samples of children’s goods were selected through cases of detected harmful substances and the results of previous research, including assembly blocks, model toys, household toys, bags, indoor play equipment, and floor mats. The selected items were measured using X-Ray Fluorescence (XRF), and the presence and content of environmentally harmful substances such as PVC or heavy metals in the materials of children's goods were examined. Results: The highest detection rate for PVC was observed in floor mats, and bags and indoor play equipment were higher than other goods in this regard. The highest detection rate for heavy metals was found in bags, followed by indoor play equipment, assembly blocks, household toys, model toys and floor mats. Except for bags containing heavy metals, five goods showed the highest level of Pb compared to other heavy metals. Floor mats contained the highest level of Pb, Cr, and Cu among all goods. Conclusion: Many children’s goods contain PVC and heavy metals, and high levels of heavy metals have been detected in some goods. It is necessary to manage children’s goods to support their health.

Abstract

Objectives: Excluding in their homes, children spend most of their time at an elementary school, daycare center, and/or kindergarten. For educational or recreational purposes, they make use of many children’s goods at these places. Some children’s goods contain phthalates and heavy metals with polyvinyl chloride (PVC), so due to their physiological and behavioral characteristics children are exposed to high concentrations of phthalates and heavy metals. This study aims to measure PVC and heavy metals, which are harmful substances in children’s goods which can have an effect on children’s health. Methods: Six samples of children’s goods were selected through cases of detected harmful substances and the results of previous research, including assembly blocks, model toys, household toys, bags, indoor play equipment, and floor mats. The selected items were measured using X-Ray Fluorescence (XRF), and the presence and content of environmentally harmful substances such as PVC or heavy metals in the materials of children's goods were examined. Results: The highest detection rate for PVC was observed in floor mats, and bags and indoor play equipment were higher than other goods in this regard. The highest detection rate for heavy metals was found in bags, followed by indoor play equipment, assembly blocks, household toys, model toys and floor mats. Except for bags containing heavy metals, five goods showed the highest level of Pb compared to other heavy metals. Floor mats contained the highest level of Pb, Cr, and Cu among all goods. Conclusion: Many children’s goods contain PVC and heavy metals, and high levels of heavy metals have been detected in some goods. It is necessary to manage children’s goods to support their health.

참고문헌 (16)

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  11. 최수정, "Bench-Top ED-XRF 및 휴대용 XRF를 이용한 토양 시료 중의 중금속 비교 분석", 분석과학, 22(4), pp.293~301 (2009), 한국분석과학회
  12. 김형진, "Portable XRF를 이용한 어린이 야외 놀이용품의 중금속 측정", 한국환경과학회지, 22(4), pp.471~479 (2013), 한국환경과학회[DOI]
  13. Gearhart J, "X-ray Fluorescence Spectroscopy as a public health screening tool for the presence of hazardous chemicals in plastics", Society of Plastics Engineers - Global Plastics Environmental Conference 2009 (2009)
  14. Sanders M, "for lead in toys at day care centers", Work, 44(Suppl 1), pp.S529~S538 (2013)
  15. Radu T, "Comparison of soil pollution concentrations determined using AAS and portable XRF techniques", J Hazard Mater, 171(1-3), pp.1168~1171 (2009)
  16. Allen JG, "Linking PBDEs in house dust to consumer products using X-ray fluorescence", Environ Sci Technol, 42(11), pp.4222~4228 (2008)

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