본문 바로가기
KERD
논문KCI 등재

Decay Resistance of the Acetylated Tropical Hardwood Species

1

조회

0

다운로드

0

인용

0

참고문헌

키워드

초록

Chemical modification of wood is an effective method to enhance the biological durability of wood with no toxic effect on the environment. In this study, wood of Triplochiton scleroxylon was modified using acetylation techniques. A total of one hundred wood blocks, (each 20×20×60 mm) obtained from a 22-year old T. scleroxylon tree were conditioned and acetylated at 120℃ in a bioreactor containing acetic anhydride for 60, 120, 180, 240 and 300 minutes. The percentage weight gain of acetylated wood was determined. The untreated (control) and treated blocks were exposed to Pleurotus ostreatus (white rot fungus) and Fibroporia vaillanti (brown rot fungus) after which moisture content (MC) and weight loss (WL) was monitored for 16 weeks. Data were analysed using descriptive and inferential statistics at p<0.05 level of significance. The percentage weight gain of acetylated wood samples increased with time from 10.4% (60 minutes) to 22.7% (300 minutes). MC of untreated blocks inoculated with Pleurotus ostreatus was significantly higher than those of Fibroporia vaillantii after 16 weeks exposure. There was no significant difference in the MC of the of the acetylated samples for the two fungi after 300 minutes reaction time. The WL of untreated blocks inoculated with Fibroporia vaillantii was higher than those of Pleurotus ostreatus, however, the two fungi showed no significant difference in the WL for the acetylated samples after 16 weeks exposure. Acetylation prevents moisture absorption and inhibition of fungi growth in acetylated wood compared to untreated wood, thereby enhancing the durability of Triplochiton scleroxylon.

Abstract

Chemical modification of wood is an effective method to enhance the biological durability of wood with no toxic effect on the environment. In this study, wood of Triplochiton scleroxylon was modified using acetylation techniques. A total of one hundred wood blocks, (each 20×20×60 mm) obtained from a 22-year old T. scleroxylon tree were conditioned and acetylated at 120℃ in a bioreactor containing acetic anhydride for 60, 120, 180, 240 and 300 minutes. The percentage weight gain of acetylated wood was determined. The untreated (control) and treated blocks were exposed to Pleurotus ostreatus (white rot fungus) and Fibroporia vaillanti (brown rot fungus) after which moisture content (MC) and weight loss (WL) was monitored for 16 weeks. Data were analysed using descriptive and inferential statistics at p<0.05 level of significance. The percentage weight gain of acetylated wood samples increased with time from 10.4% (60 minutes) to 22.7% (300 minutes). MC of untreated blocks inoculated with Pleurotus ostreatus was significantly higher than those of Fibroporia vaillantii after 16 weeks exposure. There was no significant difference in the MC of the of the acetylated samples for the two fungi after 300 minutes reaction time. The WL of untreated blocks inoculated with Fibroporia vaillantii was higher than those of Pleurotus ostreatus, however, the two fungi showed no significant difference in the WL for the acetylated samples after 16 weeks exposure. Acetylation prevents moisture absorption and inhibition of fungi growth in acetylated wood compared to untreated wood, thereby enhancing the durability of Triplochiton scleroxylon.

참고문헌 (36)

  1. Adegeye AO, "Antifungal Activities of Heart Wood Extract (HWE) of Teak Tectona grandis Against Two White Rots in Woods of Gmelina arborea and Triplochiton scleroxylon", Acad J Plant Sci, 2, pp.279~285 (2009)
  2. Adetogun AC, "The potentials of cashew nut shell liquid as a fungicide against wood decay", PhD, pp.1998
  3. Anagnost SE, "Hygroscopicity of decayed wood : implications for weight loss determination", Wood Fiber Sci, 29, pp.299~305 (1997)
  4. Anne-Marie T, "Dimensional stability and resistance to biological degradation of wood products by a simplified acetylation procedure", Proceedings, 4th International symposium of Wood and Pulping Chemistry, pp.125~129 (1987)
  5. Resistance of acetylated wood to basidiomycetes, softrot and blue stain, "Beckers EPJ", 11~, pp.No. IRG (1994), WP94-40021
  6. Blanco E, "Chemical Modification of Calophyllum brasiliense Cambess. and Enterolobium cyclocarpum (Jacq.) Griseb", Wood. Colomb For, 17, pp.125~132 (2014)
  7. Calonego FW, "Decay resistance of thermally-modified Eucalyptus grandis wood at 140 degrees C, 160 degrees C, 180 degrees C, 200 degrees C and 220 degrees C", Bioresour Technol, 101, pp.9391~9394 (2010)
  8. Chauhan SS, "Moisture adsorption behaviour of decayed rubber wood", J Institute Wood Sci, 19, pp.1~6 (2009)
  9. Comparative Biochemistry of the Decay of Sweetgum Sapwood by White-Rot and Brown-Rot Fungi, "Cowling EB", ~, pp.No. Technical Bulletin 1258 (1961)
  10. The effect of hemicellulose degradation on the mechanical properties of wood during brown rot decay, "Curling SF", ~, pp.No. IRG (2001), WP 01-20219
  11. An experimental method to simulate incipient decay of wood by basidiomycete fungi, "Curling S", ~, pp.No. IRG (2000), WP00-20200
  12. Eaton RA, "Wood: Decay, Pests, and Protection", pp.546~ (1993), Chapman & Hall
  13. Fojutowski A, "The effect of acetylation of alder, beech, birch and poplar wood on decay caused by Coniophora puteana fungus", For Wood Technol, 82, pp.273~277 (2013)
  14. Girotra K, "Process for Wood Acetylation and Product Thereof", WO2009095687, ~ (2009)
  15. Hill CAS, "Wood Modification: Chemical, Thermal and Other Processes" (2006), John Wiley & Sons
  16. Hill CAS, "An investigation of cell wall micropore blocking as a possible mechanism for the decay resistance of anhydride modified wood", Int Biodeterior Biodegrad, 55, pp.69~76 (2005)
  17. Manual for inspection of waterborne preservative treated timber products, "Lahiry AK.", ~, pp.No. IRG (2006), WP06-20322
  18. Lomelí-Ramírez MG, "Evaluation of accelerated decay of wood plastic composites by Xylophagus fungi", Int Biodeterior Biodegrad, 63, pp.1030~1035 (2009)
  19. Modification of solid wood: research and practical potential, "Militz H", ~, pp.No. IRG (1997), WP97-40098
  20. Mohebby B., "Biological attack of acetylated wood", PhD, pp.2003
  21. Mohebby B, "Application of ATR Infrared Spectroscopy in Wood Acetylation", J Agric Sci Technol, 10, pp.253~259 (2008)
  22. Neogi AN, "Methods Foresterifying Hydroxyl Groups in Wood", No. US7300705B2, ~ (2007)
  23. Norimoto M, "Wood and cellulosic chemistry", pp.573~598 (2001), Marcel Dekker
  24. Ogunsanwo OY, "Effect of Bark Extract of Erythrophleum suaveolens (Guillemin & Perrottet) Brenan on Fungal Activities in Wood of Triplochiton scleroxylon K. Schum", J Environ Ext, 9, pp.56~62 (2010)
  25. Ogunsanwo OY, "Specific gravity and shrinkage variation in plantation grown obeche (Triplochiton scleroxylon K. Schum)", J Trop For Res, 16, pp.39~45 (2000)
  26. Papadopoulos AN, "Chemical modification of solid wood and wood raw material for composites production with linear chain carboxylic acid anhydrides: a brief review", BioRes, 5, pp.499~506 (2010)
  27. Papadopoulos AN, "The biological effectiveness of wood modified with linear chain carboxylic acid anhydrides against Coniophora puteana", Holz als Roh-und Werkstoff, 60, pp.329~332 (2002)
  28. Pardo Sequeira T, "Evaluación del efecto de la concentración de anhídrido acético, temperatura y tiempo en la reacción de acetilación para la modificación química de Tectona grandis y Gmelina arborea", Master, pp.2013
  29. Peterson MD, "Protection of Wood from Decay Fungi by Acetylation-An Ultrastructural and Chemical Study", Wood Fiber, 10, pp.149~163 (1978)
  30. Rahman MR, "Wood Polymer Nanocomposites: Chemical Modifications, Properties and Sustainable Applications", pp.314~ (2018), Springer
  31. Rowell R, "Chemical Modification of Wood to Produce Stable and Durable Composites", Cellul Chem Technol, 46, pp.443~448 (2012)
  32. Sandberg D, "Wood modification technologies-a review", IForest, 10, pp.895~908 (2017)
  33. Sarker PK, "Standard Test Methods for Wood Preservatives by Laboratory Agar-Block Test", The International Research Group on Wood Protection (2006)
  34. Suttie ED, "Chemically modified solid wood. I. Resistance to fungal attack", Mater Org, 32, pp.159~182 (1998)
  35. Thomasson G, "Wood preservation and wood product treatment: A Training Manual of the University of Oregon" (1989), Extension and Station Communications
  36. Van Acker J, , Proceedings of the First European Conference on Wood Modification: ECWM 2003, pp.414~ (2003)

관련 논문AI추천

이 간행물의 다른 논문 (8건)