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Non-galvanic hydrogen production by water splitting using cermet membranes

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초록

The mixed ion-electron conducting Cu-cermet membranes are suggested for hydrogen production by water splitting at moderate temperature (873-1173oC) because of their good de-catalyzing carbon-formation reactions. The logarithmic hydrogen production rates with pH₂O in the oxidizing gas and with pH₂ in the reducing gas were investigated. Cu-based cermet membranes should be further studied to enhance their relatively poor thermal stability, with severe agglomerates of the Cu phase observed following operation at 1173K.

Abstract

The mixed ion-electron conducting Cu-cermet membranes are suggested for hydrogen production by water splitting at moderate temperature (873-1173oC) because of their good de-catalyzing carbon-formation reactions. The logarithmic hydrogen production rates with pH₂O in the oxidizing gas and with pH₂ in the reducing gas were investigated. Cu-based cermet membranes should be further studied to enhance their relatively poor thermal stability, with severe agglomerates of the Cu phase observed following operation at 1173K.

참고문헌 (4)

  1. U. Balachandran, , Fuel, 85(2), pp.150~155 (2006)
  2. U. Balachandran, , Inter. J. of Hydrogen Energy, 29, pp.291~296 (2004)
  3. U. Balachandran, , Inter. J. of Hydrogen Energy, 32, pp.451~456 (2007)
  4. S.-J. Song, , Chemistry Letters, 35(9), pp.1068~1069 (2006)

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