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Structural investigation and improvement of microwave dielectric properties in Ca1-xBaxTiO3, low loss ceramics

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초록

The effects of Ba substitution on the phase analysis, microstructure and microwave dielectric properties of Ca1-xBaxTiO3ceramics were prepared through conventional solid state reaction route. The X-ray diffraction analysis of the samples showedthat the specimens Ca1-xBaxTiO3 presented single phase compound with orthorhombic structure in the range of x=0.0 to 0.7when sintered at 1300oC for 3hrs in air. From the morphological point of view, it consists of round and rod shaped grains withporous microstructure. The substitution of Ba2+ ions over Ca2+, the microwave dielectric constant (εr) diminishes from 145 to52 whereas the quality factor (Qxf) will increases from 8105 to 24305 GHz and temperature coefficient of resonant frequencydecreases from 705 to 80 ppm/oC (at 3 GHz).

Abstract

The effects of Ba substitution on the phase analysis, microstructure and microwave dielectric properties of Ca1-xBaxTiO3ceramics were prepared through conventional solid state reaction route. The X-ray diffraction analysis of the samples showedthat the specimens Ca1-xBaxTiO3 presented single phase compound with orthorhombic structure in the range of x=0.0 to 0.7when sintered at 1300oC for 3hrs in air. From the morphological point of view, it consists of round and rod shaped grains withporous microstructure. The substitution of Ba2+ ions over Ca2+, the microwave dielectric constant (εr) diminishes from 145 to52 whereas the quality factor (Qxf) will increases from 8105 to 24305 GHz and temperature coefficient of resonant frequencydecreases from 705 to 80 ppm/oC (at 3 GHz).

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