본문 바로가기
KERD
논문KCI 등재

Controlling luminescent characteristics of ZASN glassceramics through tailored crystallization mechanism and processing

Seunggu Kang|Jihyeon Yun
청정에너지연구소 (Clean-Energy Research Institute)|2024.08|Journal of Ceramic Processing Research|제25권 제4호|pp. 475-482|DOI 10.36410/jcpr.2024.25.4.475

2

조회

0

다운로드

0

인용

0

참고문헌

키워드

PhotoluminescenceGlass-ceramicsWillemiteZASN systemCrystallization mechanism
주제분류재료공학

초록

The ZnO-Al2O3-SiO2-Na2O (ZASN) system glass was fabricated and heat-treated to produce glass-ceramics specimenscontaining willemite (Zn2SiO4). The obtained glass revealed the presence of minor phase-separated droplets, each tens ofnanometers in size, serving as nuclei for crystal growth and enabling a direct one-step heat treatment process without theneed for a separate nucleation step. The activation energy (E) for crystallization was calculated from DTA data using theKissinger equation. The resulting Avrami constant (n) was found to be 1.49 when substituted E into the Augis-Bennettequation, indicating surface nucleation, which suggests that controlling the size and distribution of droplets could enhancethe properties of glass-ceramics through induced internal crystallization. Photoluminescence (PL) properties revealed broademission peaks attributed to Zn2+ ions with d10 electronic configuration. CIE color coordinate of glass-ceramics treatedwithin 10 minutes shifted towards darker blue hues with time; exceeding 1 hour shifted towards cyan. The controllability ofcrystallization mechanism and heat treatment process in ZASN glass, along with fine adjustability of luminescent properties,suggests potential for applications in cyan-green luminescent materials.

Abstract

The ZnO-Al2O3-SiO2-Na2O (ZASN) system glass was fabricated and heat-treated to produce glass-ceramics specimenscontaining willemite (Zn2SiO4). The obtained glass revealed the presence of minor phase-separated droplets, each tens ofnanometers in size, serving as nuclei for crystal growth and enabling a direct one-step heat treatment process without theneed for a separate nucleation step. The activation energy (E) for crystallization was calculated from DTA data using theKissinger equation. The resulting Avrami constant (n) was found to be 1.49 when substituted E into the Augis-Bennettequation, indicating surface nucleation, which suggests that controlling the size and distribution of droplets could enhancethe properties of glass-ceramics through induced internal crystallization. Photoluminescence (PL) properties revealed broademission peaks attributed to Zn2+ ions with d10 electronic configuration. CIE color coordinate of glass-ceramics treatedwithin 10 minutes shifted towards darker blue hues with time; exceeding 1 hour shifted towards cyan. The controllability ofcrystallization mechanism and heat treatment process in ZASN glass, along with fine adjustability of luminescent properties,suggests potential for applications in cyan-green luminescent materials.

참고문헌 (48)

  1. G. -H. Chen, , J. Alloys Compd, 431(1-2), pp.282~286 (2007)
  2. K. A. Almasri, , Results Phys, 7, pp.2242~2247 (2017)
  3. H. Lin, , Laser Photonics Rev, 12, pp.1700344~ (2018)
  4. A. S. Rao, , J. Alloys Compd, 712, pp.672~686 (2017)
  5. F. Pei, , Ceram. Int, 46(11), pp.17825~17835 (2020)
  6. Z. Tong, , J. Ceram. Process. Res, 24(1), pp.17~28 (2023)
  7. N. Kawaguchi, , J. Ceram. Process. Res, 20(5), pp.455~459 (2019)
  8. D. Shiratori, , J. Ceram. Process. Res, 20(4), pp.301~306 (2019)
  9. M. H. M. Zaid, , J. Mater. Sci. Mater. Electron, 27, pp.11158~11167 (2016)
  10. A. M. Hu, , Thermochim Acta, 437(1-2), pp.110~113 (2005)
  11. H. Gui, , J. Eur. Ceram. Soc, 39(4), pp.1397~1410 (2019)
  12. S. A. A. Wahab, , J. Mater. Res. Technol, 9(5), pp.11013~11021 (2020)
  13. J. Hrabovsky, , J. Non. Cryst. Solids, 582, pp.121445~ (2022)
  14. Q. Zhang, , J. Ceram. Process. Res, 22(1), pp.8~15 (2021)
  15. R. Li, , J. Ceram. Process. Res, 21(1), pp.86~91 (2020)
  16. M. Takesue, , Prog. Cryst. Growth Charact. Mater, 55(3-4), pp.98~124 (2009)
  17. S. M. Abo-Naf, , Nano-Structures &Nano-Objects, 26, pp.100685~ (2021)
  18. S. A. M. Abdel-Hameed, , Optik, 206, pp.164374~ (2020)
  19. H. W. Leverenz, , Science, 109(2826), pp.183~195 (1949)
  20. G. R. Fonda, , J. Phys. Chem, 44(7), pp.851~861 (1940)
  21. M. T. Tsai, , Mater. Sci. Eng, 18, pp.032026~ (2011)
  22. A. Zatsepin, , Phys. Status Solidi B, 253(11), pp.2180~2184 (2016)
  23. C. E. Rivera-Enríquez, , J. Alloys Compd, 688, pp.775~782 (2016)
  24. M. H. M. Zaid, , J. Spectrosc, 2016, pp.8084301~ (2016)
  25. A. Tarafder, , Opt. Mater, 36(9), pp.1463~1470 (2014)
  26. N. Effendy, , Optik, 127(24), pp.11698~11705 (2016)
  27. V. Lojpur, , Appl. Phys. Lett, 103, pp.141912~ (2013)
  28. P. Yang, , Inorg. Chem. Commun, 7(2), pp.268~270 (2004)
  29. R. Ye, , J. Alloys Compd, 566, pp.73~77 (2013)
  30. T. Sakamoto, , J. Ceram. Process. Res, 14, pp.s64~s66 (2013)
  31. J. H. Zeng, , Mater. Res. Bull, 44(5), pp.1106~1110 (2009)
  32. X. Ouyang, , J. Appl. Phys, 79, pp.3229~3234 (1996)
  33. T. F. Veremeichik, , Crystallogr. Rep, 48(6), pp.974~988 (2003)
  34. T. J. Lou, , J. Colloid Interface Sci, 314(2), pp.510~513 (2007)
  35. N. F. Samsudin, , J. Spectrosc, pp.730753~ (2015)
  36. N. F. Samsudin, , Appl. Opt, 55(9), pp.2182~2187 (2016)
  37. B. C. Babu, , J. Mol. Struct, 1127, pp.6~14 (2017)
  38. K. M. Knowles, , J. Microsc, 215, pp.257~270 (2004)
  39. J. Partyka, , Ceram. Int, 42(7), pp.8513~8524 (2016)
  40. S. K. Jung, , J. Ceram. Process. Res, 16(5), pp.525~530 (2015)
  41. R. Casasola, , J. Mater. Sci, 47, pp.553~582 (2012)
  42. M. Li, , J. Ceram. Process. Res, 22(5), pp.504~509 (2021)
  43. H. W. Choi, , Phys. Chem. Chem. Phys, 15, pp.9940~ (2013)
  44. S. Saraswat, , J. Mater. Res. Technol, 5(2), pp.111~116 (2016)
  45. S. M. Son, , Ceram. Int, 49(9), pp.13677~13686 (2023)
  46. J. A. Augis, , J. Therm. Anal, 13, pp.283~292 (1978)
  47. Y. H. Na, , J. Ceram. Process. Res, 10(2), pp.230~234 (2009)
  48. Y. W. Lu, , J. Appl. Phys, 100, pp.063512~ (2006)

이 간행물의 다른 논문 (25건)

Mechanical properties of silicon carbide/graphene nanoplatelets composites prepared by spark plasma sinteringHai Wanxiu, Qi Wubin, Liu Limeng, Chen Yuhong, Zhang Xiuling, Hong Tianxiang, Xue Minpp. 483-489Quasi-nanocrystalline ZrB2 powder synthesized by saltassisted combustion and its formation mechanismShipeng Xu, Hua Zhang, Min Zhu, Yuehong Zheng, Peiqing La, Ru Bai, Faqi Zhan, Xiao Liu, Ke Xu, Jie Shengpp. 490-498Electric discharge machining of AA7075/SiCp/B4Cp hybrid composites under Cu mixed used engine oil dielectric mediumShabarinathan K.T., Senthilkumar K., Udhaya Chandran R.M., Mylsamy K.pp. 499-511Micropore controlled ceramic filter with mullite whiskers for filtering non-exhaust particulate matter from road transportJung-Hun Choi, Kyu-Sung Han, Kwang-Taek Hwang, Jong-Han Choi, Seung-Hwa Oh, Jin-Ho Kim, Taeseup Songpp. 512-520Flexural and durability performance of alkaline resistance glass fiber and basalt fiber in fiber reinforced concreteS. Christian Johnson, R. Murugesan, D. Mythilipp. 521-528
원문 보기