Synthesis, crystal structure, and near-infrared reflective properties of ZnSxSe1-x nanopigments
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In this research, a series of near-infrared (NIR) reflecting nanopigments, based on ZnSxSe1-x (x = 1, 0.75, 0.55, and 0.35), havebeen synthesized via a coprecipitation reaction and subsequent calcination. Furthermore, their crystal structure, particlemorphology, chromatic properties, and NIR reflectance have been investigated in detail; the results show that ZnSxSe1-xpigments have a cubic zinc-blende structure with a space group of F-43m(216), and the pigments’ microstructure presents theagglomerates composed of the spherical particles of different nanosizes. ZnSxSe1-x pigments exhibit not only colors rangingfrom ivory white to bright yellow but also significant NIR solar reflectance, ranging from 80.96% to 86.65%.
Abstract
In this research, a series of near-infrared (NIR) reflecting nanopigments, based on ZnSxSe1-x (x = 1, 0.75, 0.55, and 0.35), havebeen synthesized via a coprecipitation reaction and subsequent calcination. Furthermore, their crystal structure, particlemorphology, chromatic properties, and NIR reflectance have been investigated in detail; the results show that ZnSxSe1-xpigments have a cubic zinc-blende structure with a space group of F-43m(216), and the pigments’ microstructure presents theagglomerates composed of the spherical particles of different nanosizes. ZnSxSe1-x pigments exhibit not only colors rangingfrom ivory white to bright yellow but also significant NIR solar reflectance, ranging from 80.96% to 86.65%.
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