Effect of ethylene glycol on the synthesis of crystalline boron carbide powder from condensed boric-acid-glycerin precursor
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The effect of addition of ethylene glycol (C2H6O2) on the synthesis of crystalline boron carbide (B4C) powder from a condensedboric acid (H3BO3)-glycerin (C3H8O3) product was investigated. Equal molar amount of H3BO3 and glycerin was mixed andsubjected to dehydration-condensation reaction using various amount of ethylene glycol (0 to 40 mol% based on glycerolamount). Then the condensed product was thermally decomposed in air twice to obtain surface carbon-free precursor powder. The crystalline phases and surface functional groups of the material was characterized using XRD, SEM, FTIR and TGA. Addition of ethylene glycol offered a new organic sites and comparatively, reduced pyrolysis temperature from 700 to 650 oC. The complete formation of crystalline B4C powder was achieved at 1475 oC within 2.5 h, which is among the shortest timereported for B4C synthesis
Abstract
The effect of addition of ethylene glycol (C2H6O2) on the synthesis of crystalline boron carbide (B4C) powder from a condensedboric acid (H3BO3)-glycerin (C3H8O3) product was investigated. Equal molar amount of H3BO3 and glycerin was mixed andsubjected to dehydration-condensation reaction using various amount of ethylene glycol (0 to 40 mol% based on glycerolamount). Then the condensed product was thermally decomposed in air twice to obtain surface carbon-free precursor powder. The crystalline phases and surface functional groups of the material was characterized using XRD, SEM, FTIR and TGA. Addition of ethylene glycol offered a new organic sites and comparatively, reduced pyrolysis temperature from 700 to 650 oC. The complete formation of crystalline B4C powder was achieved at 1475 oC within 2.5 h, which is among the shortest timereported for B4C synthesis
참고문헌 (25)
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