Analysis of the surface characteristics of SiO2-Al2O3-CaOZnO-Na2O-based glass at heat-treatment temperature using Raman spectroscopy
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In this study, the change in surface properties based on the heat-treatment temperature of SiO2-Al2O3-CaO-ZnO-Na2O systemglass was analyzed using Raman spectroscopy. Viscosity prediction for each temperature was also conducted throughthe Vogel–Fulcher–Tammann model using differential thermal analysis and the temperatures (Tg, TS, T1/2) representing thethermal properties observed under hot-stage microscopy. The surface roughness, hardness, and glossiness of the glass wereanalyzed according to the heat-treatment temperature. Raman spectra measured at 800-1300 cm-1 were deconvolved to observethe area and peak position changes of Qn (n = 1-4) units in terms of melt viscosity and polymerization, and the studyconfirmed that the polymerization degree of the heat treated glass was the lowest at 1120 °C. Results showed that the averageroughness of the glass heat-treated at 1120 ℃ for 90 min was the lowest (53.07 nm), and the hardness was the highest at 6.73GPa.
Abstract
In this study, the change in surface properties based on the heat-treatment temperature of SiO2-Al2O3-CaO-ZnO-Na2O systemglass was analyzed using Raman spectroscopy. Viscosity prediction for each temperature was also conducted throughthe Vogel–Fulcher–Tammann model using differential thermal analysis and the temperatures (Tg, TS, T1/2) representing thethermal properties observed under hot-stage microscopy. The surface roughness, hardness, and glossiness of the glass wereanalyzed according to the heat-treatment temperature. Raman spectra measured at 800-1300 cm-1 were deconvolved to observethe area and peak position changes of Qn (n = 1-4) units in terms of melt viscosity and polymerization, and the studyconfirmed that the polymerization degree of the heat treated glass was the lowest at 1120 °C. Results showed that the averageroughness of the glass heat-treated at 1120 ℃ for 90 min was the lowest (53.07 nm), and the hardness was the highest at 6.73GPa.
참고문헌 (34)
- S. English, , J. Am. Ceram. Soc, 10, pp.551~560 (1927)
- D. U. Tulyaganov, , J. Eur. Ceram. Soc, 27(2-3), pp.1665~1670 (2007)
- Neslihan Tamsu Selli, "Effect of (MgO", CaO) molar ratio on glassy phase viscosity and pyroplastic deformation in floor tiles, 2020, pp.21(6), 632~639[DOI]
- Jae Uk Hur, "Manufacture of rapid SiC heating element and increased durability through glass frit coating", Journal of Ceramic Processing Research, 21(2), pp.213~216 (2020), 청정에너지연구소[DOI]
- G. Kaya, "Characterization of diopside-based glass-ceramic porcelain tile glazes containing borax solid wastes", Journal of Ceramic Processing Research, 12(2), pp.135~139 (2011), 청정에너지연구소[DOI]
- W. Holand, "Glass-ceramic technology" (2019), John Wiley & Sons
- R. A. Eppler, "Glazes and glass coatings" (2000), American Ceramic Society
- R.K. Brow, "Inorganic glasses and glass-ceramics chapter 6 in characterization of ceramics", pp.103~118 (1993), Butterworth-Heinemann
- Rafika Souag, "TiO2 addition into nuclear glass ceramic: Study of the crystalline phases, structure and chemical durability", Journal of Ceramic Processing Research, 23(3), pp.304~311 (2022), 청정에너지연구소[DOI]
- Dagyeong Lee, "Effect of MgO-CaO-Al2O3-SiO2 glass additive on densification of Al2O3 ceramics", Journal of Ceramic Processing Research, 23(2), pp.149~153 (2022), 청정에너지연구소[DOI]
- L. Deng, , Mater. Chem. Phys, 240, pp.122~212 (2020)
- J. Cheng, , Ceram. Int, 39(4), pp.4055~4062 (2013)
- Y.T. Huang, "Kinematic behavior of melted glass for hot-extrusion", Journal of Ceramic Processing Research, 22(3), pp.264~275 (2021), 청정에너지연구소[DOI]
- M. G. Rasteiro, , Ceram. Int, 33(3), pp.345~354 (2007)
- J. R. Taylor, "Ceramics glaze technology" (1986), Institute of Ceramics by Pergamon Press
- D. S. Sanditov, , Glass Phys. Chem, 36, pp.41~44 (2010)
- J. H. Park, , ISIJ Int, 52(9), pp.1627~1636 (2012)
- P. Colomban, , J. Raman. Spectrosc, 37, pp.841~852 (2006)
- D. H. Vogel, , Z. Phys, 22, pp.645~ (1921)
- G. S. Fulcher, , J. Am. Ceram. Soc, 8, pp.339~355 (1925)
- G. Tammann, , Z Anorg Allg Chem, 156, pp.245~257 (1926)
- F. Magrini, , Ceram. Inf, 171, pp.391~398 (1979)
- M. Leśniak, , J. Therm. Anal. Calorim, 128, pp.1343~1351 (2017)
- E. Neves, , Quim Nova, 21(4), pp.534~537 (1998)
- M. Wang, , Phys. B, 406(20), pp.3865~3869 (2011)
- J. Cheng, , Ceram. Int, 39(4), pp.4055~4062 (2013)
- J. A. Frenkel, , J. Phys. (USS R), 9(5), pp.385~ (1945)
- J. K. Mackenzie, , Proc. Phys. Soc. B, 62, pp.833~ (1949)
- I. Kansal, , Acta Biomater, 6(11), pp.4380~4388 (2010)
- C. P. Martendal, , J. Therm. Anal. Calorim, 130, pp.1903~1912 (2017)
- J. Marchi, , J. Non-cryst. Solids, 351(10-11), pp.863~868 (2005)
- N. Umesaki, , J. Non-cryst. Solids, 205, pp.225~230 (1996)
- W. Guo, , Ceramics Int, 48(18), pp.25933~25939 (2022)
- L. Chen, , Procedia CIRP, 8, pp.334~339 (2013)