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RPF 열분해 가스화시 합성가스 조성에 대한 화학평형 계산

An Equilibrium Analysis to Generate Syngas in the Pyrolysis and Gasification of Refuse Plastic Fuel

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Abstract

The aim of this study is to find out the condition that generates maximum H2 through the calculation of equilibrium model with conditions of pyrolysis gases of Refuse Plastic Fuel(RPF). This study deals with the computational simulation of a RPF gasification using an equilibrium model based on minimization of the Gibbs free energy. An equilibrium analysis was carried out to determine species composition of Syngas in RPF gasification and reactions to variation of temperature, O2/Fuel ratio and Steam/Fuel ratio. Calculated results shows that hydrocarbons in pyrolyzed gas are converted to synthesis gas which is formed on hydrogen and carbon monoxide.

참고문헌 (9)

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  2. "A Study on Development of a Pyrolysis Characteristic for Combustible Ocean Waste", 15(2), pp.103~134 (2001)
  3. "Chemical and Mineralogical evaluation of slag products derived from the pyrolysis", melting treatment of MSW, 2006, pp.26(12), 1443~1452
  4. "Carbonization of Municipal Wastes", pp.617~620 (2003)
  5. "Hydrogen rich fuel gas production from the pyrolysis of wet sewage sludge at high temperature", pp.127~132 (2006)
  6. "Hydrogen production from sewage sludge via a fixed bed gasifier product gas", 27, pp.1035~1041 (2002)
  7. "An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine", 19(12), pp.3372~3381 (1995)
  8. "Kinetic study in modeling pyrolysis of refuse plastic fuel", 21, pp.1442~1447 (2007)
  9. "Thermodynamic analysis of hydrogen production by partial oxidation reforming", 29, pp.809~816 (2004)

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