Comparison of the Chemical Reactivity between Sulfuric and Methanesulfonic Acids as a Leaching Agent
1
조회
0
다운로드
2
인용
0
참고문헌
키워드
초록
Methanesulfonic acid (MSA) can be considered effective in the leaching of metals because of its advantageous physical and chemical properties. The chemical reactivities of MSA and sulfuric acid were compared based on their structures and the dissolution data of Co and Ni metal. The inductive and resonance effects play a vital role in the chemical reactivities of these two acids. The dissolution percentages of Co and Ni in the sulfuric acid solution were higher than those in the MSA solution under the same experimental conditions. Considering the strong acidity of MSA and the high solubility of its metal salts, MSA can be employed as a leaching agent for the recovery of metals.
Abstract
Methanesulfonic acid (MSA) can be considered effective in the leaching of metals because of its advantageous physical and chemical properties. The chemical reactivities of MSA and sulfuric acid were compared based on their structures and the dissolution data of Co and Ni metal. The inductive and resonance effects play a vital role in the chemical reactivities of these two acids. The dissolution percentages of Co and Ni in the sulfuric acid solution were higher than those in the MSA solution under the same experimental conditions. Considering the strong acidity of MSA and the high solubility of its metal salts, MSA can be employed as a leaching agent for the recovery of metals.
참고문헌 (24)
- Wang, S., "Aqueous lixiviants: principle, types, and applications", JOM, 59, pp.37~42 (2007)
- Li, Y., "A review of the structure, and fundamental mechanisms and kinetics of the leaching of chalcopyrite", Advances in Colloid and Interface Science, 197-198, pp.1~32 (2013)
- Hackl, R., "Passivation of chalcopyrite during oxidative leaching in sulfate media", Hydrometallurgy, 39, pp.25~48 (1995)
- Klauber, C., "A critical review of the surface chemistry of acidic ferric sulphate dissolution of chalcopyrite with regards to hindered dissolution", Int. J. Miner. Process, 86, pp.1~17 (2008)
- Watling, H.R., "Chalcopyrite hydrometallurgy at atmospheric pressure : 2. Review of acidic chloride process options", Hydrometallurgy, 146, pp.96~110 (2014)
- Zarate-Gutierrez, R., "Aqueous oxidation of galena and pyrite with nitric acid at moderate temperatures", Hydrometallurgy, 115, pp.57~63 (2012)
- Aydogan, S., "Kinetics of galena dissolution in nitric acid solutions with hydrogen peroxide", Hydrometallurgy, 88, pp.52~57 (2007)
- Cho, K., "Recovery of gold from the refractory gold concentrate using microwave assisted leaching", Metals, 10, pp.571~ (2020)
- Florence, F., "Studies on electrodeposition of copper from methanesulphonic acid bath", International Journal of ChemTech Research, 3, pp.1318~1325 (2011)
- Kulkarni, P., "Methanesulphonic acid is green catalyst in organic synthesis", Oriental Journal of Chemistry, 31, pp.447~451 (2015)
- Gora, M., "Solventfree condensations of ketones with malononitrile catalyzed by methanesulfonic acid", morpholine system, 2009, pp.11, 863~867
- Palden, T., "Methanesulfonic acid: a sustainable acidic solvent for recovering metals from jarosite residue of the zinc industry", Green Chemistry (2019)
- Ahn, J., "Investigation on chalcopyrite leaching with methanesulfonic acid(MSA)and hydrogen peroxide", Hydrometallurgy, 187, pp.54~62 (2019)
- Gernon, M. D., "Environmental benefits of methanesulfonic acid", Green Chemistry, 1, pp.127~140 (1999)
- Finsgar, M., "Corrosion behaviour of stainless steels in aqueous solutions of methanesulfonic acid", Corros. Sci, 52, pp.2430~2438 (2010)
- Tran, T.T., "Separation of cobalt, nickel, and copper from synthetic metallic alloys by selective dissolution with acid solutions containing oxidizing agent", Mineral Processing and Extractive Metallurgy Review (2020)
- Patai, S., "The Chemistry of Sulphonic Acids, Esters and their Derivatives", pp.251~ (1991), John Wiley and Sons
- Sippola, H., "Thermodynamic Properties of Aqueous Sulfuric Acid", Journal of Chemical & Engineering Data, 59, pp.2389~2407 (2014)
- Lynch, K., "Why is sulfuric acid a much stronger acid than ethanol? Determination of the contributions by inductive", field effects and electron-delocalization effects, 2015, pp.17, 138~144
- Feng, Q., "Dissolution regularities of smithsonite in methane sulfonic acid", Russian Journal of Non-Ferrous Metals, 56, pp.365~371 (2015)
- Feng, Q., "Leaching of copper from malachite with methane sulfonic acid", Solvent Extraction Research and Development, Japan, 22, pp.159~168 (2015)
- Hidalgo, T., "Kinetic study of chalcopyrite dissolution with iron(III)chloride in methanesulfonic acid", Minerals Engineering, 125, pp.66~74 (2018)
- Zhang Q., "Dissolution kinetics of hemimorphite in methane sulfonic acid", Physicochem. Probl. Miner. Process, 55, pp.1~9 (2019)
- Gijsemans, L., "Recovery of rare earths from the green lamp phosphor LaPO4:Ce3+, Tb3+ (LAP) by dissolution in concentrated methanesulphonic acid", RSC Advances, 8, pp.26349~26355 (2018)
