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鹽酸溶液에서 PC88A와 비누화 PC88A에 의한 Gd와 Nd의 分離抽出

Solvent Extraction for the Separation of Gd and Nd from ChlorideSolution with PC88A and Saponified PC88A

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참고문헌

키워드

주제분류자원공학

초록

Gd와 Nd올 혼합된 염산용액에서 PC88A와 비누화 PC88A에 의한 용매추출실험을 ??佩??. 쉠 敗교彭벧 빔ム?? 쑹ヨ」累彭벧 PC88A에 의해 Gd올 Nd보다 추출이 ? 뎃炎엿냇, 40% 비누화된 PC88A를 ょ幅??沛 Gd와 Nd의 분배계수가 증가하였다. PC88A와 비누화 PC88Aø° 의한 ?扱압 초기추출조건으로부터 Gd¿ Nd¿ 분배계수를 遍崎“ ?? 웍? 모델을 ????佩??. ½ª 敗교彭벧 ??돐 놈뎌역 旣기?扱」累彭 웝幅??沛 ø¼Ðø Gdø Nd엮 ½¼羸빔? 쑹ヨ엿?? Ðø¡§ ?? 벧?? ? ¿œ?갓?佩??.

Abstract

Solvent extraction experiments have been performed to separate Gd and Nd from chloride solution with PC88A and saponified PC88A. In the experimental ranges conducted in this study, the extraction percentage of Gd was higher than that of Nd. Use of 40% saponified PC88A increased the distribution coefficients of Gd and Nd. A chemical model was developed to predict the distribution coefficients of the two metals from the initial extraction conditions. The measured distribution coefficients of Gd and Nd with PC88A and saponified PC88A agreed well with those calculated in this study.

참고문헌 (10)

  1. 이만승, "鹽酸溶液에서 PC88A에 의한 Nd의 溶媒抽出", 자원리싸이클링, 13(4), pp.39~45 (2004), 한국자원리싸이클링학회
  2. 이만승, "염산용액에서 PC88A에 의한 Sm의 용매추출", 대한금속·재료학회지, 42(10), pp.829~834 (2004), 대한금속ㆍ재료학회
  3. Abdeltawab, A.A., "Separation of La and Ce with PC-88A by counter-current mixer-settler extraction column", Separation and Purification Technology, 26(2), pp.265~272 (2002)
  4. Devi, N.B., "Separation and recovery of cobalt(II) and nickel(II) from sulphate solutions using sodium salts of D2EHPA, PC 88A and Cyanex 272", Hydrometallurgy, 49(1), pp.47~61 (1998)
  5. Sarangi, K., "Extraction studies of cobalt (II) and nickel (II) from chloride solutions using Na-Cyanex 272.: Separation of Co(II)", Ni(II) by the sodium salts of D2EHPA, PC88A and Cyanex 272 and their mixtures, 1999, pp.52(3), 253~265
  6. Devi, N.B., "Separation of divalent manganese and cobalt ions from sulphate solutions using sodium salts of D2EHPA, PC 88A and Cyanex 272", Hydrometallurgy, 54(2), pp.117~131
  7. 안종관, "고농도 니켈 꺹扱緣엿쾶퐣不 Na-PC88A에 의한 Co, Mn 솩 Zn엮 퐭냔彭 臨쳴 敗교", J. Kor. Inst. Met. & Mater, 39(12), pp.1455~1460 (2001)
  8. 이만승, "쏟ⅸ빴 PC88A彭 의한 NdCl3와 SmCl3 幅넷 ?扱엮 빴쳳놈뎌, ¥ë«—±›º”", 욜꿍쳳뺙죭, 42(10), pp.835~840 (2004)
  9. Wang, D.J., "Mechanism of the extractant loss in lanthanide extraction process with saponified organo-phosphorus acid extraction systems- II: Formation of aqueous aggregates", Solvent extraction and ion exchange, 14(4), pp.585~601 (1996)
  10. Bromley, L.A., "Thermodynamic properties of strong electrolytes in aqueous solutions", AIChE Journal, 19(2), pp.313~320 (1973)

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