전처리 공정에 따른 폐타이어 재생 고무분말의 특성연구
A study on the Characteristic of Waste Ground Rubber Tire Powders with Pre-treatment Process for Recycling
1
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
본 연구는 폐타이어 재활용을 위하여 수행된 전처리 공정이 재생 고무분말의 기계적 물성에 미치는 영향을 조사하는 것을 목적으로 하였다. 이를 위하여 분쇄 및 탈황공정을 통하여 생산된 폐타이어 고무분말을 재가황한 후 인장시험, 충격시험 및 파단면 관찰을 수행하였다. 분쇄 공정을 거쳐서 생산된 고무분말은 입자크기가 작아질수록 그 표면적이 증가되며 인장강도와 연신율이 모두증가되었다. 반면에 탈황공정을 거친 고무분말은 내부에 존재하는 황과의 가교결합이 줄어들어서 이후의 가황처리 후에도 인장강도와 연신율이 모두 증가되었다. 따라서 폐타이어 재활용을 위한 전처리 공정은 재활용 분말을 일정크기로 분쇄한 후 탈황공정까지를수행한 고무분말을 제조하는
Abstract
In this study, mechanical properties of waste ground rubber tire powder were investigated to evaluate the influence of pretreatment process for recycling. The tensile test, fracture test and morphology observation were carried out using various kinds of waste ground tire powders, which were produced by grinding and devulcanization process, respectively. As a results, it was found that the produced rubber powder through grinding process increased its tensile strength and elongation with decreasing particle size because of decreasing surface area. Devulcanized rubber powder also increased its tensile strength and elongation by de-crosslink with sulfur. It could be also suggested that devulcanization treatment after grinding process was more efficient recycling process for both increasing tensile property and fracture elongation of waste ground rubber tire powders.
참고문헌 (23)
- Adhikari, B, "Reclamation and recycling of waste rubber", Prog. Polym. Sci, 25(7), pp.909~948 (2000)
- Rorres, A., "Pyrolysis of scrap tyres", Fuel Process. Technol, 72, pp.9~22 (2001)
- Jang, J. W., "Discarded tire recycling practices in United States, Japn and Korea resoures", Conserv. Recycl, 22, pp.1~14 (1998)
- 폐타이어 재생처리시설현황, "한국자원재생공사", ~ (1998)
- Lee, J. Y., "Recycling of Waste Rubber", Korean Industrial Chemistry Nesws, 10(3), pp.42~49 (2007)
- Kim, J. K., "Waste Tire recycling technique", pp.1993
- 김진국, "입도분포해석에 의한 폐타이어 분말의 재활용 연구", 엘라스토머 및 콤포지트, 38(2), pp.128~138 (2003), 한국고무학회
- 金振國, "表面改質에 의한 廢타이어 분말의 再活用에 관한 연구(I)", 자원리싸이클링, 12(2), pp.28~35 (2003), 한국자원리싸이클링학회
- Cho, H. N, "Effect of the Curing Conditions on the Recycling of the Scrap Waste Tire", Journal of the Korea Institute of Rubber Industry, 31(2), pp.95~103 (1996)
- Hwang, S. H., "A Study on Utilization of Waste Tire by Fine Powder Processing and Modification of Molecule Structure", pp.1~26 (2004), Gyeongsang National University
- Paul. S, "Effect of cryogenic cooling by liquid nitrogen jet on forces, temperature and surface residual stresses in grinding steels", Cryogenics, 35(8), pp.515~523 (1995)
- Harrison, K., "An economic evaluation of cryogenic-grinding of scrap automotive tyres", Conservation & Recycling, 9(1), pp.1~14 (1986)
- Wilczek, M., "Optimised technologies for cryogenic grinding", International Journal of Mineral Processing, 74, pp.S425~S434 (2004)
- De-Link Bulletin, "De-Link recycling system, all you want to know", pp.69~92 (1995), STI-K Polymers Sdn
- Schocke, D., "Pulverization of rubber under high compression and shear", Powder technology, pp.207~214 (1999)
- Bauman, B. D, "urface-modified rubber particles in PU", Rubber Plast. News, 23, pp.56~58 (1974)
- Seo, K. H., "Effect of Ground Rubber on Mechanical Properties of EPDM Foam", Elastomer, 35(2), pp.132~137 (2000)
- Park, J. W., "Studies on Microbial Treatment for Recycling of Waste Tire", Journal of the Korea Institute of Rubber Industry, 32(5), pp.325~329 (1997)
- Levin, V. T., "Effect of crosslink type on the ultrasound devulcanization of SBR vulcanizates", Rubber Chemical Technology, 70, pp.641~649 (1997)
- 박종문, "Characteristics Studies of Waste Tire Rubber Powders using the Different Grinding Methods", 자원리싸이클링, 23(3), pp.44~50 (2014), 한국자원리싸이클링학회[DOI]
- 안주영, "폐타이어 분말과 재생PP로 제조한 열가소성 고무 플라스틱(TPV)의 물성평가", 자원리싸이클링, 23(4), pp.30~36 (2014), 한국자원리싸이클링학회[DOI]
- Park, C H., "Devulcanization Method for Wasted Tire", 10-0926346-0000(KR), ~ (2009)
- Kim, B. S., "private communication with Thinker route Co. Ltd" (2015)
