만경강과 동진강 주요 지점 하천토사 중 형태별 인의 함량
Phosphorus Fractionations in Sediment of Mankyung and Dongjin River
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만경강과 동진강 하천토사의 이화학적 특성과 형태별 인 함량을 조사한 결과 하천토사의 총인 함량은 만경강에서 290.1～405.4 mg/kg 수준으로 평균 363.4 mg/kg을, 동진강에서는 304.1～431.7 mg/kg 수준으로 평균 353.6 mg/kg을 나타냈고 조사지점 모두 6월과 9월에 높은 농도를 나타내었다. 이는 높은 농도의 질소와 인을 함유하고 있는 농경지 표토층이 강우-유출에 의해 하천에 유입되어 영향을 받았기 때문인 것으로 추정된다. 하천토사 내 인의 형태별 함량을 조사한 결과 만경강과 동진강에서 각 각 인회석태 인 52.1%와 42.7%, 유기태 인 27.3%와 34.2%, 비인회석태 인 18.1%와 22.5% 그리고 흡착태 인은 두 지역 모두 0.6%를 나타내었다. 하천토사 중 흡착태 인은 그 양이 매우 적어 수중생태계에 끼치는 영향이 미미할 것으로 판단되나, 비인회석태 인은 혐기성 상태가 되거나 pH가 높아지면 용출이 일어날 것으로 사료되어 관리가 필요할 것으로 나타났다.
Abstract
Sediments of Mankyung and Dongjin river were examined on the physico-chemical properties and phosphorus fractionations. The content of total-P in sediment of Mankyung river ranged from 290.1 to 405.4 mg/kg (average = 363.4 mg/kg), while that in sediment of Dongjin river ranged from 304.1 to 431.7 mg/kg (average = 353.6 mg/kg). In both rivers, the total-P was highest in June to September. It is presumed that surficial sediment in arable land flowed into the rivers with rainfall-runoff. Phosphorus fractionations in Mankyung and Dongjin river were apatite-P 52.1% and 42.7%, residual-P 27.3% and 34.2%, nonapatite inorganic-P 18.1% and 22.5%, and adsorbed-P 0.6% and 0.6%, respectively. Adsorbed-P in sediment was the most scarcity fraction. It thus appears that adsorbed phosphorus was not effected in aquatic ecosystem. But nonapatite inorganic-P would be highly released under changes of redox condition and pH in aquatic ecosystem.
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