쌀의 도정도에 따른 중금속 함량 변화
Investigation of Heavy Metal Contents by Milling Degrees of Rice
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BACKGROUND: Recently, various rice by milling degree is sold for health and taste. To provide safe food to consumers, it is need to know the change of heavy metal contents according to milling degree of rice. METHODS AND RESULTS: This study was to investigate residual the levels of cadmium (Cd), lead (Pb), copper (Cu) and zinc (Zn) as stated in the milling degree of the rice contaminated Cd and Pb from 2011 to 2012 in Chungcheongnam-do. Rice samples exceeded the maximum residue limits (MRL) of Cd and Pb were milled by five degrees (0.0, 2.45, 8.02, 10.48, 15.09%). Milled rice was digested by microwave method, and analyzed heavy metal contents using ICP-OES. Recovery ratios of 4 heavy metals such as Cd, Pb, Cu and Zn were ranged for 79.7-98.9%, and limits of detection (LOD) and limits of quantitation (LOQ) were fulfilled with the normal analytical standards. Concentrations of Cd, Pb, Cu and Zn were ranged 0.416- 0.433 mg/kg, 0.183-0.26 mg/kg, 3.639- 3.882 mg/kg and 16.868-19.801 mg/kg, respectively. CONCLUSION: From these results, conforming with increase of milling degree of rice, Cd, Pb, Cu, and Zn contents tended to decrease. The contents of heavy metals were decreased 3.1% in Cd, 29.3% in Pb, 6.4% in Cu and 15.1% in Zn, in according to the highest milling degree of 15.09%.
Abstract
BACKGROUND: Recently, various rice by milling degree is sold for health and taste. To provide safe food to consumers, it is need to know the change of heavy metal contents according to milling degree of rice. METHODS AND RESULTS: This study was to investigate residual the levels of cadmium (Cd), lead (Pb), copper (Cu) and zinc (Zn) as stated in the milling degree of the rice contaminated Cd and Pb from 2011 to 2012 in Chungcheongnam-do. Rice samples exceeded the maximum residue limits (MRL) of Cd and Pb were milled by five degrees (0.0, 2.45, 8.02, 10.48, 15.09%). Milled rice was digested by microwave method, and analyzed heavy metal contents using ICP-OES. Recovery ratios of 4 heavy metals such as Cd, Pb, Cu and Zn were ranged for 79.7-98.9%, and limits of detection (LOD) and limits of quantitation (LOQ) were fulfilled with the normal analytical standards. Concentrations of Cd, Pb, Cu and Zn were ranged 0.416- 0.433 mg/kg, 0.183-0.26 mg/kg, 3.639- 3.882 mg/kg and 16.868-19.801 mg/kg, respectively. CONCLUSION: From these results, conforming with increase of milling degree of rice, Cd, Pb, Cu, and Zn contents tended to decrease. The contents of heavy metals were decreased 3.1% in Cd, 29.3% in Pb, 6.4% in Cu and 15.1% in Zn, in according to the highest milling degree of 15.09%.
참고문헌 (22)
- Adriano, D. C, "Biogeochemistry of trace metals" (1992), Lewis publishers
- Alloway, B. J, "Heavy metals in soils", pp.395~409 (1995), Blackie Academic & Professional
- Bennett, J. P, "Heavy metals in wild rice from northern Wisconsin", Science of the Total Environment, 246(2), pp.261~269 (2000)
- Fergusson, J. E, "The heavy elements; Chemistry environmental impact and health effects" (1990), Pergamon ress
- Jung, J. H, "Residents of nearby mines scrap metal heavy metal contamination", pp.13~15 (2002), Jipmoon
- Jun, K. S, "Heavy Metal Concentrations in Soils and Stream around the Abandoned Mine Land", Journal of the Environmental Sciences, 8(2), pp.197~204 (1999)
- Jung, G. B, "Heavy metal contents in soils and vegetables in the plastic film house", Journal of Korean Society of Soil Science and Fertilizer, 30(2), pp.152a~160a (1997)
- 정구복, "토양내 중금속 존재형태와 미나리중 함량과의 관계", 한국토양비료학회지(Korean Journal of Soil Science and Fertilizer), 40(2), pp.164~171 (2007), 한국토양비료학회
- Jung, K. Y, "Effect of longterm application of sewage sludge on distribution and availability of heavy metals in soil-plant system", Fourth international conference, East and Southeast Asia Fedration of Soil Science Societies, pp.335~347 (1997)
- 정명채, "우리나라 백미의 As, Cd, Cu, Pb 및 Zn의 자연함유량과 일일 섭취량 조사", 자원환경지질, 36(5), pp.357~363 (2003), 대한자원환경지질학회
- 김민경, "우리 나라에서 생산된 농산물의 중금속 안정성 평가", 한국환경농학회지, 20(3), pp.169~174 (2001), 한국환경농학회
- Ko, I. S, "Investigation on harmful trace elements in food(1)", The Report of National Institute of Health, 9, pp.389~406 (1972)
- Lee, T. S, "A study on translocation of heavy metals in rice", Korean Journal of Public Health, 8(2), pp.39~46 (1982)
- Liu, J, "Uptake and translocation of Cd in different rice cultivars and the relation with Cd accumulation in rice grain", Journal of Hazardous Materials, 143(1), pp.443~447 (2007)
- Masironi, R, "Zinc, copper, cadmium and chromium in polished and unpolished rice", Science of the Total Environment, 7(1), pp.27~43 (1977)
- Muramoto, S, "Comparison of metal uptake between glutinous and non-glutinous rice for cadmium chloride, oxide and sulfide at the critical levels", Bulletin of environmental contamination and toxicology, 45(3), pp.415~421 (1990)
- Nriagu, J. O, "Trace metals in wild rice sold in the United States", Science of the total environment, 172(2-3), pp.223~228 (1995)
- 박상원, "탑라이스 생산지역 논 토양 중 잔류중금속의 벼 흡수이행", 한국환경농학회지, 28(2), pp.131~138 (2009), 한국환경농학회
- 박상원, "탑라이스 생산지역 논토양 중 중금속 함량과 쌀의 안전성", 한국식품위생안전성학회지, 23(3), pp.239~247 (2008), 한국식품위생안전성학회
- Tchai, B. S, "Food safety and health", Journal of the Korean Society of Food Science and Nutrition, 19(5), pp.509~518 (1990)
- Ullrich, S. M, "Total and exchangeable concentrations of heavy metals in soils near Bytom, an area of Pb", Zn mining and smelting in Upper Silesia, Poland, 1999, pp.14(2), 187~196
- Won, K. P, "The study on the trace metal contents in food-On the trace metals contents of cereals, pulses, potatoes, vegetables and fruits in Korea", The Report of National Institute of Health, 32(2), pp.456~469 (1995)
