Residues of Diazinon in Growing Chinese cabbage: A study Under Greenhouse Conditions
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Abstract
Chinese cabbage, Braccica campestris has long been consumed as a staple food for Koreans in various forms of fresh, salted, and fermented Kimchi. Cultivation of the crop under greenhouse has become a general practices to fulfill its off-seasonal consumer’s demand. However, agricultural practices of the crop have always accompanied with heavy applications of pesticides caused by severe outbreaks of diseases and pests under warm and humid circumferences. Since dissipation patterns of pesticide residues in/on the crop under greenhouse conditions are quite different from those in the open-air, changes of diazinon, O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphorothioate, in/on the Chinese cabbage applied by foliar spraying under greenhouse were studied. Diazinon 34% EC was applied with dilution of recommended and double dose to the crop. The shoots of crop were harvested immediately after this application and at regular intervals over a 10-day. After sample preparations, the diazinon residue was analyzed using gas chromatography equipped with electron capture detector (GC/ECD). Initially deposited amounts of the chemical in/on the crop right after applications with recommended and double doses were 8.3 and 15.2 mg/kg, respectively. The residue levels after 10 days of application were 0.03 and 0.09 mg/kg with 1.3 and 1.5 days of half-life in/on the crop, respectively. In consequent, 10 days of pre-harvest interval (PHI) for diazinon EC formulation in/on Chinese cabbage under greenhouse condition was fulfill maximum residue level set by Korea Food and Drug Administration (KFDA, 0.1 mg/kg).
참고문헌 (17)
- "Piperonyl butoxide as a tool in aquatic toxicology research with organophosphate insecticides. Ecotoxicol. Environ. Saf. 21" (1991)
- "The pesticide manual," (2000), Crop Protection Publications,
- "Human health risk assessment: diazinon. Memorandum" (2000), US Environmental Protection Agency
- "Analysis of the basic processes involved in the deposition and effectiveness of pesticides. Res. Rev. 3", pp.35~163 (1963)
- "Research on its causes and effects and approaches to its minimization. Res. Rev. 67", pp.1~132 (1977)
- "Amounts of pesticides reaching target pests: Environmental impacts and ethics.", 8, pp.1729~ (1995)
- "MRLs for pesticides in foods." (2005), Korea Food and Drug Administration
- "Pesticides application manual." (2005), Korea Crop Protection Association
- "Dissipation rates of insecticides in six minor vegetable crops grown on organic soils in Ontario", pp.605~616 (1980)
- "Investigations of the determination and transformations of diazinon and malathion under environmental conditions using gas chromatography coupled with a flame ionization detector.", 50, pp.595~601 (2003)
- "Simultaneous quantification of insecticides including carbaryl in drinking water by gas chromatography using dual electron-capture and nitrogenphosphorus detection.", 769, pp.285~291 (1997)
- "Dehydrogenase and phosphomonoesterase activities in groundnut (Arachis hypogaea L.) field after diazinon, imidacloprid and lindane treatments.", 60, pp.32~42 (2005)
- "Guidelines for Residues Monitoring in the European Union, 2nd ed.,", (SANCO, pp.3103 (2000), 2000,)[DOI]
- "Studies of the disappearance of nine pesticides on celery and lettuce grown on muck soils in Ontario", pp.1977 119~128 (1982)
- "Unequivocal identification of compounds formed in the photodegradation of fenitrothion in water", methanol and proposal of selected transformation pathways. J. Agric. Food Chem. 42, 1994, ~
- "Organophosphate insecticide degradation by non-amended Fenton’s reagent in aqueous solution.", 30, pp.585~604. (1995)
- "The degradation of organophosphorus pesticides in natural waters: A critical review.", 32, pp.1772~ (2002)
