산성광산배수슬러지의 토양 중금속 안정화 적용 가능성
The Applicability of the Acid Mine Drainage Sludge in the Heavy Metal Stabilization in Soils
1
조회
0
다운로드
8
인용
0
참고문헌
키워드
초록
BACKGROUND: Recent studies using various industrialwastes for heavy metal stabilization in soil were conductedin order to find out new alternative amendments. The acidmine drainage sludge(AMDS) contains lots of metaloxides(hydroxides) that may be useful for heavy metalstabilization not only waste water treatment but also soilremediation. The aim of this study was to investigate theapplicability of acid mine drainage sludge for heavy metalsstabilization in soilsMETHODS AND RESULTS: Alkali soil contaminatedwith heavy metals was collected from the agricultural soilsaffected by the abandoned mine sites nearby. Threedifferent amounts(1%, 3%, 5%) of AMDS were appliedinto control soil and contaminated soil. For determining thechanges in the extractable heavy metals, CaCl2 andMehlich-3 were applied as chemical assessments for metalstabilization. For biological assessments, lettuce(Lactucasativa L.) and chinese cabbage(Brassica rapa var. glabra)were cultivated and accumulation of heavy metals on eachplant were determined. It was revealed that AMDS reducedheavy metal mobility and bioavailability in soil, whichresulted in the decreases in the accumulation of As, Cd, Cu,Pb, and Zn in each plant. CONCLUSION: Though the high level of heavy metalconcentrations in AMDS, any considerable increase in theheavy metal availability was not observed with control andcontaminated soil. In conclusion, these results indicatedthat AMDS could be applied to heavy metal contaminatedsoil as an alternative amendments for reducing heavy metalmobility and bioavailability.
Abstract
BACKGROUND: Recent studies using various industrialwastes for heavy metal stabilization in soil were conductedin order to find out new alternative amendments. The acidmine drainage sludge(AMDS) contains lots of metaloxides(hydroxides) that may be useful for heavy metalstabilization not only waste water treatment but also soilremediation. The aim of this study was to investigate theapplicability of acid mine drainage sludge for heavy metalsstabilization in soilsMETHODS AND RESULTS: Alkali soil contaminatedwith heavy metals was collected from the agricultural soilsaffected by the abandoned mine sites nearby. Threedifferent amounts(1%, 3%, 5%) of AMDS were appliedinto control soil and contaminated soil. For determining thechanges in the extractable heavy metals, CaCl2 andMehlich-3 were applied as chemical assessments for metalstabilization. For biological assessments, lettuce(Lactucasativa L.) and chinese cabbage(Brassica rapa var. glabra)were cultivated and accumulation of heavy metals on eachplant were determined. It was revealed that AMDS reducedheavy metal mobility and bioavailability in soil, whichresulted in the decreases in the accumulation of As, Cd, Cu,Pb, and Zn in each plant. CONCLUSION: Though the high level of heavy metalconcentrations in AMDS, any considerable increase in theheavy metal availability was not observed with control andcontaminated soil. In conclusion, these results indicatedthat AMDS could be applied to heavy metal contaminatedsoil as an alternative amendments for reducing heavy metalmobility and bioavailability.
참고문헌 (37)
- Arai, Y., "Residence time effects in arsenate surface speciation at the aluminum oxide-water interfacem", Soil Sci, 167, pp.303~314 (2002)
- Bernstein, L., "Effects of salinity and sodicity on plant growth", Annu. Rev. Phytopathol, 13, pp.295~312 (1975)
- Chiu, V.Q., "Arsenic adsorption and oxidation at manganite surface. 1. Method for simultaneous determination of adsorbed and dissolved arsenic species", Environ. Sci. Technol, 34, pp.2029~2034 (2000)
- 최솔지, "Study on adsorption", desorption of As by mine sludge depending on pH and natural organic matter, 2013, pp.16(3), 191~199[DOI]
- Dakora, F.D., "Root exudates as mediators of mineral acquisition in low-nutrient environments", , Plant Soil, 245, pp.35~47 (2002)
- Driehaus, W., "Oxidation of arsenite(III) with manganese oxides in water treatment", Water Res, 29, pp.297~305 (1995)
- Droppa, M., "The role of copper in photosynthesis", Crit. Rev, Plant Sci, 9, pp.111~123 (1990)
- Dzombak, D.A., "Surface complexation modeling: hydrous ferric oxide", pp.279~297 (1990), Wiley
- Esnaola, M.V., "Evaluation of heavy metal lability in polluted soils by a cation exchange batch procedure", Environ. Pollut, 99, pp.79~86 (1998)
- Goldberg, S., "Mechanisms of arsenic adsorption on amorphous oxides evaluated using macroscopic measurements, vibrational spectroscopy, and surface complexation modeling", J. Colloid. Interf. Sci, 234, pp.204~216 (2001)
- Jeon, C.S., "Adsorption characteristics of As(V) on iron-coated zeolite", J. Hazard. Mater, 163, pp.804~808 (2009)
- Jeong, H.Y., "Characterization of synthetic nanocrystalline mackinawite: crystal structure, particle size, and specific surface area", Geochim. Cosmochim. Ac, 72, pp.493~505 (2008)
- 김권래, "광산 인근 밭토양에서 중금속 안정화제 처리 및 복토층 처리에 의한 토양 중 중금속 식물유효도 변화 및 고추의 중금속 흡수", 한국토양비료학회지(Korean Journal of Soil Science and Fertilizer), 43(6), pp.864~871 (2010), 한국토양비료학회
- 김민석, "중금속 오염 토양에서 안정화제가 청경채의 초기 생육과 중금속 흡수량에 미치는 영향", 한국토양비료학회지(Korean Journal of Soil Science and Fertilizer), 45(6), pp.961~967 (2012), 한국토양비료학회[DOI]
- 김민석, "여러 안정화제가 산성 및 알칼리 토양에서 중금속 안정화에 미치는 영향", 한국환경농학회지, 33(1), pp.1~8 (2014), 한국환경농학회[DOI]
- Koo, N., "Using response surface methodology to assess the effects of iron and spent mushroom substrate on arsenic phytotoxicity in lettuce (Lactuca sativa L.)", J. Hazard. Mater, 192, pp.381~387 (2011)
- Koo, N., "Arsenic mobility in the amended mine tailings and its impact on soil enzyme activity", Environ. Geochem. Health, 34, pp.337~348 (2012)
- Lee, S.H., "In situ stabilization of cadmium-, lead-, zinc-contaminated soil using various amendments", Chemosphere, pp.1069~1075 (2009)
- Lee, S.H., "Evaluation of the effectiveness of various amendments on trace metals stabilization by chemical and biological methods", J. Hazard. Mater, 188, pp.44~51 (2011)
- Lee, S.H., "Influence of amendments and aided phytostabilization on metal availability and mobility in Pb", Zn mine tailings, 2014, pp.139, 15~21
- Mall, I.D., "Characterization and utilization of mesoporous fertilizer plant waste carbon for adsorptive removal of dyes from aqueous solution", Colloid. Surface. A, 278, pp.175~187 (2006)
- Mehlich, A., "Mehlich 3 soil test extractant: A modification of Mehlich 2 extractant", Commun. Soil Sci. Plan, 15, pp.1409~1416 (1984)
- Mench, M.J., "Capacity of soil amendments in lowering the phytoavailability of sludge-borne zinc", Agronomie, 20, pp.383~397 (2000)
- Oladoja, N.A., "Snail shell as coagulant aid in the alum precipitation of malachite green from aqua system", J. Hazard. Mater, 164, pp.1496~1520 (2009)
- Penn, C.J., "Removing dissolved phosphorus from drainage ditch water with phosphorus sorbing materials", J. Soil Water Conserv, 62, pp.269~276 (2007)
- Rout, G.R., "Effect of metal toxicity on plant growth and metabolism: I", Zinc, Agronomie, 23, pp.3~11 (2003)
- Ruihua, L., "Phosphorus removal performance of acid mine drainage from wastewater", J. Hazard. Mater, 190, pp.669~676 (2011)
- Sekhon, B.S., "Competitive effect of organic anions on phosphorus attenuation capacity of acid mine drainage floc", Environ. Earth Sci, 70, pp.651~660 (2013)
- Sherman, D.M., "Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy", Geochim. Cosmochim. Ac, 67, pp.4223~4230 (2003)
- Sibrell, P.L., "Removal or phosphorus from agricultural wastewaters using adsorption media prepared from acid mine drainage sludge", Water Res, 43, pp.2240~2250 (2009)
- 송영준, "산성광산배수(AMD) 處理 슬러지의 重金屬 吸着 特性", 자원리싸이클링, 21(4), pp.35~43 (2012), 한국자원리싸이클링학회
- Tran, T.S., "Soil sampling and methods of analysis", pp.43~50 (1993), Canadian Society of Soil Science, Lewis Publishers
- Tsang D.C.W., "Soil stabilisation using AMD sludge, compost and lignite: TCLP leachability and continuous acid leaching", Chemosphere, 93, pp.2839~2847 (2013)
- Tsang, D.C.W., "Comparing chemicalenhanced washing and waste-based stabilisation approach for soil remediation", J. Soil Sediment, 14, pp.936~947 (2014)
- Wei, X., "Phosphorus removal by acid mine drainage sludge from secondary effluents of municipal wastewater treatement plants", Water Res, 42, pp.3275~3284 (2008)
- Wu, L.H., "Effects of EDTA and low molecular weight organic acids on soil solution prpperties of a heavy metal polluted soil", Chemosphere, 50, pp.819~822 (2003)
- Zhang X., "A nonpathogenic Fusarium oxysporum strain enhances phytoextraction of heavy metals by the hyperaccumulator Sedum alfredii Hance", J. Hazard. Mater, 229-230, pp.361~370 (2012)
