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농업지역(밭) 암모니아 등 대기오염물질 계절별 모니터링 연구

Study on the Emission Characteristics of Air Pollutants from Agricultural Area

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키워드

주제분류농학

초록

BACKGROUND: Fine particulate matter (PM2.5) is produced by chemical reactions between various precursors. PM2.5 has been found to create greater human risk than particulate matter (PM10), with diameters that are generally 10 micrometers and smaller. Ammonia (NH3) and nitrogen oxides (NOx) are the sources of secondary generation of PM2.5. These substances generate PM2.5 through some chemical reactions in the atmosphere. Through chemical reactions in the atmosphere, NH3 generates PM2.5. It is the causative agent of PM2.5. In 2017 the annual ammonia emission recorded from the agricultural sector was 244,335 tons, which accounted for about 79.3% of the total ammonia emission in Korea in that year. To address this issue, the agricultural sector announced the inclusion of reducing fine particulate matter and ammonia emissions by 30% in its targets for the year 2022. This may be achieved through analyses of its emission characteristics by monitoring the PM2.5 and NH3. METHODS AND RESULTS: In this study, the PM2.5 con-centration was measured real-time (every 1 hour) by using beta radiation from the particle dust measuring device (Spirant BAM). NH3 concentration was analyzed real-time by Cavity Ring-Down Spectroscopy (CRDS). The con-centrations of ozone (O3) and nitrogen dioxide (NO2) were continuously measured and analyzed for the masses col-lected on filter papers by ultraviolet photometry and chemiluminescence. CONCLUSION: This study established air pollutant monitoring system in agricultural areas to analyze the NH3 emission characteristics. The amount of PM2.5 and NH3 emission in agriculture was measured. Scientific evidence in agricultural areas was obtained by identifying the emission concentration and characteristics per season (monthly) and per hour.

Abstract

BACKGROUND: Fine particulate matter (PM2.5) is produced by chemical reactions between various precursors. PM2.5 has been found to create greater human risk than particulate matter (PM10), with diameters that are generally 10 micrometers and smaller. Ammonia (NH3) and nitrogen oxides (NOx) are the sources of secondary generation of PM2.5. These substances generate PM2.5 through some chemical reactions in the atmosphere. Through chemical reactions in the atmosphere, NH3 generates PM2.5. It is the causative agent of PM2.5. In 2017 the annual ammonia emission recorded from the agricultural sector was 244,335 tons, which accounted for about 79.3% of the total ammonia emission in Korea in that year. To address this issue, the agricultural sector announced the inclusion of reducing fine particulate matter and ammonia emissions by 30% in its targets for the year 2022. This may be achieved through analyses of its emission characteristics by monitoring the PM2.5 and NH3. METHODS AND RESULTS: In this study, the PM2.5 con-centration was measured real-time (every 1 hour) by using beta radiation from the particle dust measuring device (Spirant BAM). NH3 concentration was analyzed real-time by Cavity Ring-Down Spectroscopy (CRDS). The con-centrations of ozone (O3) and nitrogen dioxide (NO2) were continuously measured and analyzed for the masses col-lected on filter papers by ultraviolet photometry and chemiluminescence. CONCLUSION: This study established air pollutant monitoring system in agricultural areas to analyze the NH3 emission characteristics. The amount of PM2.5 and NH3 emission in agriculture was measured. Scientific evidence in agricultural areas was obtained by identifying the emission concentration and characteristics per season (monthly) and per hour.

참고문헌 (10)

  1. 송명기, "겨울철 교외 지역 장거리유입 암모니아 및 암모늄과의 관계", 한국대기환경학회지, 36(4), pp.543~557 (2020), 한국대기환경학회[DOI]
  2. 조병수, "2010~2015년 전라북도 도시대기 PM10의 특성", 한국대기환경학회지, 33(3), pp.251~264 (2017), 한국대기환경학회[DOI]
  3. 김순태, "전년 동기대비 2020년 12월 국내 초미세먼지 농도 변화 요인 분석", 한국대기환경학회지, 37(3), pp.371~387 (2021), 한국대기환경학회[DOI]
  4. 배민석, "서울시 대기 측정소간 상관관계를 감안한 측정소의 운용 방향 개선을 위한 제언", 한국대기환경학회지, 29(4), pp.447~458 (2013), 한국대기환경학회[DOI]
  5. 김순태, "2016년 국가배출목록 기반 지자체별 초미세먼지 기여도 분석: (III) 전라남도", 한국대기환경학회지, 37(2), pp.206~230 (2021), 한국대기환경학회[DOI]
  6. 김은혜, "2016년 국가배출목록 기반 지자체별 초미세먼지 기여도 분석: (IV) 전라북도", 한국대기환경학회지, 37(2), pp.292~309 (2021), 한국대기환경학회[DOI]
  7. 이기호, "제주시 지역 미세먼지의 변동과 화학적 구성 특성", 한국환경과학회지, 29(5), pp.495~506 (2020), 한국환경과학회[DOI]
  8. 유근혜, "광주지역 PM2.5의 고농도 오염현상 조사", 한국대기환경학회지, 31(3), pp.269~286 (2015), 한국대기환경학회[DOI]
  9. 손규원, "미세먼지 계절관리제 기간 동안 PM2.5 농도에 대한 기상과 배출 영향 분석: 2019년 12월~2020년 3월", 한국대기환경학회지, 36(4), pp.442~463 (2020), 한국대기환경학회[DOI]
  10. Ainsworth, E.A, "Understanding and improving global crop response to ozone pollution", The Plant Journal, 90(5), pp.886~897 (2017)[DOI]

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