식물후방식재기간(PBI) 시험에 기반한 살균제 Azoxystrobin의 알타리무 중 잔류량 평가
Evaluation of Residues of Fungicide Azoxystrobin in Radish based on Plant Back Interval Experiment
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
BACKGROUND: The pesticide residue in rotational crop is one of the main concerns to agricultural products be-cause it has the potentiality of violating positive list sys-tem (PLS). Thus, the crops used for the rotational cultivation should be considered the pesticide residue patterns to meet the PLS guideline. In this study, we evaluated the residue patterns of fungicide azoxystrobin in radish based on plant back interval (PBI) experiment. METHODS AND RESULTS: Azoxystrobin was treated onto greenhouse soil at 217 g a.i./10a in two different re-gions. Radishes were sown onto the soil 30 and 60 days af-ter azoxystrobin treatment. The soil and plant samples were subjected to a modified QuEChERS method and LC/MS/ MS analyses to determine the residues of azoxystrobin. The methods were validated to meet the guidelines of the pes-ticide residue analysis recommended by the Rural Deve-lopment Administration, Republic of Korea. Azoxystrobin was dissipated significantly in soil during the experimen-tal period and found as a level less than 0.01 mg/kg in radish 30 and 60 days after treatment. Azoxystrobin residues in radish samples were lower than the maximum residue limit (MRL) for root vegetables. CONCLUSION(S): This study suggests 30 days as a PBI for rotational cultivation of radish in greenhouse soil that had been treated with azoxystrobin at a level of 217 g a.i./10a.
Abstract
BACKGROUND: The pesticide residue in rotational crop is one of the main concerns to agricultural products be-cause it has the potentiality of violating positive list sys-tem (PLS). Thus, the crops used for the rotational cultivation should be considered the pesticide residue patterns to meet the PLS guideline. In this study, we evaluated the residue patterns of fungicide azoxystrobin in radish based on plant back interval (PBI) experiment. METHODS AND RESULTS: Azoxystrobin was treated onto greenhouse soil at 217 g a.i./10a in two different re-gions. Radishes were sown onto the soil 30 and 60 days af-ter azoxystrobin treatment. The soil and plant samples were subjected to a modified QuEChERS method and LC/MS/ MS analyses to determine the residues of azoxystrobin. The methods were validated to meet the guidelines of the pes-ticide residue analysis recommended by the Rural Deve-lopment Administration, Republic of Korea. Azoxystrobin was dissipated significantly in soil during the experimen-tal period and found as a level less than 0.01 mg/kg in radish 30 and 60 days after treatment. Azoxystrobin residues in radish samples were lower than the maximum residue limit (MRL) for root vegetables. CONCLUSION(S): This study suggests 30 days as a PBI for rotational cultivation of radish in greenhouse soil that had been treated with azoxystrobin at a level of 217 g a.i./10a.
참고문헌 (20)
- OECD, "Draft guidance document on residues in rotational crops", OECD Environ. Health Safety Public, 1, pp.1~46 (2016)
- T. Anesiadis, "Protective, Curative and Eradicant Activity of the Strobilurin Fungicide Azoxystrobin against Cercospora beticola and Erysiphe betae", Journal of Phytopathology, 151(11-12), pp.647~651 (2003), Wiley[DOI]
- Loukas Kanetis, "Comparative Efficacy of the New Postharvest Fungicides Azoxystrobin, Fludioxonil, and Pyrimethanil for Managing Citrus Green Mold", Plant Disease, 91(11), pp.1502~1511 (2007), Scientific Societies[DOI]
- Francis P. Wong, "Comparative Physical Modes of Action of Azoxystrobin, Mancozeb, and Metalaxyl Against <i>Plasmopara viticola<", i> (Grapevine Downy Mildew), 2001, pp.85(6), 649~656[DOI]
- J. R. Bertelsen, "Fungicidal effects of azoxystrobin and epoxiconazole on phyllosphere fungi, senescence and yield of winter wheat", Plant Pathology, 50(2), pp.190~205 (2001), Wiley[DOI]
- Vijay Tularam Gajbhiye, "Persistence of Azoxystrobin in", on Grapes and Soil in Different Grapes Growing Areas of India, 2011, pp.86(1), 90~94[DOI]
- E.M. Adetutu, "Azoxystrobin and soil interactions: degradation and impact on soil bacterial and fungal communities", Journal of Applied Microbiology, 105(6), pp.1777~1790 (2008), Oxford University Press (OUP)[DOI]
- Indra Purnama, "Degradation profile of azoxystrobin in Andisol soil: laboratory incubation", Toxicological and Environmental Chemistry, 96, pp.1141~1152 (2015), Informa UK Limited[DOI]
- Rakesh Kumar Ghosh, "Effect of Organic Manure on Sorption and Degradation of Azoxystrobin in Soil", Journal of Agricultural and Food Chemistry, 57(2), pp.632~636 (2009), American Chemical Society (ACS)[DOI]
- Michelangelo Anastassiades, "Fast and Easy Multiresidue Method Employing Acetonitrile Extraction", Partitioning and “Dispersive Solid-Phase Extraction” for the Determination of Pesticide Residues in Produce, 2003, pp.86(2), 412~431[DOI]
- "SANTE Guidance Document on Analytical Quality Control and Validation Procedures for Pesticide Analysis in Food and Feed", SANTE, 2019, Implemented by 01.01.2020; European Commission Directorate General for Health and Food Safety, pp.2020, ~
- Maofeng Dong, "Analysis of amicarbazone and its two metabolites in grains and soybeans by liquid chromatography with tandem mass spectrometry", Journal of Separation Science, 38(13), pp.2245~2252 (2015), Wiley[DOI]
- Da-Jung Lim, "Plant-Back Intervals of Imicyafos Based on Its Soil Dissipation and Plant Uptake for Rotational Cultivation of Lettuce and Spinach in Greenhouse", Agriculture, 11(6), pp.495~ (2021), MDPI AG[DOI]
- Kyu-Won Hwang, "Residual Level of Chlorpyrifos in Lettuces Grown on Chlorpyrifos-Treated Soils", Applied Sciences, 8(12), pp.2343~ (2018), MDPI AG[DOI]
- Jeong-In Hwang, "Bioconcentration factor-based management of soil pesticide residues: Endosulfan uptake by carrot and potato plants", Science of The Total Environment, 627, pp.514~522 (2018), Elsevier BV[DOI]
- Ju C, "Uptake, translocation, and subcellular distribution of azoxystrobin in wheat plant(Triticum aestivum L. )", Journal of Agricultural and Food Chemistry, 67, pp.6691~6699 (2019)[DOI]
- European Food Safety Authority, "Reasoned opinion on the modification of the existing MRLs for azoxystrobin in lettuce, spinach, celery, cardoon, spices and rhubarb", EFSA Journal, 10, pp.2991~ (2012)[DOI]
- European Food Safety Authority, "Reasoned opinion of EFSA prepared by the Pesticides Unit (PRAPeR) on setting of an import tolerance for azoxystrobin in passion fruits", EFSA Journal, 209, pp.25~ (2008)[DOI]
- European Food Safety Authority, "Reasoned opinion of EFSA prepared by the Pesticides Unit(PRAPeR)on the modification of the existing MRL for azoxystrobin in swedes", EFSA Journal, 20, pp.1308~ (2009)[DOI]
- European Food Safety Authority, "Reasoned opinion of EFSA prepared by the Pesticides Unit(PRAPeR)on the modification of the existing MRL for azoxystrobin in cardoon", EFSA Journal, 23, pp.1362~ (2009)[DOI]
