Metalaxyl-M 및 dinotefuran 입제의 쑥갓 중 잔류 특성 및 위해성 평가
Residual Characteristics and Risk Assessments of Metalaxyl-M and Dinotefuran in Crown Daisy
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초록
BACKGROUND: This study was performed to de-termine residual characteristics of soil-treated metal-axyl-M and dinotefuran in crown daisy and to evaluate the risks from intake of the residual pesticides in the crop. METHODS AND RESULTS: The pesticide granules were treated in soil on two levels, and the plants samples were collected 51 days after seeding. The analytes were extracted and partitioned using the QuEChERS ex-traction packet (MgSO4 4 g, NaCl 1 g). The quantitative methods for metalaxyl-M and dinotefuran were validated in linearity, accuracy, and precision. Risk assessments of the pesticides were performed using Korea national nu-trition statistics 2019. CONCLUSION(S): The residual concentrations of met-alaxyl-M in crown daisy were 0.09-0.10 mg/kg (for the treatment at 6 kg/10 a) and 0.17-0.19 mg/kg (12 kg/10 a), respectively. The residual concentrations of dinotefuran in the crop were 0.53-0.75 mg/kg (3 kg/10 a) and 1.17-1.26 mg/kg (6 kg/10 a). The amounts of pesticides were less than MRL (Maximum Residue Limits) accord-ing to the Korean MFDS (Ministry of Food and Drug Safety). The HI (Hazard Index) of metalaxyl-M and dino-tefuran for consumers was 0.0075% and 0.2250%, respectively. For females in the age between 50-64, the major consumer group, the HIs of the pesticides were <3%. Considering the consumption of crown daisy, they are not considered to be of toxicological concern.
Abstract
BACKGROUND: This study was performed to de-termine residual characteristics of soil-treated metal-axyl-M and dinotefuran in crown daisy and to evaluate the risks from intake of the residual pesticides in the crop. METHODS AND RESULTS: The pesticide granules were treated in soil on two levels, and the plants samples were collected 51 days after seeding. The analytes were extracted and partitioned using the QuEChERS ex-traction packet (MgSO4 4 g, NaCl 1 g). The quantitative methods for metalaxyl-M and dinotefuran were validated in linearity, accuracy, and precision. Risk assessments of the pesticides were performed using Korea national nu-trition statistics 2019. CONCLUSION(S): The residual concentrations of met-alaxyl-M in crown daisy were 0.09-0.10 mg/kg (for the treatment at 6 kg/10 a) and 0.17-0.19 mg/kg (12 kg/10 a), respectively. The residual concentrations of dinotefuran in the crop were 0.53-0.75 mg/kg (3 kg/10 a) and 1.17-1.26 mg/kg (6 kg/10 a). The amounts of pesticides were less than MRL (Maximum Residue Limits) accord-ing to the Korean MFDS (Ministry of Food and Drug Safety). The HI (Hazard Index) of metalaxyl-M and dino-tefuran for consumers was 0.0075% and 0.2250%, respectively. For females in the age between 50-64, the major consumer group, the HIs of the pesticides were <3%. Considering the consumption of crown daisy, they are not considered to be of toxicological concern.
참고문헌 (26)
- Govinda Bhandari, "Pesticide residues in Nepalese vegetables and potential health risks", Environmental Research, 172, pp.511~521 (2019), Elsevier BV[DOI]
- Duck Woong Park, "Pesticide Residues and Risk Assessment from Monitoring Programs in the Largest Production Area of Leafy Vegetables in South Korea: A 15-Year Study", Foods, 10(2), pp.425~ (2021), MDPI AG[DOI]
- Jong-Hyouk Park, "Analysis of imidacloprid and pyrimethanil in shallot (<i>Allium ascalonicum<", i>) grown under greenhouse conditions using tandem mass spectrometry: establishment of pre-harvest residue limits, 2012, pp.27(4), 451~457[DOI]
- Nirmala Basnet, "Impact of Pesticide and Fertilizer on Human Health: A Case Study in Godawari Area, Lalitpur, Nepal", The Geographic Base, 6, pp.65~76 (2019), Nepal Journals Online (JOL)[DOI]
- William R Reeves, "Assessing the Safety of Pesticides in Food: How Current Regulations Protect Human Health", Advances in Nutrition, 10(1), pp.80~88 (2019), Elsevier BV[DOI]
- 우나리야, "충북지역에 유통되는 일부 채소 농산물의 잔류농약 모니터링", 한국식품영양학회지, 26(4), pp.865~878 (2013), 한국식품영양학회[DOI]
- 강향리, "Positive List System 도입에 따른 열대과일류의 잔류농약 안전성 조사", 한국식품위생안전성학회지, 33(4), pp.310~315 (2018), 한국식품위생안전성학회[DOI]
- 강민성, "쑥갓 중 bifenthrin과 chlorothalonil의 경시적 잔류량 변화 및 생물학적 반감기", 한국식품위생안전성학회지, 34(2), pp.191~198 (2019), 한국식품위생안전성학회[DOI]
- 전상오, "소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상", 한국환경농학회지, 34(3), pp.223~229 (2015), 한국환경농학회[DOI]
- 정형욱, "위해성평가에 근거한 농산물 중 22종 농약의 잔류허용기준설정", 한국환경농학회지, 30(2), pp.156~162 (2011), 한국환경농학회
- Lee JK, "Current status for management of pesticide maximum residue limits in foods", Food Science and Industry, 43(2), pp.2~23 (2010)[DOI]
- Jakob A. Shimshoni, "Pesticide distribution and depletion kinetic determination in honey and beeswax: Model for pesticide occurrence and distribution in beehive products", PLOS ONE, 14(2), pp.e0212631~ (2019), Public Library of Science (PLoS)[DOI]
- 이강범, "충남도내 유통 과일류의 잔류농약 안전성 조사", 한국식품위생안전성학회지, 34(5), pp.421~430 (2019), 한국식품위생안전성학회[DOI]
- Gabriela Svartz, "Differential sensitivity of developmental stages of the South American toad to a fungicide based on fludioxonil and metalaxyl-M", Environmental Science and Pollution Research, 25(24), pp.23857~23863 (2018), Springer Science and Business Media LLC[DOI]
- Jana Pavelková, "Efficacy of fosetyl-Al, propamocarb, dimethomorph, cymoxanil, metalaxyl and metalaxyl-M in Czech Pseudoperonospora cubensis populations during the years 2005 through 2010", Crop Protection, 60, pp.9~19 (2014), Elsevier BV[DOI]
- 김아름누리, "네오니코티노이드계 4종 농약의 서양뒤영벌 급성 접촉 및 섭식 독성평가", 한국환경농학회지, 39(2), pp.106~113 (2020), 한국환경농학회[DOI]
- 부경환, "시설재배 아스파라거스 중 살충제 dinotefuran의 잔류특성", 한국산학기술학회논문지, 19(6), pp.375~381 (2018), 한국산학기술학회[DOI]
- Eiki Watanabe, "Analytical evaluation of enzyme-linked immunosorbent assay for neonicotinoid dinotefuran for potential application to quick and simple screening method in rice samples", Talanta, 84(4), pp.1107~1111 (2011), Elsevier BV[DOI]
- Kevin A. Ford, "Comparative Metabolism and Pharmacokinetics of Seven Neonicotinoid Insecticides in Spinach", Journal of Agricultural and Food Chemistry, 56(21), pp.10168~10175 (2008), American Chemical Society (ACS)[DOI]
- Xiaoxin Chen, "Simultaneous determination of pyridaben, dinotefuran, DN and UF in eggplant ecosystem under open-field conditions: Dissipation behaviour and residue distribution", Chemosphere, 195, pp.245~251 (2018), Elsevier BV[DOI]
- Chang-Hwan Oh, "Monitoring of Residual Pesticides in Herbal Drug Materials of Korea and China", Bulletin of Environmental Contamination and Toxicology, 82(5), pp.639~643 (2009), Springer Science and Business Media LLC[DOI]
- Gunjan Pandey, "Biotransformation of the neonicotinoid insecticides imidacloprid and thiamethoxam by Pseudomonas sp. 1G", Biochemical and Biophysical Research Communications, 380(3), pp.710~714 (2009), Elsevier BV[DOI]
- Wei Yao, "Multi-residue Analysis of 34 Pesticides in Black Pepper by QuEChERS with d-SPE Vs. d-SLE Cleanup", Food Analytical Methods, 12(1), pp.176~189 (2018), Springer Science and Business Media LLC[DOI]
- J.-M. Bonmatin, "Environmental fate and exposure; neonicotinoids and fipronil", Environmental Science and Pollution Research, 22(1), pp.35~67 (2014), Springer Science and Business Media LLC[DOI]
- 이유진, "기능성 쌀의 잔류농약 및 이산화황 안전성 실태조사", 한국식품위생안전성학회지, 32(6), pp.493~499 (2017), 한국식품위생안전성학회[DOI]
- 전종섭, "인천광역시 유통 농산물의 최근 3년간의 잔류농약 실태 조사연구", 한국환경농학회지, 25(2), pp.180~189 (2006), 한국환경농학회
