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Metalaxyl-M 및 dinotefuran 입제의 쑥갓 중 잔류 특성 및 위해성 평가

Residual Characteristics and Risk Assessments of Metalaxyl-M and Dinotefuran in Crown Daisy

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참고문헌

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주제분류농학

초록

BACKGROUND: This study was performed to de-termine residual characteristics of soil-treated metal-axyl-M and dinotefuran in crown daisy and to evaluate the risks from intake of the residual pesticides in the crop. METHODS AND RESULTS: The pesticide granules were treated in soil on two levels, and the plants samples were collected 51 days after seeding. The analytes were extracted and partitioned using the QuEChERS ex-traction packet (MgSO4 4 g, NaCl 1 g). The quantitative methods for metalaxyl-M and dinotefuran were validated in linearity, accuracy, and precision. Risk assessments of the pesticides were performed using Korea national nu-trition statistics 2019. CONCLUSION(S): The residual concentrations of met-alaxyl-M in crown daisy were 0.09-0.10 mg/kg (for the treatment at 6 kg/10 a) and 0.17-0.19 mg/kg (12 kg/10 a), respectively. The residual concentrations of dinotefuran in the crop were 0.53-0.75 mg/kg (3 kg/10 a) and 1.17-1.26 mg/kg (6 kg/10 a). The amounts of pesticides were less than MRL (Maximum Residue Limits) accord-ing to the Korean MFDS (Ministry of Food and Drug Safety). The HI (Hazard Index) of metalaxyl-M and dino-tefuran for consumers was 0.0075% and 0.2250%, respectively. For females in the age between 50-64, the major consumer group, the HIs of the pesticides were <3%. Considering the consumption of crown daisy, they are not considered to be of toxicological concern.

Abstract

BACKGROUND: This study was performed to de-termine residual characteristics of soil-treated metal-axyl-M and dinotefuran in crown daisy and to evaluate the risks from intake of the residual pesticides in the crop. METHODS AND RESULTS: The pesticide granules were treated in soil on two levels, and the plants samples were collected 51 days after seeding. The analytes were extracted and partitioned using the QuEChERS ex-traction packet (MgSO4 4 g, NaCl 1 g). The quantitative methods for metalaxyl-M and dinotefuran were validated in linearity, accuracy, and precision. Risk assessments of the pesticides were performed using Korea national nu-trition statistics 2019. CONCLUSION(S): The residual concentrations of met-alaxyl-M in crown daisy were 0.09-0.10 mg/kg (for the treatment at 6 kg/10 a) and 0.17-0.19 mg/kg (12 kg/10 a), respectively. The residual concentrations of dinotefuran in the crop were 0.53-0.75 mg/kg (3 kg/10 a) and 1.17-1.26 mg/kg (6 kg/10 a). The amounts of pesticides were less than MRL (Maximum Residue Limits) accord-ing to the Korean MFDS (Ministry of Food and Drug Safety). The HI (Hazard Index) of metalaxyl-M and dino-tefuran for consumers was 0.0075% and 0.2250%, respectively. For females in the age between 50-64, the major consumer group, the HIs of the pesticides were <3%. Considering the consumption of crown daisy, they are not considered to be of toxicological concern.

참고문헌 (26)

  1. Govinda Bhandari, "Pesticide residues in Nepalese vegetables and potential health risks", Environmental Research, 172, pp.511~521 (2019), Elsevier BV[DOI]
  2. Duck Woong Park, "Pesticide Residues and Risk Assessment from Monitoring Programs in the Largest Production Area of Leafy Vegetables in South Korea: A 15-Year Study", Foods, 10(2), pp.425~ (2021), MDPI AG[DOI]
  3. Jong-Hyouk Park, "Analysis of imidacloprid and pyrimethanil in shallot (<i>Allium ascalonicum<", i>) grown under greenhouse conditions using tandem mass spectrometry: establishment of pre-harvest residue limits, 2012, pp.27(4), 451~457[DOI]
  4. Nirmala Basnet, "Impact of Pesticide and Fertilizer on Human Health: A Case Study in Godawari Area, Lalitpur, Nepal", The Geographic Base, 6, pp.65~76 (2019), Nepal Journals Online (JOL)[DOI]
  5. William R Reeves, "Assessing the Safety of Pesticides in Food: How Current Regulations Protect Human Health", Advances in Nutrition, 10(1), pp.80~88 (2019), Elsevier BV[DOI]
  6. 우나리야, "충북지역에 유통되는 일부 채소 농산물의 잔류농약 모니터링", 한국식품영양학회지, 26(4), pp.865~878 (2013), 한국식품영양학회[DOI]
  7. 강향리, "Positive List System 도입에 따른 열대과일류의 잔류농약 안전성 조사", 한국식품위생안전성학회지, 33(4), pp.310~315 (2018), 한국식품위생안전성학회[DOI]
  8. 강민성, "쑥갓 중 bifenthrin과 chlorothalonil의 경시적 잔류량 변화 및 생물학적 반감기", 한국식품위생안전성학회지, 34(2), pp.191~198 (2019), 한국식품위생안전성학회[DOI]
  9. 전상오, "소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상", 한국환경농학회지, 34(3), pp.223~229 (2015), 한국환경농학회[DOI]
  10. 정형욱, "위해성평가에 근거한 농산물 중 22종 농약의 잔류허용기준설정", 한국환경농학회지, 30(2), pp.156~162 (2011), 한국환경농학회
  11. Lee JK, "Current status for management of pesticide maximum residue limits in foods", Food Science and Industry, 43(2), pp.2~23 (2010)[DOI]
  12. Jakob A. Shimshoni, "Pesticide distribution and depletion kinetic determination in honey and beeswax: Model for pesticide occurrence and distribution in beehive products", PLOS ONE, 14(2), pp.e0212631~ (2019), Public Library of Science (PLoS)[DOI]
  13. 이강범, "충남도내 유통 과일류의 잔류농약 안전성 조사", 한국식품위생안전성학회지, 34(5), pp.421~430 (2019), 한국식품위생안전성학회[DOI]
  14. Gabriela Svartz, "Differential sensitivity of developmental stages of the South American toad to a fungicide based on fludioxonil and metalaxyl-M", Environmental Science and Pollution Research, 25(24), pp.23857~23863 (2018), Springer Science and Business Media LLC[DOI]
  15. Jana Pavelková, "Efficacy of fosetyl-Al, propamocarb, dimethomorph, cymoxanil, metalaxyl and metalaxyl-M in Czech Pseudoperonospora cubensis populations during the years 2005 through 2010", Crop Protection, 60, pp.9~19 (2014), Elsevier BV[DOI]
  16. 김아름누리, "네오니코티노이드계 4종 농약의 서양뒤영벌 급성 접촉 및 섭식 독성평가", 한국환경농학회지, 39(2), pp.106~113 (2020), 한국환경농학회[DOI]
  17. 부경환, "시설재배 아스파라거스 중 살충제 dinotefuran의 잔류특성", 한국산학기술학회논문지, 19(6), pp.375~381 (2018), 한국산학기술학회[DOI]
  18. Eiki Watanabe, "Analytical evaluation of enzyme-linked immunosorbent assay for neonicotinoid dinotefuran for potential application to quick and simple screening method in rice samples", Talanta, 84(4), pp.1107~1111 (2011), Elsevier BV[DOI]
  19. Kevin A. Ford, "Comparative Metabolism and Pharmacokinetics of Seven Neonicotinoid Insecticides in Spinach", Journal of Agricultural and Food Chemistry, 56(21), pp.10168~10175 (2008), American Chemical Society (ACS)[DOI]
  20. Xiaoxin Chen, "Simultaneous determination of pyridaben, dinotefuran, DN and UF in eggplant ecosystem under open-field conditions: Dissipation behaviour and residue distribution", Chemosphere, 195, pp.245~251 (2018), Elsevier BV[DOI]
  21. Chang-Hwan Oh, "Monitoring of Residual Pesticides in Herbal Drug Materials of Korea and China", Bulletin of Environmental Contamination and Toxicology, 82(5), pp.639~643 (2009), Springer Science and Business Media LLC[DOI]
  22. Gunjan Pandey, "Biotransformation of the neonicotinoid insecticides imidacloprid and thiamethoxam by Pseudomonas sp. 1G", Biochemical and Biophysical Research Communications, 380(3), pp.710~714 (2009), Elsevier BV[DOI]
  23. Wei Yao, "Multi-residue Analysis of 34 Pesticides in Black Pepper by QuEChERS with d-SPE Vs. d-SLE Cleanup", Food Analytical Methods, 12(1), pp.176~189 (2018), Springer Science and Business Media LLC[DOI]
  24. J.-M. Bonmatin, "Environmental fate and exposure; neonicotinoids and fipronil", Environmental Science and Pollution Research, 22(1), pp.35~67 (2014), Springer Science and Business Media LLC[DOI]
  25. 이유진, "기능성 쌀의 잔류농약 및 이산화황 안전성 실태조사", 한국식품위생안전성학회지, 32(6), pp.493~499 (2017), 한국식품위생안전성학회[DOI]
  26. 전종섭, "인천광역시 유통 농산물의 최근 3년간의 잔류농약 실태 조사연구", 한국환경농학회지, 25(2), pp.180~189 (2006), 한국환경농학회

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