비소 오염 토양의 복원을 위한 자철석과 바닥재 활용
Remediation of As-contaminated Soil Using Magnetite and Bottom Ash
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BACKGROUND: Mining activities, smelter discharges, and sludges are the major sources of heavy metal contamination to soils. The objective of this study was to determine the efficiency of magnetite and bottom ash derived from coal ash in remediating As-contaminated soil. METHODS AND RESULTS: An incubation experiment was conducted for 10 weeks. Magnetite and bottom ash at different rates and ratios were applied to each plastic bottle repacked with 1,000 g of dried As-contaminated soil. After 3-weeks of incubation, the concentrations of available As were measured by using Mehlich-3, SBET, and sequential extraction methods. All of the subjected soil amendments resulted in significant decreases in available As concentration compared to the controls. The addition of magnetite at the highest rate was the best to stabilize As in the soils; however, the values of As concentration varied with the extraction methods. CONCLUSION(S): To ensure the stabilization accuracy of heavy metals in soil, both single and sequential extractions are recommended. The magnetite derived from fly coal ash can also be applicable as a heavy metal stabilizer for the As-contaminated soil.
Abstract
BACKGROUND: Mining activities, smelter discharges, and sludges are the major sources of heavy metal contamination to soils. The objective of this study was to determine the efficiency of magnetite and bottom ash derived from coal ash in remediating As-contaminated soil. METHODS AND RESULTS: An incubation experiment was conducted for 10 weeks. Magnetite and bottom ash at different rates and ratios were applied to each plastic bottle repacked with 1,000 g of dried As-contaminated soil. After 3-weeks of incubation, the concentrations of available As were measured by using Mehlich-3, SBET, and sequential extraction methods. All of the subjected soil amendments resulted in significant decreases in available As concentration compared to the controls. The addition of magnetite at the highest rate was the best to stabilize As in the soils; however, the values of As concentration varied with the extraction methods. CONCLUSION(S): To ensure the stabilization accuracy of heavy metals in soil, both single and sequential extractions are recommended. The magnetite derived from fly coal ash can also be applicable as a heavy metal stabilizer for the As-contaminated soil.
참고문헌 (21)
- 안진성, "(구)장항제련소 주변 송림숲 등 식생지역에서의 비소오염토양 위해도 저감 조치: 안정화 공법 적용성 평가 및 사후관리 계획", 지하수토양환경, 22(6), pp.1~11 (2017), 한국지하수토양환경학회[DOI]
- Jinsung An, "Evaluation of the effectiveness of in situ stabilization in the field aged arsenic-contaminated soil: Chemical extractability and biological response", Journal of Hazardous Materials, 367, pp.137~143 (2019), Elsevier BV[DOI]
- Kamil Banaszkiewicz, "Fly Ash as an Ingredient in the Contaminated Soil Stabilization Process", Energies, 15(2), pp.565~ (2022), MDPI AG[DOI]
- Young-Kyu Hong, "Effect of Combined Soil Amendment on Immobilization of Bioavailable As and Pb in Paddy Soil", Toxics, 10(2), pp.90~ (2022), MDPI AG[DOI]
- 정슬기, "화학적 추출법에 따른 (구)장항제련소 주변 토양의 중금속 오염특성 분석과 식물 전이 가능량 예측", 지하수토양환경, 16(1), pp.42~50 (2011), 한국지하수토양환경학회
- Mahatheva Kalaruban, "Iron-impregnated granular activated carbon for arsenic removal: Application to practical column filters", Journal of Environmental Management, 239, pp.235~243 (2019), Elsevier BV[DOI]
- Eun Jung Kim, "Arsenic speciation and bioaccessibility in arsenic-contaminated soils: Sequential extraction and mineralogical investigation", Environmental Pollution, 186, pp.29~35 (2014), Elsevier BV[DOI]
- Min-Suk Kim, "Assessment of Fraction and Mobility of Arsenic in Soil Near the Mine Waste Dam", Sustainability, 12(4), pp.1480~ (2020), MDPI AG[DOI]
- Min-Yong Lee, "Environmental Assessment of Recycling (EAoR) for Safe Recycling of Steelmaking Slag in the Republic of Korea: Applications, Leaching Test, and Toxicity", Sustainability, 13(16), pp.8805~ (2021), MDPI AG[DOI]
- 이종철, "국내 토양오염물질 분포 특성 및 중금속 오염도 평가", 한국환경농학회지, 41(1), pp.9~15 (2022), 한국환경농학회[DOI]
- Jining Li, "Arsenic immobilization and removal in contaminated soil using zero-valent iron or magnetic biochar amendment followed by dry magnetic separation", Science of The Total Environment, 768, pp.144521~ (2021), Elsevier BV[DOI]
- A. Mehlich, "Mehlich 3 soil test extractant: A modification of Mehlich 2 extractant", Communications in Soil Science and Plant Analysis, 15(12), pp.1409~1416 (1984), Informa UK Limited[DOI]
- 오세진, "Coal Bottom Ash Application on Park Site Soil and Its Impacts on Turfgrass Growth and Soil Quality", 한국토양비료학회지(Korean Journal of Soil Science and Fertilizer), 50(2), pp.127~134 (2017), 한국토양비료학회[DOI]
- Jinhee Park, "Reduction of bioaccessibility of As in soil through in situ formation of amorphous Fe oxides and its long-term stability", Science of The Total Environment, 745, pp.140989~ (2020), Elsevier BV[DOI]
- Jinhee Park, "Effect of neutralizing agents on the type of As co-precipitates formed by in situ Fe oxides synthesis and its impact on the bioaccessibility of As in soil", Science of The Total Environment, 743, pp.140686~ (2020), Elsevier BV[DOI]
- Rozineide A. Antunes Boca Santa, "Geopolymers with a high percentage of bottom ash for solidification", immobilization of different toxic metals, 2016, pp.318, 145~153[DOI]
- Senila M, "Simulated bioavailability of heavy metals (Cd, Cr, Cu, Pb, Zn) in contaminated soil amended with natural zeolite using diffusive gradients in thin-films (DGT) Technique", Agriculture, 12, pp.321~ (2022)[DOI]
- Yuliang Tu, "Field demonstration of on-site immobilization of arsenic and lead in soil using a ternary amending agent", Journal of Hazardous Materials, 426, pp.127791~ (2022), Elsevier BV[DOI]
- Walkley A, "An examination of the Degtjareffmethod for determining soil organic matter, and a proposed modification of the chromic acid titration method", Soil Science, 37, pp.29~38 (1934)
- Kaikai Wu, "Remediation of arsenic-contaminated paddy field by a new iron oxidizing strain (Ochrobactrum sp.) and iron-modified biochar", Journal of Environmental Sciences, 115, pp.411~421 (2022), Elsevier BV[DOI]
- Xiaorui Zhang, "Synergistic effects of iron (Fe) and biochar on light-weight geopolymers when used in wastewater treatment applications", Journal of Cleaner Production, 322, pp.129033~ (2021), Elsevier BV[DOI]
