Electrocatalytic Reduction of Hydrogen Peroxide at Nanoporous Gold Surfaces
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
We report on the electrocatalytic reduction of hydrogen peroxide at nanoporous gold (NPG) surfaces. Various NPG surfaces with different surface structure were prepared by changing the conditions of electrodeposition for Ag-Au layers such as the concentration ratios of KAu(CN)2 over KAg(CN)2 and deposition charges. The effects of different electrochemical conditions on the electrocatalysis of H2O2 reduction were investigated. The NPG surfaces exhibited sensitive amperometric responses for H2O2 reduction, from which calibration plots with higher sensitivity than a bare Au surface were obtained.
Abstract
We report on the electrocatalytic reduction of hydrogen peroxide at nanoporous gold (NPG) surfaces. Various NPG surfaces with different surface structure were prepared by changing the conditions of electrodeposition for Ag-Au layers such as the concentration ratios of KAu(CN)2 over KAg(CN)2 and deposition charges. The effects of different electrochemical conditions on the electrocatalysis of H2O2 reduction were investigated. The NPG surfaces exhibited sensitive amperometric responses for H2O2 reduction, from which calibration plots with higher sensitivity than a bare Au surface were obtained.
참고문헌 (13)
- M. C. Daniel, "Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology", Chem. Rev., 104, pp.293~ (2004)
- A. Wittstock, "Nanoporous Gold Catalysts for Selective Gas- Phase Oxidative Coupling of Methanol at Low Temperature", Science, 327, pp.319~ (2010)
- Y. Ding, "Nanoporous metals with controlled multimodal pore size distribution", J. Am. Chem. Soc., 125, pp.7772~ (2003)
- J. Erlebacher, "Evolution of nanoporosity in dealloying", Nature, 410, pp.450~ (2001)
- Z. Liu, "Electrocatalytic oxidation of d-glucose at nanoporous Au and Au-Ag alloy electrodes in alkaline aqueous solutions", Electrochim. Acta, 54, pp.7286~ (2009)
- L. H. Qian, "Surface enhanced Raman scattering of nanoporous gold: Smaller pore sizes stronger enhancements", Appl. Phys. Lett., 90 (2007)
- Z. Liu, "Electrochemical sensor for detection of p-nitrophenol based on nanoporous gold", Electrochem. Commun., 11, pp.1365~ (2009)
- H. J. Qiu, "A novel nanoporous gold modified electrode for the selective determination of dopamine in the presence of ascorbic acid", Colloid Surf. B-Biointerfaces, 69, pp.105~ (2009)
- K. C. Hu, "Electrochemical DNA Biosensor Based on Nanoporous Gold Electrode and Multifunctional Encoded DNA-Au Bio Bar Codes", Anal. Chem., 80, pp.9124~ (2008)
- C. X. Ji, "Synthesis and characterization of nanoporous gold nanowires", J. Phys. Chem. B, 107, pp.4494~ (2003)
- B. Seo, "Electrooxidation of Glucose at Nanoporous Gold Surfaces: Structure Dependent Electrocatalysis and Its Application to Amperometric Detection", Electroanalysis, 22, pp.939~ (2010)
- R. Zeis, "Catalytic reduction of oxygen and hydrogen peroxide by nanoporous gold", J. Catal., 253, pp.132~ (2008)
- S. Trasatti, "Real surface-area measurements in electrochemistry", Pure Appl. Chem., 63, pp.711~ (1991)
