Consideration on the Non-linearity of Warburg Impedance for Fourier Transform Electrochemical Impedance Spectroscopy
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Here I report on how Fourier Transform Electrochemical Impedance Spectroscopy(FTEIS) overcomes the potential-current linearity problem encountered in the impedance calculationprocess. FTEIS was first invented to solve the time-related drawback of the conventionalimpedance technique. The dramatic time reduction of FTEIS enabled the real-timeimpedance measurement but brought about the linearity problem at the same time. While theconventional method circumvents the problem using the steady-state made by a sufficiently longmeasurement time, FTEIS cannot because of its real-time function. However, according to themathematical development reported in this article, the potential step used in FTEIS is provedto avoid the linearity problem. During the step period, the potential and the current are linearizedby the electrochemical impedance. Also, Fourier transform of the differentiated potentialand current is proved to give the same result of the original ones.
Abstract
Here I report on how Fourier Transform Electrochemical Impedance Spectroscopy(FTEIS) overcomes the potential-current linearity problem encountered in the impedance calculationprocess. FTEIS was first invented to solve the time-related drawback of the conventionalimpedance technique. The dramatic time reduction of FTEIS enabled the real-timeimpedance measurement but brought about the linearity problem at the same time. While theconventional method circumvents the problem using the steady-state made by a sufficiently longmeasurement time, FTEIS cannot because of its real-time function. However, according to themathematical development reported in this article, the potential step used in FTEIS is provedto avoid the linearity problem. During the step period, the potential and the current are linearizedby the electrochemical impedance. Also, Fourier transform of the differentiated potentialand current is proved to give the same result of the original ones.
참고문헌 (22)
- B.-Y. Chang, , Annu. Rev. Anal. Chem, 3, pp.207~229 (2010)
- 조하나, "자가조립 단층 전극에 대한 순환전위법의 특성해석Characteristic Analysis of Cyclic Voltammetry on a Self-Assembled Mono-layer Electrode", 전기화학회지, 16(4), pp.217~224 (2013), 한국전기화학회
- 천진영, "Determination of the Frumkin and Temkin Adsorption Isotherms of Underpotentially Deposited Hydrogen at Pt Group Metal Interfaces Using the Standard Gibbs Energy of Adsorption and Correlation Constants", 전기화학회지, 16(4), pp.211~216 (2013), 한국전기화학회
- 조운, "쌀밥으로 제조된 활성탄을 사용하는 전기이중층형 슈퍼커패시터 전극의 전기화학적 특성", 전기화학회지, 16(3), pp.129~137 (2013), 한국전기화학회
- 조하나, "확산모델을 이용한 다중전자 전극반응에 대한 순환전위법의 전산모델링", 전기화학회지, 15(3), pp.165~171 (2012), 한국전기화학회
- 김승기, "유리염소 측정을 위한 일회용 스트립 센서", 전기화학회지, 15(4), pp.242~248 (2012), 한국전기화학회
- M. Sluyters-Rehbach, , J. Electroanal. Chem, 102, pp.415~419 (1979)
- Z.B. Stoynov, , Electrochim. Acta, 37, pp.2357~2359 (1992)
- A.M. Bond, , Anal. Chem, 77, pp.186A~195A (2005)
- G.A. Ragoisha, , Electrochemistry Communications, 5, pp.392~395 (2003)
- S.M. Park, , Anal. Chem, 75, pp.455A~461A (2003)
- B.-Y. Chang, , Anal. Chem, 79, pp.4892~4899 (2007)
- J.-Y. Park, , Anal. Chem, 81, pp.3843~3850 (2009)
- J.-Y. Park, , Anal. Chem, 82, pp.8342~8348 (2010)
- R. Jurczakowski, , Anal. Chem, 76, pp.5033~5038 (2004)
- A.J. Bard, "Electrochemical Methods: Fundamentals and Applications" (2002), Wiley
- A. Lasia, "Modern Aspects of Electrochemistry" (1999), Plenum Press
- E. Barsoukov, "Impedance spectroscopy: theory, experiment, and applications" (2005), Wiley- Interscience
- K.-M. Nam, , Analytical Chemistry, 85, pp.2246~2252 (2013)
- P. Delahay, , Anal. Chem, 27, pp.478~483 (1955)
- P. Delahay, , J. Am. Chem. Soc, 75, pp.1430~1435 (1953)
- E. Kreyzig, "Advanced Engineering Mathematics" (2011), Laurie Rosatone