Physioelectrochemical Investigation of Electrocatalytic Activity of Modified Carbon Paste Electrode in Alcohol Oxidation as Anode in Fuel Cell
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Methanol electro oxidation on the surface of carbon paste modified by NiCl2/6H2Owas studied in 1M NaOH by potentiostatic and potentiodynamic methods. Ni/C catalyst bythe concentration of 5% Ni showed about twice higher electro catalytic activity than Ni metal. The amount of monolayer’s on the surface of electrode is almost one order higher for Ni/Cthan Ni electrode. The kinetic parameters and the diffusion coefficient of methanol were derivedfrom chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) measurements
Abstract
Methanol electro oxidation on the surface of carbon paste modified by NiCl2/6H2Owas studied in 1M NaOH by potentiostatic and potentiodynamic methods. Ni/C catalyst bythe concentration of 5% Ni showed about twice higher electro catalytic activity than Ni metal. The amount of monolayer’s on the surface of electrode is almost one order higher for Ni/Cthan Ni electrode. The kinetic parameters and the diffusion coefficient of methanol were derivedfrom chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) measurements
참고문헌 (41)
- G. Cacciola, , J. PowerSources, 100, pp.67~ (2001)
- J. M. Andu’ jar, , Renew Sust Energ Rev, 13, pp.2309~ (2009)
- J. Ge, , J. Power Sources, 142, pp.56~ (2005)
- I. Danaee, , Electrochim Acta, 55, pp.2093~ (2010)
- G. Orozco, , J. Electro Anal Chem, 495, pp.71~ (2000)
- L. Jiang, , Int J. HydrogenEnerg, 35, pp.365~ (2010)
- Xu Yuan hang, , J. ElectroanalChem, 398, pp.95~ (1995)
- S. Berchmans, , J.Electroanal Chem, 394, pp.267~ (1995)
- F. Vogel, , J. Supercrit Fluid, 34, pp.249~ (2005)
- I. Beceryk, , J. ElectroanalChem, 502, pp.118~ (2001)
- T. Okada, , ElectrochimActa, 51, pp.1130~ (2005)
- H. Heli, , Electrochim Acta, 49, pp.4999~ (2004)
- A. Aramata, , Electrochim Acta, 36, pp.1043~ (1991)
- C. H. Lee, , J. Power Sources, 86, pp.478~ (2000)
- W. Tokarz, , ElectrochimActa, 52, pp.5565~ (2007)
- I. Danaee, , Int. J. Hydrogen Energ, 34, pp.859~ (2009)
- M. A. Abdel Rahim, , J. Power Sources, 134, pp.160~ (2004)
- A. Nozad Golikand, , J. Electroanal Chem, 588, pp.155~ (2006)
- J. Raoof, , J. ElectroanalChem, 633, pp.153~ (2009)
- R. Ojani, , J. Solid State Electr, 13, pp.927~ (2009)
- R. Ojani, , J. ElectroanalChem, 571, pp.1~ (2004)
- J. Taraszewska, , J. Electroanal Chem, 364, pp.209~ (1994)
- R. M. Van Effen, , J. Electroanal Chem, 103, pp.383~ (1979)
- A. J. Motheo, , J. Brazil Chim Soc, 5, pp.161~ (1994)
- M. Fleischmann, , J. ElectroanalChem, 31, pp.39~ (1971)
- A. A. El-Shafei, , J. Electroanal Chem, 471, pp.89~ (1999)
- A. Hamnett, , CATAL TODAY, 38, pp.445~ (1997)
- A. Ehsani, , J. PowerSources, 257, pp.300~ (2014)
- M. Nasrollahzadeh, , Ultrasound Sonochem, 21, pp.275~ (2014)
- A. Ehsani, , AppliedSurface Science, 283, pp.1060~ (2013)
- A. Ehsani, , J. Electroanal.Chem, 710, pp.29~ (2013)
- M. Mahjani, , SYNTH. METH, 160, pp.1252~ (2010)
- Ali Ehsani, "Electrochemical and quantum chemical investigation of inhibitory of 1,4-Ph(OX)2(Ts)2 on corrosion of 1005 aluminum alloy in acidic medium", Journal of Industrial and Engineering Chemistry, 20(6), pp.4363~4370 (2014), 한국공업화학회
- A. Ehsani, , RSC Adv, 38, pp.20031~20037 (2014)
- A. Ehsani, , Journalof Chemistry, 35, pp.1~ (2011)
- A. Ehsani, , Progress Organic Coating, 69, pp.510~ (2010)
- A. Ehsani, , Synth Met, 161, pp.1760~ (2011)
- A. Ehsani, , SynthMet, 162, pp.199~ (2012)
- A. Ehsani, , Electrochim Acta, 71, pp.128~ (2012)
- A. R. Feizbakhsh, , J. Chiness Chem. Soc, 59, pp.1086~ (2012)
- A. Ehsani, , J. Electroanal Chem, 713, pp.91~ (2014)