Electrochemical Behavior of TiO2 Nanotube/Ti Prepared by Anodizing for Micro-Lithium Ion Batteries
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
The TiO2 nanotube/Ti electrode are used as an anode in thin-film lithium microbatteriesis known to have high oxidation-reduction potential of 1.8 V (vs. Li/Li+). It can preventfrom dendrite growth of lithium during charging. The TiO2 nanotube/Ti electrode was preparedby anodizing at constant voltages for thin-film lithium microbatteries. The capacities of TiO2nanotube/Ti anode prepared by anodizing at 10 V, 20 V and 30 V were observed to be23.9 μAh cm−2, 43.1 μAh cm−2 and 74.0 μAh cm−2. We identified it was found that the capacityof TiO2 nanotube/Ti increases with increasing anodizing voltage and the anatase structure ofTiO2 nanotube/Ti compared with amorphous structure has batter cycle performance than amorphousTiO2 nanotube/Ti.
Abstract
The TiO2 nanotube/Ti electrode are used as an anode in thin-film lithium microbatteriesis known to have high oxidation-reduction potential of 1.8 V (vs. Li/Li+). It can preventfrom dendrite growth of lithium during charging. The TiO2 nanotube/Ti electrode was preparedby anodizing at constant voltages for thin-film lithium microbatteries. The capacities of TiO2nanotube/Ti anode prepared by anodizing at 10 V, 20 V and 30 V were observed to be23.9 μAh cm−2, 43.1 μAh cm−2 and 74.0 μAh cm−2. We identified it was found that the capacityof TiO2 nanotube/Ti increases with increasing anodizing voltage and the anatase structure ofTiO2 nanotube/Ti compared with amorphous structure has batter cycle performance than amorphousTiO2 nanotube/Ti.
참고문헌 (15)
- P. G. Bruce, "Nanomaterials for Rechargeable Lithium Batteries’", Angew. Chem., Int. Ed, 47, pp.2930~ (2008)
- J. B. Bates, "Rechargeable thin-film lithium batteries", Solid State Ionics, 71, pp.619~ (1994)
- K. H. Hwang, "Fabrication and characterization of LiMnO thin-film cathode for rechargeable lithium microbatteries", J. Power Sources, 54, pp.224~ (1995)
- K. Kushida, "Hundred-micronsized all-solid-state Li secondary battery arrays embedded in a Si substrate", Appl. Phys. Lett, 81, pp.5066~ (2002)
- J. B. Bates, "Thin-film rechargeable lithium batteries", J. Power Sources, 54, pp.58~ (1995)
- K. S. Han, "Soft solution processing for fabrication of lithiated thin-film electrodes in a single synthetic step", J. Mater. Chem, 8, pp.2043~ (1998)
- J. M. Macak, "Multilayer TiO2-Nanotube Formation by Two-Step Anodization", Electrochemical and Solid-state Letters, 10, pp.K28~ (2007)
- J. M. Macak, "High-Aspect-Ratio TiO2 Nanotubes by Anodization of Titanium", Angew. Chem., Int. Ed, 44, pp.2100~ (2005)
- S. P. Albu, "Self-organized, free-standing TiO2 nanotube membrane for flow-through photocatalytic applications", Nano Lett, 7, pp.1286~ (2007)
- G. K. Mor, "Use of Highly-Ordered TiO2 Nanotube Arrays in Dye-Sensitized Solar Cells", Nano Lett, 6, pp.215~ (2006)
- Z. Wei, "Solvothermal Growth of Well-Aligned TiO2 Nanowire Arrays for Dye-Sensitized Solar Cell: Dependence of Morphology and Vertical Orientation Upon Substrate Pretreatment", Int. J. Electrochem. Sci, 6, pp.1871~ (2011)
- H. Furukawa, "Electrochemical Properties of Nanostructured Amorphous, Sol-gel-Synthesized TiO2", Acetylene Black Composite Electrodes, 2004, pp.151, A527~
- H. Yamada, "Porous TiO2 (anatase) Electrodes for High-Power Batteries", Chem. Lett, 33, pp.1548~ (2004)
- Z. Y. Wang, "Preparation and Li-Intercalation Properties of Mesoporous Anatase- TiO2 Sphere", Electrochem. Solid-State Lett, 10, pp.A77~ (2007)
- A. Hagfeldt, "Fast electrochromic switching with nanocrystalline oxide semiconductor films", J. Electrochem. Soc, 141, pp.L82~ (1994)
