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산소 발생 반응 용 전기화학촉매로 사용되는 CoFe2O4 나노 입자 합성 및 특성 분석

Synthesis of CoFe2O4 Nanoparticles as Electrocatalyst for Oxygen Evolution Reaction

이주영|김글한|양주찬|박유세|장명제|최승목
한국전기화학회 (The Korean Electrochemical Society)|2020.11|전기화학회지 (Journal of the Korean Electrochemical Society)|제23권 제4호|pp. 97-104|DOI 10.5229/JKES.2020.23.4.97

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키워드

Oxygen Evolution ReactionTransition MetalOxideInverse Spinel StructureNanoparticle
주제분류화학

초록

전기 물 분해 기술 중 주요 과제 중 하나는 귀금속의 Ir과 Ru 기반의 촉매를 대체할 수 있는고성능, 저비용의 산소 발생 반응 (OER) 촉매를 개발하는 것이다. 본 연구에서는 CoSO4와Fe(NO3)3 수용액을 1차 가열 후 KNO3와 NaOH 추가 반응을 이용한 침전법을 이용하여 OER 촉매로 사용 가능한 역스피넬 구조의 약 44 nm 크기를 갖는 CoFe2O4 나노 입자를 합성하였다. CoFe2O4 나노 입자의 합성 시간을 조절하여 입자 및 결정립 크기를 제어하였다. CoFe2O4 나노 입자의 합성 시간이 6시간일 때, 높은 전도성과 전기 화학 표면적을 가졌다. 이 CoFe2O4 (6 h)는 전류 밀도 10 mA/cm2의 과전압 및 Tafel slope는 각각 395 mV 및 52 mV/dec으로 나타났다. 또한, 이 촉매는 10 mA/cm2에서 18시간 동안 우수한 내구성을 나타냈다.

Abstract

One of the main challenges of electrochemical water splitting technology is to develop a high performance, low cost oxygen-evolving electrode capable of substituting a noble metal catalyst, Ir or Ru based catalyst. In this work, CoFe2O4 nanoparticles with sub-44 nmsize of a inverse spinel structure for oxygen evolution reaction (OER) were synthesized by the injection of KNO3 and NaOH solution to a preheated CoSO4 and Fe(NO3)3 solution. The synthesis time of CoFe2O4 nanoparticles was controlled to control particle and crystallite size. When the synthesis time was 6 h, CoFe2O4 nanoparticles had high conductivity and electrochemical surface area. The overpotential at current denstiy of 10 mA/cm2 and Tafel slope of CoFe2O4 (6h) were 395 mV and 52 mV/dec, respectively. In addition, the catalyst showed excellent durability for 18 hours at 10 mA/cm2.

참고문헌 (49)

  1. D. M. F. Santos, "Hydrogen production by alkaline water electrolysis", Quim. Nova, 36, pp.1176~1193 (2013)
  2. M. M. Rashid, "Hydrogen Production by Water Electrolysis: A Review of Alkaline Water Electrolysis, PEM Water Electrolysis and High Temperature Water Electrolysis", Int. J. Eng. Technol, 4, pp.2249~8958 (2015)
  3. E. Rios, "Mixed valency spinel oxides of transition metals and electrocatalysis: case of the MnxCo3xO4system", Electrochim. Acta, 44, pp.1491~1497 (1998)
  4. C. -C. Kuo, "Redox preparation of mixed-valence cobalt manganese oxide nanostructured materials: highly efficient noble metalfree electrocatalysts for sensing hydrogen peroxide", Nanoscale, 6, pp.334~341 (2014)
  5. T. Audichon, "IrO2 Coated on RuO2 as Efficient and Stable Electroactive Nanocatalysts for Electrochemical Water Splitting", J. Phys. Chem. C, 120, pp.2562~2573 (2016)
  6. H. Osgood, "Transition metal (Fe, Co, Ni, and Mn) oxides for oxygen reduction and evolution bifunctional catalysts in alkaline media", Nano Today, 11, pp.601~625 (2016)
  7. J. Y. C. Chen, "Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion", Energy Environ. Sci, 7, pp.1382~1386 (2014)
  8. M. O. Tolentino, "Bifunctional electrocatalysts for oxygen reduction", evolution reactions derived from NiCoFe LDH materials, 2018, pp.48, 947~957
  9. J. Béjar, "An advanced three-dimensionally ordered macroporous NiCo2O4 spinel as a bifunctional electrocatalyst for rechargeable Zn–air batteries", J. Mater. Chem. A, 8, pp.8554~8565 (2020)
  10. H. Zhu, "Monodisperse MxFe3−xO4 (M = Fe, Cu, Co, Mn)Nanoparticles and Their Electrocatalysis for Oxygen Reduction Reaction", Nano Lett, 13, pp.2947~2951 (2013)
  11. B. Cui, "Core-Ring Structured NiCo2O4 Nanoplatelets: Synthesis, Characterizagtion, and Electrocatalytic Applications", Adv. Funct. Mater, 18, pp.1440~1447 (2008)
  12. F. Cheng, "Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts", Chem. Soc. Rev, 41, pp.2172~2192 (2012)
  13. C. Si, "Mesoporous nanostructured spinel-type MFe2O4(M = Co, Mn, Ni) oxides as efficient bi-functional electrocatalysts towards oxygen reduction and oxygen evolution", Electrochim. Acta, 245, pp.829~838 (2017)
  14. M. Li, "Facile synthesis of electrospun MFe2O4 (M =Co, Ni, Cu, Mn) spinel nanofibers with excellent electrocatalytic properties for oxygen evolution and hydrogen peroxide reduction", Nanoscale, 7, pp.8920~8930 (2015)
  15. H. Zeng, "Shape-Controlled Synthesis and Shape-Induced Texture of MnFe2O4 Nanoparticles", J. am. Chem. Soc, 126, pp.11458~11459 (2004)
  16. R. N. Singh, "Effect of partial substitution of Cr on electrocatalytic properties ofMnFe2O4 towards O2 evolution in alkaline medium", Int. J. Hydrog. Energy, 31, pp.1372~1378 (2006)
  17. X. Wu, "Mesoporous Hollow Nitrogen-Doped Carbon Nanospheres with Embedded MnFe2O4", Fe Hybrid Nanoparticles as Efficient Bifunctional Oxygen Electrocatalysts in Alkaline Media, 2018, pp.10, 20440~20447
  18. Z. Zhang, "One-pot synthesis of MnFe2O4", C by microwave sintering as anefficient bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions, 2019, pp.786, 565~567
  19. D. M. Fernandes, "MnFe2O4@CNT-N as novel electrochemical nanosensor fordetermination of caffeine, acetaminophen and ascorbic acid", Sens. Actuators B Chem, 218, pp.128~136 (2015)
  20. S. Khilari, "MnFe2O4@nitrogen-doped reduced graphene oxide nanohybrid: an efficient bifunctional electrocatalyst for anodic hydrazine oxidation and cathodic oxygen reduction", Catal. Sci. Technol, 7, pp.5920~5931 (2017)
  21. W. Bian, "A CoFe2O4", graphene nanohybrid as an efficient bi-functional electrocatalyst for oxygen reduction and oxygen evolution, 2014, pp.250, 196~203
  22. M. I. Godinho, "Effect of the partial replacement of Fe by Ni and", or Mn on theelectrocatalytic activity for oxygen evolution of the CoFe2O4spineloxide electrod, 2002, pp.47, 4307~4314
  23. W. Yan, "Nitrogen", sulfur dual-doped 3D reduced graphene oxide networks-supported CoFe2O4with enhanced electrocatalytic activities foroxygen reduction and evolution reactions, 2016, pp.99, 195~202
  24. Xue-Feng L., "Bimetal-Organic Framework Derived CoFe2O4", C Porous Hybrid Nanorod Arrays as High-Performance Electrocatalysts for Oxygen Evolution Reaction, 2017, pp.29, 1604437~
  25. W. Yan, "An Efficient Bi-functional Electrocatalyst Based on Strongly CoupledCoFe2O4", Carbon Nanotubes Hybrid for Oxygen Reduction and Oxygen Evolution, 2015, pp.177, 65~72
  26. R. N. Singh, "Electrocatalytic activity of electrodeposited composite films of polypyrrole and CoFe2O4nanoparticles towards oxygen reduction reaction", Electrochim. Acta, 49, pp.4605~4612 (2004)
  27. C. Mahala, "2D Nanostructures of CoFe2O4 and NiFe2O4: Efficient Oxygen Evolution Catalyst", Electrochim. Acta, 273, pp.462~473 (2018)
  28. T. Zhang, "Spinel CoFe2O4supported by three dimensional graphene as high-performance bi-functional electrocatalysts for oxygen reduction and evolution reaction’", Int. J. Hydrog. Energy, 44, pp.1610~1619 (2019)
  29. G. Zhum X. Li, "Activating CoFe2O4electrocatalysts by trace Au for enhanced oxygen evolution activity", Appl. Surf. Sci, 478, pp.206~212 (2019)
  30. X. Zhao, "Ni-doped CoFe2O4Hollow Nanospheres as Efficient Bifunctional Catalysts", Electrochim. Acta, 201, pp.172~178 (2016)
  31. K. M. Naik, "Two-step oxygen reduction on spinel NiFe2O4catalyst: Rechargeable,aqueous solution- and gel-based, Zn-air batteries", Electrochim. Acta, 292, pp.268~275 (2018)
  32. W. Hu, "Threedimensional ordered microporous IrO2 as electrocatalyst for oxygen evolution reaction in acidic medium", J. Mater. Chem, 22, pp.6010~6016 (2012)
  33. S. Du, "Co3O4 nanocrystal ink printed on carbon fiber paper as a large-area electrode for electrochemical water splitting", Chem. Commun, 51, pp.8066~8069 (2015)
  34. N. B. Halck, "Beyond the volcano limitations in electrocatalysis –oxygen evolution reaction", Phys. Chem. Chem. Phys, 16, pp.13682~13688 (2014)
  35. S. T. Hunt, "Activating earth-abundant electrocatalysts for efficient, low-cost hydrogen evolution", oxidation: sub-monolayer platinum coatings on titanium tungsten carbide nanoparticles, 2016, pp.9, 3290~3301
  36. R. T. Olsson, "Making flexible magnetic aerogels and stiff magnetic nanopaper using cellulose mano fibrils as templates", Nat. Nanotechnol, 5, pp.584~588 (2010)
  37. R. Yang, "Nano-scale pore structure and fractal dimension of organic-rich Wufeng-Longmaxi shale from Jiaoshiba area, Sichuan Basin:Investigations using FE-SEM, gas adsorption and helium pycnometry", Mar Pet Geol, 70, pp.27~45 (2016)
  38. M. Peumans, "Porcelain veneers bonded to tooth structure: an ultra-morphological FE-SEM examination of the adhesive interface", Dent Mater, 15, pp.105~119 (1999)
  39. M. Morcrette, "In sity X-ray diffraction techniques as a powerful tool to study battery electrode materials", Electrochim. Acta, 47, pp.3137~3149 (2002)
  40. M. R. Fitzsimmons, "Structural characterization of nanometer-sized crystalline Pd by x-ray-diffraction techniques", Phys. Rev. B, 44, pp.2452~2460 (1991)
  41. L. Wu, "Direct Growth of CoFe2 Alloy Strongly Coupling and Oxygen-vacancy-rich CoFe2O4 Porous Hollow Nanofibers:an Efficient Electrocatalyst for Oxygen Evolution Reaction", Energy Thchnol, 6, pp.2350~2357 (2018)
  42. C. Zhang, "Electrodeposited Nanostructured CoFe2O4 for Overall Water Splitting and Supercapacitor Applications", Catalysts, 9, pp.176~ (2019)
  43. K. Liu, "High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction", ACS Nano, 12, pp.158~167 (2018)
  44. C. Mahala, "2D Nanostructures of CoFe2O4 and NiFe2O4: Efficient Oxygen Evolution Catalyst", Electrochimi. Acta, 273, pp.462~473 (2018)
  45. J. S. Sagu, "Electrocatalytic activity of CoFe2O4 thin films prepared by AACVD towards the oxygen evolution reaction in alkaline media", Electrochem. Commun, 87, pp.1~4 (2018)
  46. S. Sun, "Impact of Surface Area in Evaluation of Catalyst Activity", Joule, 2, pp.1019~1027 (2018)
  47. T. Shinagawa, "Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion", Sci. Rep, 5, pp.13801~ (2015)
  48. N. D. Leonard, "Deconvolution of Utilization, Site Density, and Turnover Frequency of Fe−Nitrogen−Carbon Oxygen Reduction Reaction Catalysts Prepared with Secondary N-Precursors", ACS Catal, 8, pp.1640~1647 (2018)
  49. R. Beugré, "Local electrochemistry of nickel (oxy)hydroxide material gradients prepared using bipolar electrodeposition", Electrochim. Acta, 319, pp.331~338 (2019)

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