종이 기반 전기화학 센서의 연구 동향
A Review on Paper-based Electrochemical Sensors
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
신체에 부착하는 웨어러블(wearable) 센서 및 현장 진단 검사(point-of-care testing)가 용이한센서의 필요성이 부각되면서, 종이를 기반으로 하는 센서들이 활발히 연구되어왔다. 종이는 매우저렴하면서도 가볍고 유연할 뿐만 아니라, 표면에 카본과 같은 전도성 물질 및 왁스와 같은 소수성 물질을 입히기 쉽다. 또한, 종이를 이루는 셀룰로오스 섬유에 의한 모세관 현상으로 외부 힘없이 용액의 흐름을 유도할 수 있어 웨어러블 전기화학 센서의 플랫폼으로 특히 주목받고 있다. 이에 따라, 다양한 분석 물질들을 전기화학적인 방법으로 검출하는 종이 기반 센서들이 활발히 개발되어 왔다. 특히, 분석 물질에 따른 전류 값 이외에도, 전기화학 발광현상(electrochemiluminescence) 혹은 전기 변색 물질(electrochromic material)을 도입하여 시각적으로 데이터를 나타내는 센서들도 보고되어 왔다. 이 논문에서는 종이 기반 전기화학 센서들의 제작법 및 다양한 활용 전략을사례 중심으로 소개하였다.
Abstract
With the increasing demand for wearable sensors that are capable of point-of-care testing, paper-based sensors have been extensively studied. Paper is not only extremely costeffective but also lightweight and flexible, and it is easy to apply conductive materials such as carbon and hydrophobic substances like wax to its surface. Moreover, the capillary action caused by cellulose fibers in paper allows the flow of liquid without help from external forces, making paper a particularly promising platform for wearable electrochemical sensors. Accordingly, paper-based sensors for detecting various analytes through electrochemical methods have been actively developed. Recently, paper-based electrochemical sensors that utilize electrochemiluminescence (ECL) or electrochromic materials for the optical read-out have been reported. This review introduces the basic fabrication methods and various application strategies of paperbased electrochemical sensors.
참고문헌 (41)
- E. Noviana, "Electrochemical paper-based devices: sensing approaches and progress toward practical applications", Lab Chip, 20(1), pp.9~ (2019)
- Y. Sun, "Paper-based electrochemical sensor", Electrochem. Sci. Adv, 2, pp.e2100057~ (2022)
- P. B. Deroco, "Paper-based wearable electrochemical sensors: A new generation of analytical devices", Electroanalysis, 35(1), pp.e202200177~ (2023)
- E. Noviana, "Simultaneous electrochemical detection in paper-based analytical devices", Curr. Opin. Electrochem, 23, pp.1~6 (2020)
- A. W. Martinez, "Patterned paper as a platform for inexpensive, low-volume, portable bioassays", Angew. Chem. Int. Ed, 46(8), pp.1318~1320 (2007)
- G. G. Morbioli, "Technical aspects and challenges of colorimetric detection with microfluidic paper-based analytical devices (μPADs) - A review", Anal. Chim. Acta, 970, pp.1~22 (2017)
- L. Su, "A ratiometric fluorescent paper sensor for consecutive color change-based visual determination of blood glucose in serum", New J. Chem, 42(9), pp.6867~6872 (2018)
- J. R. Windmiller, "Wearable electrochemical sensors and biosensors: A review", Electroanalysis, 25(1), pp.29~46 (2013)
- W. Dungchai, "Electrochemical detection for paper-based microfluidics", Anal. Chem, 81(14), pp.5821~5826 (2009)
- N. Colozza, "A wearable origami-like paper-based electrochemical biosensor for sulfur mustard detection", Biosens. Bioelectron, 129, pp.15~23 (2019)
- P. K. Sekhar, "An electrochemical ammonia sensor on paper substrate", J. Electrochem. Soc, 164(4), pp.B113~ (2017)
- T. Kant, "Inkjet-printed paper-based electrochemical sensor with gold nano-ink for detection of glucose in blood serum", New J. Chem, 45(18), pp.8297~8305 (2021)
- O. Amor-Gutiérrez, "Paper-based maskless enzymatic sensor for glucose determination combining ink and wire electrodes", Biosens. Bioelectron, 93, pp.40~45 (2017)
- W. Li, "Fully-drawn origami paper analytical device for electrochemical detection of glucose", Sens. Actuators B Chem, 231, pp.230~238 (2016)
- W. R. de Araujo, "Single-step reagentless laser scribing fabrication of electrochemical paper-based analytical devices", Angew. Chem. Int. Ed, 56(47), pp.15113~15117 (2017)
- T. Pinheiro, "Laser-induced graphene on paper toward efficient fabrication of flexible, planar electrodes for electrochemical sensing", Adv. Mater. Interfaces, 8(22), pp.2101502~ (2021)
- B. Pérez-Fernández, "Electrochemical (bio)sensors for pesticides detection using screen-printed electrodes", Biosensors, 10(4), pp.32~ (2020)
- T. H. da Costa, "A paper-based electrochemical sensor using inkjetprinted carbon nanotube electrodes", ECS J. Solid State Sci. Technol, 4, pp.S3044~ (2015)
- N. Ruecha, "Fully inkjet-printed paper-based potentiometric ionsensing devices", Anal. Chem, 89(19), pp.10608~10616 (2017)
- N. Dossi, "Pencil-drawn paper supported electrodes as simple electrochemical detectors for paper-based fluidic devices", Electrophoresis, 34(14), pp.2085~2091 (2013)
- Z. Li, "Pen-on-paper strategy for point-of-care testing: Rapid prototyping of fully written microfluidic biosensor", Biosens. Bioelectron, 98, pp.478~485 (2017)
- J. Lin, "Laser-induced porous graphene films from commercial polymers", Nat. Commun, 5, pp.5714~ (2014)
- R. Ye, "Laser-induced graphene: From discovery to translation", Adv. Mater, 31(1), pp.1803621~ (2019)
- E. Carrilho, "Understanding wax printing: A simple micropatterning process for paper-based microfluidics", Anal. Chem, 81(16), pp.7091~7095 (2009)
- A. Murphy, "Microfluidic paper analytical device for the chromatographic separation of ascorbic acid and dopamine", RSC Adv, 5(113), pp.93162~93169 (2015)
- K. Kunpatee, "A paper chromatographic-based electrochemical analytical device for the separation and simultaneous detection of carbofuran and carbaryl pesticides", Sens. Actuators B Chem, 377, pp.133116~ (2023)
- A. Yakoh, "3D Capillary-driven paper-based sequential microfluidic device for electrochemical sensing applications", ACS Sens, 4(5), pp.1211~1221 (2019)
- Q. Cao, "Three-dimensional paper-based microfluidic electrochemical integrated devices (3D-PMED) for wearable electrochemical glucose detection", RSC Adv, 9(10), pp.5674~5681 (2019)
- R. Liu, "Open bipolar electrodeelectrochemiluminescence imaging sensing using paperbased microfluidics", Sens. Actuators B Chem, 216, pp.255~262 (2015)
- X., Zhang, "Graphite paper-based bipolar electrode electrochemiluminescence sensing platform", Biosens. Bioelectron, 94, pp.47~55 (2017)
- X. Sun, "Rotational paper-based electrochemiluminescence immunodevices for sensitive and multiplexed detection of cancer biomarkers", Anal. Chim. Acta, 1007, pp.33~39 (2018)
- H. Liu, "Paperbased bipolar electrode electrochemiluminescence switch for label-free and sensitive genetic detection of pathogenic bacteria", Anal. Chem, 88(20), pp.10191~10197 (2016)
- J. Xu, "Colorimetric and electrochemiluminescence dualmode sensing of lead ion based on integrated lab-onpaper device", ACS Appl. Mater. Interfaces, 10(4), pp.3431~3440 (2018)
- F. Wang, "Paper-based closed Au-Bipolar electrode electrochemiluminescence sensing platform for the detection of miRNA-155", Biosens. Bioelectron, 150, pp.111917~ (2020)
- A. Ahmadi, "Electrochemiluminescence paper-based screen-printed electrode for HbA1c detection using two-dimensional zirconium metal-organic framework", Fe3O4 nanosheet composites decorated with Au nanoclusters, 2021, pp.188, 296~
- D. D., "Toward paper-based sensors: Turning electrical signals into an optical readout system", ACS Appl. Mater. Interfaces, 7(34), pp.19201~19209 (2015)
- S. Y. Yeon, "Paper-based electrochromic glucose sensor with polyaniline on indium tin oxide nanoparticle layer as the optical readout", Biosens. Bioelectron, 203, pp.114002~ (2022)
- E. Rafatmah, "Colorimetric and visual determination of hydrogen peroxide and glucose by applying paper-based closed bipolar electrochemistry", Microchim. Acta, 186, pp.684~ (2019)
- M. Seo, "Recent advances in electrochromic sensors", J. Korean Electrochem. Soc, 25(4), pp.125~133 (2022)
- C.-C. Wang, "A paper-based “Pop-up” electrochemical device for analysis of beta-hydroxybutyrate", Anal. Chem, 88(12), pp.6326~6333 (2016)
- P. Teengam, "NFCenabling smartphone-based portable amperometric immunosensor for hepatitis B virus detection", Sens. Actuators B Chem, 326, pp.128825~ (2021)
