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A Facile Approach to Fabrication of Hollow ZnO Nanoparticles

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주제분류재료공학

초록

Well-defined, monodispersed hollow ZnO nanoparticles were successfully synthesized by a facile one-pot solution method at room temperature. Hollow ZnO nanoparticles were fabricated using polystyrene nanoparticles as seed particles. The removal of core particles via solvent extraction yields hollow nanoparticles. The structures and morphologies of the obtained products were characterized with Fourier transform infrared (FT-IR), Thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), X-ray diffraction pattern (XRD) and Scanning electron microscopy (SEM). The formation mechanism of the hollow structure of the ZnO nanoparticles was also investigated. The technique developed here is expected to be useful in the preparation other metal oxides and hollow architectures.

Abstract

Well-defined, monodispersed hollow ZnO nanoparticles were successfully synthesized by a facile one-pot solution method at room temperature. Hollow ZnO nanoparticles were fabricated using polystyrene nanoparticles as seed particles. The removal of core particles via solvent extraction yields hollow nanoparticles. The structures and morphologies of the obtained products were characterized with Fourier transform infrared (FT-IR), Thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), X-ray diffraction pattern (XRD) and Scanning electron microscopy (SEM). The formation mechanism of the hollow structure of the ZnO nanoparticles was also investigated. The technique developed here is expected to be useful in the preparation other metal oxides and hollow architectures.

참고문헌 (24)

  1. Zhu, C., "A Simple Method for the Preparation of Hollow ZnO Nanospheres for Use as a High Performance Photocatalyst", Nanoscale, 4, pp.3060~3064 (2012)[DOI]
  2. Zhang, J., "ZnO Hollow Spheres: Preparation, Characterization, and Gas Sensing Properties", Sensors and Actuators. B, 139, pp.411~417 (2009)[DOI]
  3. Tang, S., "Hollow Mesoporous Zirconia Nanocapsules for Drug Delivery", Advanced Functional Materials, 20, pp.2442~2447 (2010)[DOI]
  4. Wang, Z., "Metal Oxide Hollow Nanostructures for Lithium-ion Batteries", Advanced Materials, 24, pp.1903~1911 (2012)[DOI]
  5. Xia, Y., "One-dimensional Nanostructures: Synthesis, Characterization, and Applications", Advanced Materials, 15, pp.353~389 (2003)[DOI]
  6. 이진우, "중공 자성입자를 포함한 복합재료 제조 및 전자파 특성 측정", Composites Research, 21(2), pp.31~35 (2008), 한국복합재료학회
  7. Lee, J.W., "Functionalization of Hollow Nanoparticles for Nanoreactor Applications", Nano Today, 9, pp.631~667 (2014)[DOI]
  8. Lou, X.W., "Hollow Micro-", nanostructures: Synthesis and Applications, 2008, pp.20, 3987~4019
  9. Wang, Y., "Shape-controlled Synthesis of Hollow Silica Colloids", Langmuir, 29, pp.11575~11581 (2013)[DOI]
  10. Tao, C., "Synthesis of Shape-controlled Hollow Silica Nanostructures with a Simple Soft-templating Method and Their Application as Superhydrophobic Antireflective Coatings with Ultralow Refractive Indices", Colloids and Surface A: Physicochemical and Engineering Aspects, 501, pp.17~23 (2016)
  11. Wang, Y., "Shape-controlled Synthesis of <TEX>$TiO_2$<", TEX> Hollow Structures and Their Application in Lithium Batteries, 2012, pp.22, 1969~1976
  12. Cheng, K., "Recent Advances in Syntheses and Therapeutic Applications of Multifunctional Porous Hollow Nanoparticles", Nano Today, 5, pp.183~196 (2010)[DOI]
  13. Deng, T.S., "Synthesis of Monodisperse Polystyrene@ Vinyl-<TEX>$SiO_2$<", TEX> Core-Shell Particles and Hollow <TEX>$SiO_2$<, Chemistry of Materials, pp.2012, 24[DOI]
  14. Zhang, L., "Facile Synthesis of Nanocrystal Tin Oxide Hollow Microspheres by Microwave-Assisted Spray Pyrolysis Method", Journal of Materials Science & Technology, 33, pp.874~878 (2017)[DOI]
  15. Fuji, M., "Shape-controlled Hollow Silica Nanoparticles Synthesized by an Inorganic Particle Template Method", Advanced Power Technology, 23, pp.562~565 (2012)[DOI]
  16. Arnal, P.M., "Highly Monodisperse Zirconia-Coated Silica Spheres and Zirconia", Silica Hollow Spheres with Remarkable Textural Properties, 2006, pp.18, 2733~2739
  17. Deng, Z., "A Facile Method to Fabricate ZnO Hollow Spheres and Their Photocatalytic Property", The Journal of Physical Chemistry B, 112, pp.16~22 (2008)[DOI]
  18. Xu, Z., "Hollow <TEX>$ZnO", Zn_2SiO_4, TEX> Sub-microspheres with Mesoporous Shells: Synthesis, Characterization, Adsorption and Photoluminescence, pp.Journal of Alloys and Compounds, 2013[DOI]
  19. Dong, Z., "Accurate Control of Multishelled ZnO Hollow Microspheres for Dye-Sensitized Solar Cells with high Efficiency", Advanced Materials, 24, pp.1046~1049 (2012)[DOI]
  20. Yin, M., "Preparation of ZnO Hollow Spheres with Different Surface Roughness and Their Enhanced Gas Sensing Property", Sensors and Actuators B: Chemical, 197, pp.58~65 (2014)[DOI]
  21. Sinha, A.K., "Fabrication of Large‐Scale Hierarchical ZnO Hollow Spheroids for Hydrophobicity and Photocatalysis", Chemistry-A European Journal, 16, pp.7865~7874 (2010)[DOI]
  22. Song, P., "Acetone Sensing Characteristics of ZnO Hollow Spheres Prepared by One-pot Hydrothermal Reaction", Materials Letters, 86(1), pp.168~170 (2012)[DOI]
  23. 이동훈, "Preparation of Silica Hollow Composite Particles", Bulletin of the Korean Chemical Society, 35(11), pp.3303~3306 (2014), 대한화학회[DOI]
  24. Meulenkamp, E.A., "Synthesis and Growth of ZnO Nanoparticles", The Journal of Physical Chemistry B, 102, pp.5566~5572 (1998)[DOI]

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