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나노실리카 졸을 배합수 중량치환 방법으로 혼합한 OPC-slag cement의 특성

The Properties of OPC-Slag Cement Mixed with Nano-Silica Solution by Mixing Water Weight Replacement Method

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참고문헌

키워드

주제분류안전공학

초록

본 연구는 nano-silica solution(NSS)을 배합수 중량치환방법을 사용한 OPC-slag cement의 특성에 관한 연구이다. 새로운 치환방법은 선행연구들보다 높은 NSS 치환율의 시멘트에 대한 거동을 연구하기 위한 기초 단계이다. NSS는 배합수 중량의 10%, 20%, 30%, 40%, 그리고 50% 치환하였다. 그 결과 역학적 및 미세구조적 특성이 향상되는 결과를 보였다. 이는 두 가지 원인으로 요약된다. 첫 번째는 NSS를 배합수중량 치환하면 나노 실리카 입자의 균질한 분산작용이 향상된다. 이는 초기 수화작용을 촉진한다. 두 번째는 배합수 보다 밀도가 큰 NSS의 치환은 w/b를 감소시킨다. 이는 치밀한 수화반응물질을 형성시킨다. 새로운 치환방법은 선행연구에서 밝혀진 분말형 나노 실리카 입자를 사용한 결과와 비교하여 역학적과 미세구조 특성의 저하가 나타나지 않았다. 따라서 본 연구에서 사용한 NSS를 배합수 중량 치환한 방법은OPC-GGBFS cement의 배합에 적용 가능할 것으로 판단된다.

Abstract

This research is a study on the characteristics of OPC-slag cement using nano-silica solution (NSS) with water-weight substitution method. The new replacement method is a fundamental step to study the behavior of cement with higher NSS replacement rates than previous studies. NSSwas replaced by 10%, 20%, 30%, 40%, and 50% of the mixing water weight. As a result, the mechanical and microstructural characteristics wereimproved. This can be summarized in two ways. First, when the NSS is replaced with mixing water, the homogeneous dispersion action of the nano-silicaparticles is improved. This promotes initial hydration. Second, substitution of NSS with higher density than mixing water reduces w / b. This formsa dense hydration reaction material. The new substitution method did not show any degradation of mechanical and microstructural properties ascompared with the results using the powdered nano-silica particles revealed in the previous study. Therefore, it is considered that the method of weightsubstitution of NSS used in this study can be applied to the formulation of OPC-slag cement.

참고문헌 (53)

  1. Acevedo-Martinez, E., "Portland cement-blast furnace slag mortars activated using waterglass : – Part 1 : Effect of slag replacement and alkali concentration", Construction and Building Materials, 37, pp.462~469 (2012)
  2. Amin, M., "Effect of using different types of nano materials on mechanical properties of high strength concrete", Construction and Building Materials, 80, pp.116~124 (2015)
  3. Angulo-Ramírez, D. E., "Alkali-activated Portland blast-furnace slag cement : Mechanical properties and hydration", Construction and Building Materials, 140, pp.119~128 (2017)
  4. Ardalan, R. B., "Enhancing the permeability and abrasion resistance of concrete using colloidal nano-SiO2 oxide and spraying nanosilicon practices", Construction and Building Materials, 146, pp.128~135 (2017)
  5. Benouisa, A., "Estimation of concrete"s porosity by ultrasounds", Physics Procedia, 21, pp.53~58 (2011)
  6. Björnström, J., "Accelerating effects of colloidal nano-silica for beneficial calcium-silicate-hydrate formation in cement", Chemical Physics Letters, 392, pp.242~248 (2004)
  7. Chithra, S., "The effect of Colloidal Nano-silica on workability, mechanical and durability properties of High Performance Concrete with Copper slag as partial fine aggregate", Construction and Building Materials, 113, pp.794~804 (2016)
  8. Collins, F., "Effect of pore size distribution on drying shrinking of alkali-activated slag concrete", Cement and Concrete Research, 30(9), pp.1401~1406 (2000)
  9. Du, H., "Durability performances of concrete with nano-silica", Construction and Building Materials, 73, pp.705~712 (2014)
  10. Dumont, F., "Colloidal Silica: Fundmentals and Applications", pp.243~252 (2006), CRC Press
  11. Ercikdi, B., "Strength and ultrasonic properties of cemented paste backfill", Ultrasonics, 54, pp.195~204 (2014)
  12. Escalante-Garcia, J. I., "Portland cement-blast furnace slag mortars activated using waterglass : Effect of temperature and alkali concentration", Construction and Building Materials, 66, pp.323~328 (2014)
  13. Gaitero, J. J., "Reduction of the calcium leaching rate of cement paste by addition of silica nanoparticles", Cement and Concrete Research, 38, pp.1112~1118 (2008)
  14. Hadj-sadok, A., "Microstructure and durability of mortars modified with medium active blast furnace slag", Construction and Building Materials, 25, pp.1018~1025 (2011)
  15. Hossein, i P., "Effect of nano-particles and aminosilane interaction on the performances of cement-based composites : An experimental study", Construction and Building Materials, 66, pp.113~124 (2014)
  16. Hou, P., "Modification effects of colloidal nanoSiO2 on cement hydration and its gel property", Composites : Part B, 45, pp.440~448 (2013)
  17. Ismael, R., "Influence of nano-SiO2and nano-Al2O3 additions on steel-to-concrete bonding", Construction and Building Materials, 125, pp.1080~1092 (2016)
  18. Jiang, Z., "Autogenous relative humidity change an autogenous shrinkage of high-performance cement pastes", Cement and Concrete Research, 35(8), pp.1539~1545 (2005)
  19. Jo, B. -W., "Characteristics of cement mortar with nano-SiO2 particles", Construction and Building Materials, 21, pp.1351~1355 (2007)
  20. Kong, D., "Influence of colloidal silica on fresh properties of cement paste as compared to nano-silica powder with agglomerates in micron-scale", Cement and Concrete Composites, 63, pp.30~41 (2015)
  21. Li, L. G., "Synergistic effects of micro-silica and nano-silica on strength and microstructure of mortar", Construction and Building Materials, 140, pp.229~238 (2017)
  22. Liu, M., "The synergistic effect of nano-silica with blast furnace slag in cement based materials", Construction and Building Materials, 126, pp.624~631 (2016)
  23. Massana, J., "Influence of nano-and micro-silica additions on the durability of a high-performance self-compacting concrete", Construction and Building Materials, 165, pp.93~103 (2018)
  24. Mindess, S., "Concrete" (2003), Prentice Hall
  25. Mohseni, E., "Single and combined effects of nano-SiO2, nano-Al2O3 and nano-TiO2 on the mechanical, rheological and durability properties of self-compacting mortar containing fly ash", Construction and Building Materials, 84, pp.331~340 (2015)
  26. Najigivi, A., "Investigating the effects of using different types of SiO2nanoparticles on the mechanical properties of binary blended concrete", Composites : Part B, 54, pp.52~58 (2013)
  27. Nazari, A., "Splitting tensile strength of concrete using ground granulated blast furnace slag and SiO2 nanoparticles as binder", Energy and Buildings, 43, pp.864~872 (2011)
  28. Nazari, A., "The effects of SiO2 nanoparticles on physical and mechanical properties of high strength compacting concrete", Composites : Part B, 42, pp.570~578 (2011)
  29. Neto, A.A.M., "Drying and autogenous shrinkage of pastes and mortars with activated slag cement", Cement and Concrete Research, 38(4), pp.565~574 (2008)
  30. Nili, M., "Investigating the effect of the cement paste and transition zone on strength development of concrete containing nanosilica and silica fume", Materials and Design, 75, pp.174~183 (2015)
  31. Norhasri, M. S. M., "Applications of using nano material in concrete : A review", Construction and Building Materials, 133, pp.91~97 (2017)
  32. Oltulu, M., "Single and combined effects of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strength and capillary permeability of cement mortar containing silica fume", Materials Science and Engineering A, 528, pp.7012~7019 (2011)
  33. Oltulu, M., "Effect of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strengths and capillary water absorption of cement mortar containing fly ash : A comparative study", Energy and Buildings, 58, pp.292~301 (2013)
  34. Qing, Y., "Influence of nano-SiO2 addition on properties of hardened cement paste as compared with silica fume", Construction and Building Materials, 21, pp.539~545 (2007)
  35. Quercia, G., "Water demand of amorphous nano silica and its impact on the workability of cement paste", Cement and Concrete Research, 42, pp.344~357 (2012)
  36. Rashad, A. M., "A synopsis about the effect of nano-Al2O3, nano-Fe2O3, nano-Fe3O4 and nano-clay on some properties of cementtitious materials – A short guide for Civil Engineer", Materials and Design, 52, pp.143~157 (2013)
  37. Rupasingle, M., "Investigation of strength and hydration characteristics on nano-silica incorporated cement paste", Cement and Concrete Composites, 80, pp.17~30 (2017)
  38. Said, A. M., "Properties of concrete incorporating nano-silica", Construction and Building Materials, 36, pp.838~844 (2012)
  39. Sanchez, F., "Nanotechnology in concrete – A review", Construction and Building Materials, 24, pp.2060~2071 (2010)
  40. Senff, L., "Effect of nano-silica on rheology and fresh properties of cement pastes and mortars", Construction and Building Materials, 23, pp.2487~2491 (2009)
  41. Shekari, A. H., "Influence of nano particles on durability and mechanical properties of high performance concrete", Procedia Engineering, 14, pp.3036~3041 (2011)
  42. Singh, L.P., "Beneficial role of nanosilica in cement based materials, -A review", Construction and Building materials, 47 (2013)
  43. Stefanidou, M., "Influence of nano-SiO2 on the Portland cement pastes", Composites : Part B, 43, pp.2706~2710 (2012)
  44. Vergara, L., "NDE ultrasonic methods to characterise the porosity of mortar", NDT&E International, 34, pp.557~562 (2001)
  45. Wittmann, F.H., "Creep and shrinkage in concrete structures", pp.129~161 (1982), Wiley
  46. Wu, D., "Mechanical performance and ultrasonic properties of cemented gangue backfill with admixture of fly ash", Ultrasonics, 64, pp.89~96 (2016)
  47. Wu, Z., "The hydration of tricalcium silicate in the presence of colloidal silica", Journal of Materials Science, 19, pp.3477~3486 (1984)
  48. Xu, Z., "Effects of nano-silica on hydration properties of tricalcium silicate", Construction and Building Materials, 125, pp.1169~1177 (2016)
  49. Zhang, M. -H., "Use of nano-silica to increase early strength and reduce setting time of concretes with high volumes of slag", Cement & Concrete Composites, 34, pp.650~662 (2012)
  50. Zhang, P., "Influence of nano-SiO2on properties of fresh and hardened high performance concrete : A state-of-the-art review", Construction and Building Materials, 148, pp.648~658 (2017)
  51. Zhang, M. -H., "Use of nano-silica to reduce setting time and increase early strength of concretes with high volumes of fly ash or slag", Construction and Building Materials, 29, pp.573~580 (2012)
  52. Zhang, M. -H., "Effect of silica fume on cement hydration in low porosity cement pastes", Cement and Concrete Research, 21, pp.800~808 (1991)
  53. Zhang, W., "Drying shrinkage and microstructure characteristics of mortar incorporating ground granulated blast furnace slag and shrinkage reducing admixture", Construction and Building Materials, 93, pp.267~277 (2015)

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