침지된 해수 온도 및 결합재 혼합비에 따른 비소성 시멘트의 강도 특성
Properties of Non-Sintered Cement Pastes Immersed in Sea Waters at Different Temperatures for Binders Mixed with Different Ratios
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초록
본 연구에서는 해수 침지 온도에 따른 비소성 시멘트 경화체의 물리적 및 역학적 특성에 대해 비교 분석하였다. 비소성 시멘트는 플라이애시와 고로슬래그미분말을 6:4, 7:3 및 8:2의 중량비로 혼합하여 수산화나트륨과 액상규산나트륨으로 알칼리 활성화 하여 제작되었다. 알칼리 활성화를 위한 활성화제는 플라이애시와 고로슬래그미분말을 혼합한 중량의 5%로 하였으며, 화학첨가제로 탄산칼슘이 사용되었다. 본 연구에서는 알칼리 활성화된 시험체들을 3가지 다른 온도(5°C, 15°C 및 25°C)의 해수에 각각 침지 시킨 후, 침지 재령 3일 및 28일에 대해 경화체의 압축 강도, 밀도 및 흡수율을 측정하였으며, 해수 침지 재령 28일에 대해서는 XRD 및 SEM 시험 분석을 실시하였다. 또한, 해수 침지 재령 28일에 대하여 시험체들 내의 수용성 염화물(자유염화물) 및 산-가용성 염화물(총염화물) 함유량을 측정하여 분석하였다. 본 연구에서 해수온도별로 침지시킨 플라이애시-고로슬래그미분말 혼합 알칼리 활성화 경화체는 플라이애시 혼합률이 증가함에 따라 밀도 감소, 흡수율 증가및 강도가 감소하는 경향을 나타냈다. 또한 플라이애시 혼합률이 증가할수록 시험체 내의 수용성 염화물 및 산-가용성 염화물의 양이 증가하는것으로 나타났다. 본 연구에서 제작된 플라이애시-고로슬래그미분말 혼합 알칼리 활성화 경화체는 노출된 해수 온도 영향으로 인한 강도 차이는 없는 것으로 판단되며, 플라이애시와 고로슬래그미분말의 혼합중량비에 따라 강도 특성이 달라지는 것으로 나타났다.
Abstract
This paper presents an investigation of the mechanical properties on non-sintered cement pastes immersed in sea waters at three differenttemperatures. The non-sintered cement pastes were synthesized using blended binder(Class F fly ash; FA and ground granulated blast furnace slag;GGBFS) and alkali activator(sodium hydroxide and sodium silicate). Binders were prepared by mixing the FA and GGBFS in different blend weightratios of 6:4, 7:3 and 8:2. The alkali activators were used 5wt% of blended binder, respectively. Calcium carbonate was used as an chemical additive. The compressive strength, bulk density and absorption of alkali-activated FA-GGBFS blends pastes were measured at 3 and 28 days after immersedin sea waters at three different temperatures(5°C, 15°C and 25°C). The XRD and SEM tests of the pastes were conducted at 28 days. Water-solublechloride(free chloride) and acid-soluble chloride(total chloride) contents in the pastes were also measured after 28 days immersion in sea water. Theexperimental results showed that increasing the content of FA in alkali-activated FA-GGBFS blends pastes immersed in sea water increases theabsorption, water-soluble chloride content and acid-soluble chloride content, and reduces the compressive strength and bulk density. And it was foundthat there was a variation of strength change for the alkali-activated FA-GGBFS blends pastes immersed in sea waters at three different temperaturesthat depends on the blending ratio of FA and GGBFS.
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