DEA 용액에서 암모니아를 함유한 염화니켈 수용액으로부터 니켈 분말의 입경 제어
Size Control of Nickel Powders from Nickel Chloride SolutionContaining Ammonia in DEA Solutions
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Abstract
Nickel powders were synthesized by the hydrazine reduction of nickel chloride solution containing ammonia in DEA solutions. The size distribution of nickel powders were investigated as a function of ammonia concentration, hydrazine concentration and the mixed composition ratio of diethanolammine (DEA) and triethanolammine (TEA). Nickel powders with the size in submicron range were obtained at 185℃ for 45 minutes by hydrazine reduction of nickel chloride solution in DEA solutions. The hydrazine concentrations showed significant effects on the particle size and shape distribution of nickel powders under NH3/Ni2+ molar ratio of 2.0 condition. As the mixed volume ratio of TEA and DEA increased, nickel powders with relatively larger particle size and low agglomeration were obtained. Nickel powders with particle size in the ranged from 0.4 to 0.9 mm were obtained at the 50 vol.% of TEA.
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