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논문

흡,탈수 반복 환경하에서의 유기도막의 방식석 평가

Evaluation of Anticorrosive Performance of Organic Coatings Subjected to Cyclic Wet-dry Exposure

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키워드

주제분류해양공학

초록

Abstract

Organic coatings are widely used to control the corrosion of a steel structure. The water in coatings may cause the coatings to swell, leading to the degradation of the coatings. In addition, water affects the permeation of oxygen and other corrosive agents, and consequently, the presence of such substances at coating-metal interface promotes corrosion of the metal substrate. In this study, the anticorrosive properties of 4 types of coating, such as epoxy-epoxy, epoxy-urethane, urethane-epoxy, urethane-urethane, were evaluated. The evaluation tests were conducted under cyclic water-absorption/desorption conditions, consisting of alternative exposure to diluted 0.001M-LiCl(aH2O≒1) and concentrated 10M-LiCl(aH2O≒0.15). The anticorrosive performance of coatings was found to decrease in the order of urethane-urethane > urethane-epoxy > epoxy-epoxy coating.1. 서 론

참고문헌 (10)

  1. Bellucci, F, "Water Transport in Organic Coatings", Corrosion, 49, pp.235~247 (1993)
  2. Brasher, D. M, "Electrical Measurements in the Study of Immersed Paint Coatings on Metal", J. Appl. Chem., 4, pp.62~72 (1954)
  3. Hare, C. H, "Protective Coatings", pp.240~ (1994), Technology Publishing Co., Pittsburgh, USA
  4. Pebere, N, "Evaluation of Corrosion Performance of Coated Steel by the Impedance Technique", Corros. Sci., 29, pp.1073~1086 (1989)
  5. Perera, D. Y, "Water Transport through Paint Films", J. Oil. Col. Chem. Assoc., 54, pp.313~333 (1971)
  6. Popov, B. N, "Using Electrochemical Impedance Spectroscopy as a Tool for Organic Coating Solute Saturation Monitoring", J. Electrochem. Soc., 140, pp.947~951 (1993)
  7. Silverman, D. C, "Corrosion Prediction in Complex Environments Using Electrochemical Impedance Spectroscopy", Electrchimica Acta, 38, pp.2075~2078 (1993)
  8. Scully, J. R, "Electrochemical Impedance of Organic Coated Steel", J. Electrochem. Soc., 136, pp.979~990 (1989)
  9. Westing, E. P. M. Van, "The Determination of Coating Performance Using Electrochemical Impedance Spectroscopy", Electrochimica Acta, 39, pp.899~910 (1994)
  10. Walter, G. W, "The Application of Impedance Spectroscopy to Study the Uptake of Sodium Chloride Solution in Painted Metals", Corros. Sci., 32, pp.1041~1058 (1991)

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