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나노튜브 전극 기반 양자점 감응 태양전지 구현을 위한 투명한 상대전극

Transparent Counter Electrode for Quantum Dot-Sensitized Solar Cells with Nanotube Electrodes

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주제분류기계공학

초록

Anodic oxidized TiO2 nanotube arrays are promising materials for application in photoelectrochemical solar cells as the photoanode, because of their attractive properties including slow electron recombination rate, superior light scattering, and smooth electrolyte diffusion. However, because of the opacity of these nanotube electrodes, the back-side illumination is inevitable for the application in solar cells. Therefore, for the fabrication of solar cells with the anodic oxidized nanotube electrodes, it is required to develop efficient and transparent counter electrodes. Here, we demonstrate quantum dot-sensitized solar cells (QDSCs) based on the nanotube photoanode and transparent counter electrodes. The transparent counter electrodes based on Pt electrocatalysts were prepared by a simple thermal decomposition methods. The photovoltaic performances of QDSCs with nanotube photoanode were tested and optimized depending on the concentration of Pt precursor solutions for the preparation of counter electrodes.

Abstract

Anodic oxidized TiO2 nanotube arrays are promising materials for application in photoelectrochemical solar cells as the photoanode, because of their attractive properties including slow electron recombination rate, superior light scattering, and smooth electrolyte diffusion. However, because of the opacity of these nanotube electrodes, the back-side illumination is inevitable for the application in solar cells. Therefore, for the fabrication of solar cells with the anodic oxidized nanotube electrodes, it is required to develop efficient and transparent counter electrodes. Here, we demonstrate quantum dot-sensitized solar cells (QDSCs) based on the nanotube photoanode and transparent counter electrodes. The transparent counter electrodes based on Pt electrocatalysts were prepared by a simple thermal decomposition methods. The photovoltaic performances of QDSCs with nanotube photoanode were tested and optimized depending on the concentration of Pt precursor solutions for the preparation of counter electrodes.

참고문헌 (7)

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  3. J.-Y. Kim, "Enhanced Photovoltaic Properties of a Cobalt Bipyridyl Redox Electrolyte in Dye-Sensitized Solar Cells Employing Vertically Aligned TiO2 Nanotube Electrodes", J. Phys. Chem. C, 115, pp.19979~ (2011)
  4. J.-Y. Kim, "Highly Uniform and Vertically Aligned SnO2Nanochannel Arrays for Photovoltaic Applications", Nanoscale, 7, pp.8368~ (2015)
  5. J.-Y. Kim, "Highly Efficient Copper-Indium-Selenide Quantum Dot Solar Cells:Suppression of Carrier Recombination by Controlled ZnS Overlayers", ACS Nano, 9, pp.11286~ (2015)
  6. P. V. Kamat, "Quantum Dot Solar Cells. The Next Big Thing in Photovoltaics", J. Phys. Chem. Lett, 4, pp.908~ (2013)
  7. A. J. Nozik, "Semiconductor Quantum Dots and Quantum Dot Arrays and Applications of Multiple Exciton Generation to Third-Generation Photovoltaic Solar Cells", Chem. Rev, 110, pp.6873~ (2010)

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