전기화학적 가속 부식 평가법에서 강재의 부식 손상에 미치는 인가전류밀도의 영향
Effect of Applied Current Density on the Corrosion Damage of Steel with Accelerated Electrochemical Test
1
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
In this study, we investigated the corrosion damage characteristics of steel for offshore wind turbine tower substructure using an accelerated electrochemical test. The galvanostatic corrosion test method was employed with a conventional 3 electrode cell in natural sea water, and the steel specimen was served as a working electrode to induce corrosion in an accelerated manner. Surface and cross-sectional image of the damaged area were obtained by optical microscope and scanning electron microscope. The weight of the specimens was measured to determine the gravimetric change before and after corrosion test. The result revealed that the steel tended to suffer uniform corrosion rather than localized corrosion due to active dissolution reaction under the constant current regime. With increasing galvanostatic current density, the damage depth and surface roughness of surface was increased, showing approximately 25 times difference in damage depth between the lowest current density (1 mA/cm2) and the highest current density (200 mA/cm2). The gravimetric observation showed that the weight loss was proportionally increased with increment of current density that has 75 times different according by experimental conditions. Consequently, uniform corrosion of the steel specimen was conveniently induced by the electrochemically accelerated corrosion technique, and it was possible to control the extent of the corrosion damage by varying the current density.
Abstract
In this study, we investigated the corrosion damage characteristics of steel for offshore wind turbine tower substructure using an accelerated electrochemical test. The galvanostatic corrosion test method was employed with a conventional 3 electrode cell in natural sea water, and the steel specimen was served as a working electrode to induce corrosion in an accelerated manner. Surface and cross-sectional image of the damaged area were obtained by optical microscope and scanning electron microscope. The weight of the specimens was measured to determine the gravimetric change before and after corrosion test. The result revealed that the steel tended to suffer uniform corrosion rather than localized corrosion due to active dissolution reaction under the constant current regime. With increasing galvanostatic current density, the damage depth and surface roughness of surface was increased, showing approximately 25 times difference in damage depth between the lowest current density (1 mA/cm2) and the highest current density (200 mA/cm2). The gravimetric observation showed that the weight loss was proportionally increased with increment of current density that has 75 times different according by experimental conditions. Consequently, uniform corrosion of the steel specimen was conveniently induced by the electrochemically accelerated corrosion technique, and it was possible to control the extent of the corrosion damage by varying the current density.
참고문헌 (17)
- S. P. Breton, "Status, plans and technologies for offshore wind turbines in Europe and North America", Renew. Energ., 34, pp.646~654 (2009)
- B. Snyder, "Ecological and economic cost-benefit analysis of offshore wind energy", Renew. Energ, 34, pp.1567~1578 (2009)
- X. Sun, "The current state of offshore wind energy technology development", Energy, 41, pp.298~312 (2012)
- 김성종, "선박의 해양 부식과 부식방지 장치", 한국표면공학회지, 44(3), pp.105~116 (2011), 한국표면공학회
- Ministry of ocean and fisheries, "Design standards for harbor and fishery port", 402~ (2014)
- S. K. Chang, "Evaluation of atmospheric corrosion for metals", J. Kor. Inst. Surf. Eng, 30, pp.69~82 (1997)
- 장석기, "해수 온도에 따른 S355ML 강재의 부식 경향 평가", CORROSION SCIENCE AND TECHNOLOGY, 14(5), pp.232~238 (2015), 한국부식방식학회[DOI]
- B. Ingham, "In situ synchrotron X-ray diffraction study of surface scale formation during CO2 corrosion of carbon steel at temperatures up to 90℃", Corros. Sci, 52, pp.3052~3061 (2010)
- A. Poursaee, "Potential pitfalls in assessing chloride-induced corrosion of steel in concrete", Cement. Concrete Res, 39, pp.391~400 (2009)
- Z. Shi, "Galvanostatic anodic polarisation of WE43", J. Magnesium Alloys, 2, pp.197~202 (2014)
- R. W. Revie, "Corrosion and corrosion control", pp.68~ (2008), John Wiley & Sons
- E. S. M. Sherif, "A comparative study on the electrochemical corrosion behavior of iron and X-65 steel in 4.0 wt% sodium chloride solution after different exposure intervals", Molecules, 19, pp.9962~9974 (2014)
- P. K. Srivastava, "High rate of anodic dissolution of iron work piece during electrochemical machining", Int. J. Mech. Eng, 41, pp.1110~1116 (2013)
- I. M. Dmytrakh, "Mechanism and stages of the electrochemical dissolution of metals in the vicinity of the crack tip", Mater. Sci, 31, pp.337~342 (1996)
- C. Alonso, "Factors controlling cracking of concrete affected by reinforcement corrosion", Mater. Struct, 31, pp.435~441 (1998)
- Parametric study of CO2 corrosion of carbon steel, "K. Videm", ~, pp.paper no. 14 (1994)
- T. D. Clark, "An analysis of microstructure and corrosion resistance in underwater friction stir welded 304L stainless steel", pp.2005
