본문 바로가기
KERD
논문KCI 등재

Fe-2%Ni 합금의 고온 산화

High-temperature Oxidation of Fe-2%Ni Alloys

2

조회

0

다운로드

1

인용

0

참고문헌

키워드

주제분류기계공학

초록

Fe-2 wt.%Ni alloys were fabricated by metal powder injection molding, and their oxidation behavior at 600-700 ℃ for 30 h in air was studied in order to find the effect of the small addition of Ni in the iron matrix on the high-temperature oxidation. Oxide scales that formed after oxidation consisted primarily of Fe2O3, where microscopic voids were scattered. Nickel was segregated initially at the scale/matrix interface, and later at the lower part of the Fe2O3 scale. At 600 ℃, Fe-2wt.%Ni alloys oxidized parabolically initially, and linearly after 15 h. At 650-700 ℃, they oxidized linearly from the initial period. Although Fe-2wt.%Ni alloys oxidized slower than pure iron, their oxidation rates were relatively fast.

Abstract

Fe-2 wt.%Ni alloys were fabricated by metal powder injection molding, and their oxidation behavior at 600-700 ℃ for 30 h in air was studied in order to find the effect of the small addition of Ni in the iron matrix on the high-temperature oxidation. Oxide scales that formed after oxidation consisted primarily of Fe2O3, where microscopic voids were scattered. Nickel was segregated initially at the scale/matrix interface, and later at the lower part of the Fe2O3 scale. At 600 ℃, Fe-2wt.%Ni alloys oxidized parabolically initially, and linearly after 15 h. At 650-700 ℃, they oxidized linearly from the initial period. Although Fe-2wt.%Ni alloys oxidized slower than pure iron, their oxidation rates were relatively fast.

참고문헌 (15)

  1. K. Nakama, "Effects of Cold-working and Heattreatment Conditions and Alloying Elements on Thermal Expansion, Strength and Other Properties of Fe-36wt%Ni Invar Alloy", Sanyo Tech. Rep., 21, pp.38~46 (2014)
  2. G. L. Wulf, "The Oxidation of Fe-Ni Alloys", Corros. Sci., 9, pp.689~701 (1969)[DOI]
  3. I. A. Menzies, "Oxidation of an Fe-30%Ni Alloy in Oxygen at <TEX>$700^{\circ}C-1000^{\circ}C$<", TEX>, 1970, pp.117, 1539~1544
  4. I. A. Menzies, "Oxidation of an Fe-12%Ni Alloys in Oxygen at <TEX>$700-1000^{\circ}C$<", TEX>, 1971, pp.3, 41~58
  5. W. J. Tomlinson, "Oxidation of an Fe-19wt.%Ni alloy in <TEX>$CO_2$<", TEX> at <TEX>$700-1000^{\circ}C$<, Oxid. Met., pp.1978, 12[DOI]
  6. W. J. Tomlinson, "Oxidation of an Fe-9 w", o Ni Alloy in <TEX>$CO_2$<, TEX>, pp.J. Electrochem. Soc., 1978[DOI]
  7. S. Ando, "Effect of Oxide Scale on Carbon Deposition on Fe-Ni Alloys in Carburizing Gas", Metall. Trans. A, 10, pp.2393~2399 (1991)
  8. K. Kusabiraki, "High Temperature Oxidation of Fe-Ni Alloys in Ar-<TEX>$H_2O$<", TEX> Atmospheres, 1988, pp.67, 871~878
  9. R. A. Rapp, "The High Temperature Oxidation of Metals Forming Cation-Diffusing Scales", Metall. Trans. B, 15, pp.195~212 (1984)[DOI]
  10. D. A. Channing, "A Mossbauer Study of the Oxidation of Fe-Ni Alloys at 535 and <TEX>$635^{\circ}C$<", TEX>, 1977, pp.12, 2475~2487
  11. Y. Z. Nakamura, "The Oxidation Behavior of an Iron-Nickel Alloy Containing Yttrium or Rare Earth Elements Between <TEX>$900^{\circ}C$<", TEX> and <TEX>$1200^{\circ}C$<, Metall. Trans. A, pp.1975, 6[DOI]
  12. 김기현, "사출성형 된 Fe-50%Ni 소결체의 제조", 한국분말재료학회지, 11(6), pp.472~476 (2004), 한국분말재료학회
  13. F. Matsuno, "Oxidation of Fe-Ni Alloys at High Temperatures", Tetsu-to-Hagane, 67, pp.2029~2038 (1981)[DOI]
  14. 임채홍, "방전플라즈마 소결법에 의해 제조된 Fe-Ni 합금의 미세조직 및 고온산화특성", 한국분말재료학회지, 24(1), pp.53~57 (2017), 한국분말재료학회[DOI]
  15. I. E. Klein, "The Oxidation Mechanism of Fe-Ni-Co Alloys", Oxid. Met., 16, pp.99~106 (1981)[DOI]

이 간행물의 다른 논문 (6건)