Development of electrodeposited lithium metal anodes for next-generation lithium metal batteries
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This study presents a lithium electroplating technology designed to enhance the quality of lithium anodes for next-generation lithium metal batteries. We investigate the electroplating process to achieve a high-density lithium layer. By employing atmospheric-pressure plasma treatment on copper current collectors and applying uniaxial pressure during the electroplating process, significant progress was made in improving the properties of the electrodeposited lithium. Furthermore, we analyze the factors contributing to performance degradation at low E/C ratios (electrolyte-to-capacity ratio) and discuss strategies for the commercialization of electroplated lithium as anode material for lithium metal batteries.
Abstract
This study presents a lithium electroplating technology designed to enhance the quality of lithium anodes for next-generation lithium metal batteries. We investigate the electroplating process to achieve a high-density lithium layer. By employing atmospheric-pressure plasma treatment on copper current collectors and applying uniaxial pressure during the electroplating process, significant progress was made in improving the properties of the electrodeposited lithium. Furthermore, we analyze the factors contributing to performance degradation at low E/C ratios (electrolyte-to-capacity ratio) and discuss strategies for the commercialization of electroplated lithium as anode material for lithium metal batteries.
참고문헌 (31)
- Z. Wang, "Toward safer solid-state lithium metal batteries : a review", Nanoscale Advances, 2, pp.1828~1836 (2020)
- Z. Jiang, "Lithiophilic onionlike carbon spheres as lithium metal uniform deposition host", Journal of Colloid and Interface Science, 627, pp.783~792 (2022)
- H. Ye, "An outlook on low-volume-change lithium metal anodes for long-life batteries", ACS Central Science, 6, pp.661~671 (2020)
- L. S. Zhang, "CHAIN : unlocking informatics-aided design of Li metal anode from materials to applications", Rare Metals, 41, pp.1477~1489 (2022)
- T. Mukra, "Enhancing performance of anode-free Li-metal batteries by addition of ceramic nanoparticles : part I", Journal of Electrochemistry, 168, pp.090541~ (2021)
- C. C. Su, "Cyclic carbonate for highly stable cycling of high voltage lithium metal batteries", Energy Storage Materials, 17, pp.284~292 (2019)
- K. R. Adair, "Towards high performance Li metal batteries : nanoscale surface modification of 3D metal hosts for pre-stored Li metal anodes", Nano Energy, 54, pp.375~387 (2018)
- J. Zhang, "Research progress of anode-free lithium metal batteries", Crystals, 12, pp.1241~ (2022)
- S. Hasselwander, "Technoeconomic analysis of different battery cell chemistries for the passenger vehicle market", Batteries, 9, pp.379~ (2023)
- Q. Hu, "Solidenergy Systems", United States Patent US, 16, 2016
- G. Zhou, "Formulating energy density for designing practical lithium–sulfur batteries", Nature Energy, 7, pp.312~319 (2022)
- J. Xia, "Thin lithium metal foil technology for advanced battery manufacturing", Meeting, 362~ (2021)
- L. Suo, "A new class of solvent-in-salt electrolyte for highenergy rechargeable metallic lithium batteries", Nature Communications, 4, pp.1481~ (2013)
- N. W. Li, "Construction of stable lithium metal anodes using 3D conductive nanocellulose networks", Advanced Science, 4, pp.1600400~ (2016)
- J. Liang, "Site-selective sulfur vacancies in MoS₂ for electrocatalytic hydrogen evolution", Advanced Materials, 30, pp.1804684~ (2018)
- W. Liu, "Extending the life of lithium-based rechargeable batteries by reaction of lithium with sulfur dioxide", ACS Central Science, 3, pp.135~140 (2017)
- S. Liu, "The progress and prospects of flexible zinc-air batteries", Advanced Energy Materials, 8, pp.1702322~ (2017)
- X. Ren, "High-concentration ether electrolytes for stable high-voltage lithium metal batteries", ACS Energy Letters, 4, pp.896~903 (2019)
- Y. Zheng, "Localized high concentration electrolyte behavior near a lithium-metal anode surface", Journal of Materials Chemistry A, 7, pp.25047~25055 (2019)
- K. Kanamura, "Electrochemical oxidation of organic additives on lithium metal anodes", Journal of the Electrochemical Society, 143, pp.2187~2197 (1996)
- C. Shen, "Effects of solvent properties on ion transport in battery electrolytes", ACS Applied Materials & Interfaces, 7, pp.25441~25447 (2015)
- G. Jing, "Vinylene carbonate–LiNO3 : A hybrid additive in carbonic ester electrolytes for SEI modification on Li metal anode", Electrochemistry Communications, 51, pp.59~63 (2015)
- J. Qian, "Stable lithium metal anodes via self-assembled monolayers", Nano Energy, 15, pp.135~143 (2015)
- Y. Zhang, "High-concentration electrolytes for lithium batteries", Nano Letters, 14, pp.6889~6896 (2014)
- S. Li, "High safety and performance in lithiumion batteries enabled by phosphate additives", Energy Storage Materials, 18, pp.222~228 (2018)
- Q. Zhao, "Solid-state lithium batteries with fluorine-rich electrolytes", Angewandte Chemie International Edition, 57, pp.992~996 (2017)
- Y. Ma, "Zinc-based rechargeable batteries for electric vehicles", Energy Storage Materials, 11, pp.197~204 (2018)
- J. H. Oh, "Effects of plasma pretreatment of the Cu seed layer on Cu electroplating", Korean Journal of Materials Research, 11, pp.802~809 (2001)
- C. Fang, "Pressure-tailored lithium deposition and dissolution in lithium metal batteries", Nature Energy, 6, pp.987~994 (2021)
- B. Horstmann, "Strategies towards enabling lithium metal in batteries : interphases and electrodes", Energy &Environmental Science, 14, pp.5289~5314 (2021)
- E. Peled, "Review—SEI: past, present and future", Journal of the Electrochemical Society, 164, pp.A1703~ (2017)