Recovery of Silk Sericin from Soap-Alkaline Degumming Solution
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초록
Sericin is usually abandoned after the degumming process. However, it could be a valuable bioresource if an economically efficient recovery process could be set up. In this study, sericin was recovered directly from the degummed waste solution by adding calcium chloride, which induced the precipitation of the surfactant, sodium oleate, by charge interaction. The recovery yield was maximum when 10% of calcium chloride was added. Further increase in the calcium chloride concentration induced the precipitation of sericin. The recovered sericin had a molecular weight distribution similar to that of the hot-water-extracted sericin; but some highmolecular- weight sericin could not be recovered. The secondary structure and amino acid composition of the recovered sericin were similar to those of conventional hot-water-extracted sericin. We expect that sericin recovered from the degummed waste solution could be an alternative to the hot-water-extracted sericin, which is widely used in various applications.
Abstract
Sericin is usually abandoned after the degumming process. However, it could be a valuable bioresource if an economically efficient recovery process could be set up. In this study, sericin was recovered directly from the degummed waste solution by adding calcium chloride, which induced the precipitation of the surfactant, sodium oleate, by charge interaction. The recovery yield was maximum when 10% of calcium chloride was added. Further increase in the calcium chloride concentration induced the precipitation of sericin. The recovered sericin had a molecular weight distribution similar to that of the hot-water-extracted sericin; but some highmolecular- weight sericin could not be recovered. The secondary structure and amino acid composition of the recovered sericin were similar to those of conventional hot-water-extracted sericin. We expect that sericin recovered from the degummed waste solution could be an alternative to the hot-water-extracted sericin, which is widely used in various applications.
참고문헌 (14)
- Aramwit P, "Potential applications of silk sericin, a natural protein from textile industry by-broducts", Waste Manage Res, 30, pp.217~224 (2012)
- Capar G, "Treatment of silk production wastewaters by membrane processes for sericin recovery", J Membrane Sci, 325, pp.920~931 (2008)
- Capar G, "Separation of sericin from fatty acids towards its recovery from silk degumming wastewaters", J Membrane Sci, 342, pp.179~189 (2009)
- Capar G, "Separation of silkworm proteins in cocoon cooking wastewaters via nanofiltration: Effect of solution pH on enrichment of sericin", J Membrane Sci, 389, pp.509~521 (2012)
- Fabiani C, "Treatment of waste water from silk degumming processes for protein recovery and water reuse", Desalination, 105, pp.1~9 (1996)
- Gulrajani ML, "Studies on structural and functional properties of sericin recovered from silk degumming liquor by membrane technology", J Appl Polym Sci, 113, pp.2796~2804 (2009)
- 김무곤, "Effect of Lyoprotectant on the Solubility and Structure of Silk Sericin", International Journal of Industrial Entomology, 25(1), pp.133~137 (2012), 한국잠사학회
- Kundu SC, "Natural protective glue protein, sericin bioengineered by silkworms: Potential for biomedical and biotechnological applications", Prog Polym Sci, 33, pp.998~1102 (2008)
- 곽효원, "Chromium(VI) Adsorption Behavior of Silk Sericin Beads", International Journal of Industrial Entomology, 26(1), pp.47~53 (2013), 한국잠사학회
- Lin J, "Coagulation of sericin protein in silk degumming wastewater using quaternized chitosan", J Polym Environ, 20, pp.858~864 (2012)
- Oh H., "Refining hot-water extracted silk sericin by ethanol-induced precipitation", Int J Biol Macromol, 48, pp.32~37 (2011)
- Pereira RF, "What drives the precipitation of long-chain calcium carboxylates(soaps)in aqueous solution", Phys Chem Chem Phys, 13, pp.7517~7527 (2012)
- Vaithanomsat P, "Sericin separation from silk degumming wastewater", Sep Purif Technol, 59, pp.129~133 (2008)
- Yun H, "Extraction Conditions of Antherea mylitta Sericin with High Yields and Minimum Molecular Weight Degradation", Int J of Biol Macromol, 52, pp.59~65 (2013)
