키토산 가교 처리된 면직물의 천연염색에 관한 연구(Ⅰ) - 울금을 중심으로 -
Natural Dyeing of Chitosan-crosslinked Cotton Fabrics(Ⅰ) - Turmeric -
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For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of turmeric was studied. In this study, the colorants of turmeric were extracted with boiling water. Chitosan-crosslinked cotton fabrics was dyed with aqueous extract of turmeric and their dyeabilities on the fabrics were studied. Additionally the fastness to washing and light were also investigated. Cotton fabrics were treated with a crosslinking agent epichlorohydrin in the presence of chitosan to provide the cotton fabrics the dyeing properties of natural dye(turmeric) by the chemical linking of chitosan to the cellulose structure. The chitosan finishing and durable press finishing of the cotton fabrics occurred simultaneously in the mercerization bath. The dyeability(K/S), which was obtained by CCM observation, remarkably became increased when the crosslinked chitosan concentration was higher. Dyeability of turmeric was improved on chitosan- crosslinked cotton fabric rather than only cotton fabric, while the saturated dyeing time was 20minutes at 60℃. The hue value indicated greenish yellow with increasing the crosslinked chitosan concentration. And the color fastness to washing and light was almost the same.
Abstract
For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of turmeric was studied. In this study, the colorants of turmeric were extracted with boiling water. Chitosan-crosslinked cotton fabrics was dyed with aqueous extract of turmeric and their dyeabilities on the fabrics were studied. Additionally the fastness to washing and light were also investigated. Cotton fabrics were treated with a crosslinking agent epichlorohydrin in the presence of chitosan to provide the cotton fabrics the dyeing properties of natural dye(turmeric) by the chemical linking of chitosan to the cellulose structure. The chitosan finishing and durable press finishing of the cotton fabrics occurred simultaneously in the mercerization bath. The dyeability(K/S), which was obtained by CCM observation, remarkably became increased when the crosslinked chitosan concentration was higher. Dyeability of turmeric was improved on chitosan- crosslinked cotton fabric rather than only cotton fabric, while the saturated dyeing time was 20minutes at 60℃. The hue value indicated greenish yellow with increasing the crosslinked chitosan concentration. And the color fastness to washing and light was almost the same.
참고문헌 (21)
- 신남희, "오배자에 의한 회색계열 염색에 관한 연구", 한국의류산업학회지, 7(5)통권 : 7, pp.547~552 (2005), 한국의류산업학회
- S. S. Cho, "The dyeability properties of some yellow natural dyes-Extracted from turmeric-", Journal of the Korean Society for Clothing and Textiles, 통권 : 21, pp.1051~1059 (1997)
- 吉岡常雄, "天然纖維の硏究", pp.45~80 (1973), 光村推古書院
- J. S. Jung, "Color development of combination dyeing of indian indigo and turmeric extracts, gardenia extracts", Journal of the Korean Society for Clothing and Textiles, 통권 : 26, pp.325~336 (2002)
- Y. J. Chu, "The study of curcuma Longa L. dyeing", Journal of the Korean Society for Clothing and Textiles, 통권 : 20, pp.429~437 (1996)
- 刹光達夫林村雄匹郞, "和漢藥用植物", pp.366~367 (1968), 廣州書店
- 조경래, "염색이론과 실험", pp.44~ (2000), 형설출판사
- 문범수, "식품첨가물", pp.13~ (1984), 수학사
- 곽미정, "키토산가교처리된 면직물의 천연염색에 관한 연구(Ⅰ) -정향을 중심으로-", 한국의류산업학회지, 10(2)통권 : 10, pp.260~266 (2008), 한국의류산업학회
- N. Sakkayawong, "Adsorption mechanism of synthetic reactive dye wastewater by chitosan", Journal of Colloid and Interface Science, 통권 : 286, pp.36~42 (2005)
- 김민지, "키토산 가교 처리된 면직물의 태 변화에 관한 연구(Ⅱ) -키토산 농도 및 분자량의 영향-", 한국의류산업학회지, 7(4)통권 : 7, pp.439~444 (2005), 한국의류산업학회
- 김민지, "키토산 가교처리된 면직물의 태 변화에 관한 연구 -에피클로로히드린과 키토산 농도의 영향-", 한국의류산업학회지, 6(5)통권 : 6, pp.660~666 (2004), 한국의류산업학회
- S. H. Lee, "Ripening time and fiber formation of chitosan spinning dope", Journal of Applied Polymer Science, 통권 : 90, pp.2870~2877 (2003)
- K. R. Cho, "Studies on the Natural Dyes(7) -Dyeing properties of cochineal colors for silk fibers-", Journal of the Korean Society of Dyers and Finishers, 통권 : 6, pp.144~150 (1994)
- Y. J. Chu, "A study on the mordanting and dyeing properties of Rhusjara ica Dye", Journal of the Korean Society of Clothing and Textiles, 통권 : 22, pp.971~977 (1998)
- S. H. Lee, "Characteristics of cotton fabrics treated with epichlorohydrin and chitosan", Journal of Applied Polymer Science (2008), Article in press
- H.Mark, "Chemical Aftertreatment of Textiles", pp.444~ (1971), Wiley Interscience
- J. B. Mckelvey, "The cellulose-epichlorohydrin reaction in the presence of neutral salt and salt-alkali solutions", Textile Research Journal, 통권 : 34, pp.759~767 (1964)
- W. S. W. Ngah, "Removal of copper(II) ions from aqueous solution onto chitosanand rosslinked chitosan beads", Reactive and Functional Polymers, 통권 : 50, pp.181~190 (2002)
- X. F. Zeng, "Control of pore sizes in macroporous chitosan and chitin membranes", Industrial & Engineering Chemistry Research, 통권 : 35, pp.4169~4175 (1996)
- M. S. Chiou, "Equilibrium and kinetic modeling of adsorption of reactive dyes on crosslinked chitosan beads", Journal of Hazardous Materials, 통권 : B93, pp.233~248 (2002)
