전사 방법에 따른 그래핀의 물 접촉각 변화
Water Contact Angles of Graphene Transferred by Wet and Dry Transfer Methods
0
조회
0
다운로드
2
인용
0
참고문헌
키워드
초록
Graphene is a monolayer of carbon atoms (approximately 0.34 nm), arranged in a honeycomb network. It has been hailed as a next-generation flexible and transparent material because it has high electrical and thermal conductivities, excellent mechanical properties, as well as flexible and transparent properties. The wettability of graphene alters its adhesion or surface energy, and it is therefore an important parameter influencing its application in the fabrication of next-generation flexible and transparent electronics. Studies on the wettability of graphene are numerous and various opinions exist. However, almost all of these studies use the wet transfer method to transfer the graphene. In this study, therefore, we investigated the effect of wet and dry transfer methods on water contact angles of graphene on a substrate. The contact angles of substrates vary depending on the type of substrate. It was found that after graphene is transferred to the substrate, regardless of transfer method, the graphene/substrate contact angle increases to a value. The contact angle of graphene transferred using the dry transfer method is higher than the contact angle of graphene transferred using wet transfer methods. The wet transferred graphene is affected by the poly(methyl methacrylate) (PMMA) residue and the polar surface of substrate. The dry transferred graphene is influenced by the conformal contact between graphene and substrate.
Abstract
Graphene is a monolayer of carbon atoms (approximately 0.34 nm), arranged in a honeycomb network. It has been hailed as a next-generation flexible and transparent material because it has high electrical and thermal conductivities, excellent mechanical properties, as well as flexible and transparent properties. The wettability of graphene alters its adhesion or surface energy, and it is therefore an important parameter influencing its application in the fabrication of next-generation flexible and transparent electronics. Studies on the wettability of graphene are numerous and various opinions exist. However, almost all of these studies use the wet transfer method to transfer the graphene. In this study, therefore, we investigated the effect of wet and dry transfer methods on water contact angles of graphene on a substrate. The contact angles of substrates vary depending on the type of substrate. It was found that after graphene is transferred to the substrate, regardless of transfer method, the graphene/substrate contact angle increases to a value. The contact angle of graphene transferred using the dry transfer method is higher than the contact angle of graphene transferred using wet transfer methods. The wet transferred graphene is affected by the poly(methyl methacrylate) (PMMA) residue and the polar surface of substrate. The dry transferred graphene is influenced by the conformal contact between graphene and substrate.
참고문헌 (10)
- Das, T., "Graphene-based flexible and wearable electronics", J. Semicond., 39(1), pp.011007~ (2018)[DOI]
- Kozbial, A., "Understanding the intrinsic water wettability of graphite", Carbon, 74, pp.218~225 (2014)[DOI]
- Shih, C. J., "Breakdown in the wetting transparency of graphene", Phys. Rev. Lett., 109, pp.176101~ (2012)[DOI]
- Rafiee, J., "Wetting transparency of graphene", Nat. Mater., 11, pp.217~222 (2012)[DOI]
- Li, Z., "Effect of airborne contaminants on the wettability of supported graphene and graphite", Nat. Mater., 12, pp.925~931
- Shih, C. J., "Wetting translucency of graphene", Nat. Mater., 12, pp.866~869 (2013)[DOI]
- Jo, K., "One-step etching, doping, and adhesion-control process for graphene electrodes", Carbon, 82, pp.168~175 (2015)[DOI]
- Choi, T., "Roll-to-roll continuous patterning and transfer of graphene via dispersive adhesion", Nanoscale, 7, pp.7138~7142 (2015)[DOI]
- Israelachvili, J. N., "Intermolecular and surface forces" (2011), Elsevier
- Lee, S. M., "Materialization of strained CVD-graphene using thermal mismatch", Nano Research, 8, pp.2082~2091 (2015)[DOI]
